GB924945A - Urethane polymer compositions - Google Patents

Urethane polymer compositions

Info

Publication number
GB924945A
GB924945A GB8346/61A GB834661A GB924945A GB 924945 A GB924945 A GB 924945A GB 8346/61 A GB8346/61 A GB 8346/61A GB 834661 A GB834661 A GB 834661A GB 924945 A GB924945 A GB 924945A
Authority
GB
United Kingdom
Prior art keywords
oxide
phosphorus
antimony
phosphate
bromine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8346/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13983A external-priority patent/US3164558A/en
Priority claimed from US32620A external-priority patent/US3259593A/en
Priority claimed from US32619A external-priority patent/US3162609A/en
Priority claimed from US32621A external-priority patent/US3379656A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB924945A publication Critical patent/GB924945A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/016Flame-proofing or flame-retarding additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/02Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers

Abstract

Flame retardant and/or self-extinguishing urethane polymer compositions or shaped articles made therefrom are characterized in that the flame-retardant properties are due to the presence of (1) combinations comprising effective amounts of ammonium bromide and of either (a) antimony oxide, arsenic oxide, phosphorus oxide, the nitrogen-phosphorus complex resulting from the reaction of ammonia with phosphorus pentoxide, or an antimony salt, or of (b) a mixture of two or more of such antimony, arsenic and phosphorus compounds; (ii) a combination comprising effective amounts of a polybromoalkyl phosphate, containing at least 45% by weight of bromide, and of either (a) antimony oxide, arsenic oxide, phosphorus oxide, the nitrogen-phosphorus complex resulting from reaction of ammonia with phosphorus pentoxide, or an antimony salt, or of (b) a mixture of two or more such inorganic antimony, arsenic and phosphorus compounds; (iii) a combination comprising effective amounts of a phosphorus oxide and at least one organic flame-proofing agent containing at least 45% by weight of bromine and having a plurality of bromine atoms in an aliphatic or cycloaliphatic portion of the molecule; (iv) a combination comprising effective amounts of the nitrogen-phosphorus complex resulting from the reaction of ammonia with phosphorus pentoxide and at least one organic flame-proofing agent other than a polybromoalkyl phosphate, which organic flame-proofing agent contains at least 45% by weight of bromine and has a plurality of bromine atoms in an aliphatic or cycloaliphatic portion of the molecule; or (v) a combination comprising effective amounts of a halogen-containing antimony salt and at least one organic flame-proofing agent other than a polybromoalkyl phosphate, which organic flame-proofing agent contains at least 45% by weight of bromine and has a plurality of bromine atoms in an aliphatic or cycloaliphatic portion of the molecule. The combination of the different kinds of compound imports greater self-extinguishing properties than does the same amount of either of the materials used alone. Specified bromides are methyl 2,3-dibromopropionate, tris(2,3-dibromopropyl) phosphate, carbon tetrabromide, tetrabromoethylene, 1,2-dibromo-1,1,2,2-tetrachloroethane, 1,1,2,2-tetrabromoethane, dibromodichloromethane, pentabromoethane, hexabromoethane, dibromosuccinic acid, 1,2-di(dibromomethyl) benzene, a ,b -dibromoethyl benzene, 1,2,3,4,5,6-hexabromocyclohexane, 1,2,3,4,5-pentabromo-6-chlorocyclohexane, tetrabromodichloro-cyclohexanes and tribromotrichlorocyclohexanes. The specified inorganic compounds include antimonous oxide, arsenous oxide, arsenic oxide, phosphoric oxide, antimonous chloride, bromide or iodide, antimony oxychloride or antimonous sulphide. The phosphoric oxide is preferably used as a nitrogen-phosphorus complex obtained by heating phosphorus pentoxide with excess anhydrous ammonia. The polymer compositions can be used as mouldings, castings, coatings, laminates and foams and in potting electrical equipment. In Example (1) a composition of a polyol (obtained by reacting glycerol and sucrose with propylene oxide), triethylene diamine, dibutyltin dilaurate and a copolymer of polyethylene glycol and dimethylsiloxane, is mixed with trichlorofluoromethane and an adduct of toluene-2,4 and 2,6-diisocyanates with a propylene oxide/glycerol condensate. Tris(2,3-dibromopropyl) phosphate and finely divided antimonous oxide are stirred in, the mixture is poured into a mould, and the gelled foam is cured at 70 DEG C. The use of other flame-proofing materials is illustrated in further examples of the preparation of foams. Other starting materials used include (22 to 24) octakis (2-hydroxypropyl) sucrose, and an adduct of toluene diisocyanates with a propylene oxide/2,2-di(hydroxymethyl) butanol condensate; (25) a polyester from glycerine, adipic acid and phthalic anhydride, and tolylene diisocyanate, foam being obtained by adding dioctyl sulphosuccinate in acetone and zinc distearate; (30) a mixture of propoxylated glycerol and polypropylene oxide; (44) a tolylene diisocyanate/polyol reaction product and