GB923584A - Polymeric compounds - Google Patents

Polymeric compounds

Info

Publication number
GB923584A
GB923584A GB2599658A GB2599658A GB923584A GB 923584 A GB923584 A GB 923584A GB 2599658 A GB2599658 A GB 2599658A GB 2599658 A GB2599658 A GB 2599658A GB 923584 A GB923584 A GB 923584A
Authority
GB
United Kingdom
Prior art keywords
chain
triazine
atoms
methyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2599658A
Inventor
Heinz Rudolf Niebergall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel UK PLC
Original Assignee
Courtaulds PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Courtaulds PLC filed Critical Courtaulds PLC
Priority to GB2599658A priority Critical patent/GB923584A/en
Publication of GB923584A publication Critical patent/GB923584A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/62—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/12—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing tin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A polymer having the unit general formula <FORM:0923584/IV(a)/1> wherein A is N or CH, R is H or CH3, X is -O- or -NH-, R1 and R2 are each an alkyl or aryl radical, Y is a divalent group comprising a direct chain of at least 3 C atoms and may also contain a S atom in the chain, and M is Si or Sn, may be made by reacting together (a) an unsaturated derivative of 1, 3, 5-triazine or of 1, 3-pyrimidine having the general formula <FORM:0923584/IV(a)/2> in which A is N or CH, X is -O- or -NH- and Y1 is an unsaturated group comprising a direct chain of at least 3 C atoms with a single ethylenic double bond in the chain, and (b) a diorgano tin or silicon compound of the formula <FORM:0923584/IV(a)/3> wherein the Z's are H atoms or mercapto groups of the formula -(CH2)n-SH, n being a small number, and R1, R2 and M are as above defined. Reactants specified are 2-methyl-4:6-diallyloxy-1:3:5-triazine, 2-methyl-4:6-diallylamino-1:3:5-triazine, 2-methyl-4:6-diallyloxy-pyrimidine, diethyl tin hydride and diethyl-, diphenyl-, methylphenyl- and dimethyl-bis-(mercaptopropyl)-silanes. The reaction may be effected in the absence or presence of (i) solvents, e.g. tributylamine, tetrahydrofuran, pyran, dioxane, diethyleneglycol dimethylether and ethyleneglycol diethylether, and (ii) catalysts, e.g. organic peroxides, azo-compounds, ultra-violet light (with or without such catalysts), platinum, nickel and hydrochloroplatinic acid, at temperatures varying from room temperature to 200 DEG C. The resulting polymers may be oils, resins, rubbers or amorphous powders. Examples are given.
GB2599658A 1958-08-13 1958-08-13 Polymeric compounds Expired GB923584A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2599658A GB923584A (en) 1958-08-13 1958-08-13 Polymeric compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2599658A GB923584A (en) 1958-08-13 1958-08-13 Polymeric compounds

Publications (1)

Publication Number Publication Date
GB923584A true GB923584A (en) 1963-04-18

Family

ID=10236672

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2599658A Expired GB923584A (en) 1958-08-13 1958-08-13 Polymeric compounds

Country Status (1)

Country Link
GB (1) GB923584A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5393859A (en) * 1993-06-07 1995-02-28 Ciba-Geigy Corporation Organopolysiloxanes containing substituted 1,3,5-triazine units

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5393859A (en) * 1993-06-07 1995-02-28 Ciba-Geigy Corporation Organopolysiloxanes containing substituted 1,3,5-triazine units

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