GB927532A - Polymerisation catalysts - Google Patents
Polymerisation catalystsInfo
- Publication number
- GB927532A GB927532A GB39624/59A GB3962459A GB927532A GB 927532 A GB927532 A GB 927532A GB 39624/59 A GB39624/59 A GB 39624/59A GB 3962459 A GB3962459 A GB 3962459A GB 927532 A GB927532 A GB 927532A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- metal
- diphenylamide
- magnesium
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
A polymerization catalyst comprises a compound of a metal of Group I, II or III of the Periodic Table according to Mendel<\>aeeff in which the metal is bound to nitrogen atoms and in which no metal-to-carbon or covalent metal-to-hydrogen bonds are present, together with a compound of a transition metal of Group IV, V, VI, VII or VIII of the Table. Preferred compounds are those having the general formula Xn Me [N (R1 R2)]m wherein Me is beryllium, lithium, magnesium or aluminium, R1 and R2 are the same or different and represent alkyl, cycloalkyl, aryl or alkylaryl groups or, conjointly with the nitrogen atom form a heterocyclic ring, X is chlorine, bromine or iodine, n is zero or an integer, m is an integer, and n+m is the valency of the metal Me. Specified compounds are: aluminium-tris (diphenylamide), magnesium diphenylamide bromide, aluminium bis (diphenylamide) chloride, magnesium (diethylamide) bromide, aluminium tris (N-carbazyl), aluminium bis (diphenylamide) bromide, aluminium bis (diethylamide) monochloride, aluminium tris diethylamide, bis (magnesium iodide) phenylamide, and aluminium nitride. The second compound may be TiCl3, CoCl3, Ti(OC3H7)4, CrCl3 or VCl3.ALSO:A polymerization catalyst comprises a compound of a metal of Group I, II or III of the Periodic Table according to Mendel<\>aeef in which the metal is bound to nitrogen atoms and in which no metal-to-carbon or covalent metal-to-hydrogen bonds are present, together with a compound of a transition metal of Group IV, V, VI, VII or VIII of the Table. Preferred compounds are those having the general formula XnMe[N(R1R2)]m wherein Me is beryllium, lithium, magnesium or aluminium, R1 and R2 are the same or different and represent alkyl, cycloalkyl, aryl or alkylaryl groups or, conjointly with the nitrogen atom form a heterocyclic ring, X is chlorine, bromine or iodine, n is zero or an integer, m is an integer, and n+m is the valency of the metal Me. Specified compounds are aluminium-tris(diphenylamide), magnesium diphenylamide bromide, aluminium bis(diphenylamide) chloride, magnesium (diethylamide) bromide, aluminium tris(N-carbazyl), aluminium bis(diphenylamide) bromide, aluminium bis(diethylamide) monochloride, aluminium tris diethylamide, bis(magnesium iodide) phenylamide, and aluminium nitride. The second compound may be TiCl3, CoCl3, Ti(OC3H7)4, CrCl3 or VCl3. The catalyst may be used for the polymerization of ethylene, propylene or butadiene.ALSO:Magnesium diphenylamide bromide is reacted with AlCl3 to give aluminium trisdiphenylamide. The latter compound may be reacted with AlCl3 to give aluminium bis(diphenylamide) chloride, or with AlBr3 to give the corresponding bromide. Aluminium tris-diethylamide is prepared from AlCl3 and magnesium diethylamide bromide; the product may be reacted with AlCl3 to give aluminium bis(diethylamide) chloride. Aluminium tris(N-carbazyl) is prepared from AlEt3 and carbazole.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT1769058 | 1958-11-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB927532A true GB927532A (en) | 1963-05-29 |
Family
ID=11150552
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB39624/59A Expired GB927532A (en) | 1958-11-28 | 1959-11-23 | Polymerisation catalysts |
Country Status (7)
Country | Link |
---|---|
US (1) | US3208986A (en) |
BE (1) | BE585112A (en) |
ES (1) | ES253768A1 (en) |
FR (1) | FR1241521A (en) |
GB (1) | GB927532A (en) |
IT (1) | IT601433A (en) |
NL (2) | NL110227C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5320993A (en) * | 1992-07-17 | 1994-06-14 | Phillips Petroleum Company | Dimerization catalyst systems and processes |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2588557B1 (en) * | 1985-10-16 | 1990-04-20 | Rhone Poulenc Chim Base | PROCESS FOR THE PREPARATION OF ARYLAMINOALUMINIUM |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2918494A (en) * | 1959-12-22 | Production of organometallic | ||
BE551789A (en) * | 1955-10-20 | |||
US2910493A (en) * | 1955-12-28 | 1959-10-27 | J W Ayers & Co | Hydroxy-, alkoxy-aluminum salts of aliphatic amino acids |
US2929808A (en) * | 1956-04-04 | 1960-03-22 | Exxon Research Engineering Co | Removal of metal contaminants in polymerization processes |
US2907781A (en) * | 1956-06-08 | 1959-10-06 | Victor M Hermelin | Monohydroxy magnesium aluminum salt of an amino aliphatic acid and method of preparing same |
US2909510A (en) * | 1958-11-20 | 1959-10-20 | Hercules Powder Co Ltd | Propylene polymerization process |
-
0
- BE BE585112D patent/BE585112A/xx unknown
- IT IT601433D patent/IT601433A/it unknown
- NL NL245847D patent/NL245847A/xx unknown
- NL NL110227D patent/NL110227C/xx active
-
1959
- 1959-11-20 US US854230A patent/US3208986A/en not_active Expired - Lifetime
- 1959-11-23 GB GB39624/59A patent/GB927532A/en not_active Expired
- 1959-11-25 FR FR811189A patent/FR1241521A/en not_active Expired
- 1959-11-27 ES ES0253768A patent/ES253768A1/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5320993A (en) * | 1992-07-17 | 1994-06-14 | Phillips Petroleum Company | Dimerization catalyst systems and processes |
US5414178A (en) * | 1992-07-17 | 1995-05-09 | Phillips Petroleum Company | Dimerization catalyst systems and processes |
Also Published As
Publication number | Publication date |
---|---|
ES253768A1 (en) | 1960-05-16 |
FR1241521A (en) | 1960-09-16 |
NL110227C (en) | 1900-01-01 |
US3208986A (en) | 1965-09-28 |
IT601433A (en) | 1900-01-01 |
BE585112A (en) | 1900-01-01 |
NL245847A (en) | 1900-01-01 |
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