octakis[2-(2-hydroxypropoxy) propyl]-sucrose. Specification 793,501 is referred to.ALSO:Flame retardant and/or self-extinguishing urethane polymer compositions or shaped articles made therefrom are characterised in that the flame-retardant properties are due to the presence of (i) combinations comprising effective amounts of ammonium bromide and of either (a) antimony oxide, arsenic oxide, phosphorus oxide, the nitrogen-phosphorus complex resulting from the reaction of ammonia with phosphorus pentoxide, or an antimony salt or of (b) a mixture of two or more of such antimony, arsenic and phosphorus compounds; (ii) a combination comprising effective amounts of a polybromoalkyl phosphate, containing at least 45% by weight of bromine and of either (a) antimony oxide, arsenic oxide, phosphorus oxide, the nitrogen-phosphorus complex resulting from reaction of ammonia with phosphorus pentoxide, or an antimony salt, or of (b) a mixture of two or more such inorganic antimony, arsenic and phosphorus compounds; (iii) a combination comprising effective amounts of a phosphorus oxide and at least one organic flame-proofing agent containing at least 45% by weight of bromine and having a plurality of bromine atoms in an aliphatic or cycloaliphatic portion of the molecule; (iv) a combination comprising effective amounts of the nitrogen-phosphorus complex resulting from the reaction of ammonia with phosphorus pentoxide and at least one organic flame-proofing agent other than a polybromoalkyl phosphate, which organic flame-proofing agent contains at least 45% by weight of bromine and has a plurality of bromine atoms in an aliphatic or cycloaliphatic portion of the molecule; or (v) a combination comprising effective amounts of a halogen-containing antimony salt and at least one organic flame-proofing agent other than a polybromoalkyl phosphate, which organic flame-proofing agent contains at least 45% by weight of bromine and has plurality of bromine atoms in an aliphatic or cycloaliphatic portion of the molecule. The combination of the different kinds of compound imparts greater self-extinguishing properties than does the same amount of either of the materials used alone. Specified bromides are methyl 2, 3-dibromopropionate, tris(2, 3-dibromopropyl) phosphate, carbon tetrabromide, tetrabromo-ethylene, 1, 2-dibromo1, 1, 2, 2-tetrachloroethane, 1, 1, 2, 2-tetrabromoethane, dibromodichloromethane, pentabromoethane, hexabromoethane, dibromo-succinic acid, 1, 2-di (dibromomethyl) benzene, a , b -dibromoethyl benzene, 1, 2, 3, 4, 5,-pentabromo-6-chlorocyclohexane, tetrabromodichloro-cyclohexanes and tribromotrichlorocyclohexanes. The specified inorganic compounds include antimonous oxide, arsenous oxide, arsenic oxide, phosphoric oxide, antimonous chloride, bromide or iodide, antimony oxychloride or antimonous sulphide. The phosphorus oxide is preferably used as a nitrogen-phosphorus complex obtained by heating phosphorus pentoxide with excess anhydrous ammonia. The polymer compositions can be used as mouldings, castings, coatings, laminates and foams and in potting electrical equipment. In Example (1) a composition of a polyol (obtained by reacting glycerol and sucrose with propylene oxide), triethylenediamine, dibutyltin dilaurate and a copolymer of polyethylene glycol and dimethylsiloxane is mixed with trichlorofluoromethane and an adduct of toluene -2, 4 and 2, 6-diisocyanates with a propylene oxide/glycerol condensate. Tris (2, 3-dibromopropyl)- phosphate and finely divided antimonous oxide are stirred in, the mixture is poured into a mould, and the gelled foam is cured at 70 DEG C. The use of other flame-proofing materials is illustrated in further examples of the preparation of foams. Other starting materials used include (22 to 24) octakis (2-hydroxypropyl)-sucrose, an adduct of toluene diisocyanates with a propylene oxide/2, 2-di(hydroxymethyl) butanol condensate; (25) a polyester from glycerine, adipic acid and phthalic anhydride, and tolylene diisocyanate, foam being obtained by adding dioctyl sulphosuccinate in acetone and zinc distearate; (30) a mixture of propoxylated glycerol and polypropylene oxide; (44) a tolylene diisocyanate/polyol reaction product and octakis [2-(2-hydroxypropoxy) propyl]- sucrose. Specification 793,501 is referred to.
GB8346/61A 1960-03-10 1961-03-07 Urethane polymer compositions Expired GB924945A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13983A US3164558A (en) 1960-03-10 1960-03-10 Self-extinguishing urethane polymer compositions
US32620A US3259593A (en) 1960-05-31 1960-05-31 Self-extinguishing urethane polymer compositions
US32619A US3162609A (en) 1960-05-31 1960-05-31 Self-extinguishing urethane polymer compositions
US32621A US3379656A (en) 1960-05-31 1960-05-31 Urethanepolymer compositions

Publications (1)

Publication Number Publication Date
GB924945A true GB924945A (en) 1963-05-01

Family

ID=27486352

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8346/61A Expired GB924945A (en) 1960-03-10 1961-03-07 Urethane polymer compositions

Country Status (2)

Country Link
DE (1) DE1249519B (en)
GB (1) GB924945A (en)

Also Published As

Publication number Publication date
DE1249519B (en) 1967-09-07

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