GB923154A - Method for the manufacture of polymeric trioxane - Google Patents

Method for the manufacture of polymeric trioxane

Info

Publication number
GB923154A
GB923154A GB2446361A GB2446361A GB923154A GB 923154 A GB923154 A GB 923154A GB 2446361 A GB2446361 A GB 2446361A GB 2446361 A GB2446361 A GB 2446361A GB 923154 A GB923154 A GB 923154A
Authority
GB
United Kingdom
Prior art keywords
trioxane
polymeric
manufacture
heptane
acetone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2446361A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JAPANESE ASS FOR RADIATION RES
Original Assignee
JAPANESE ASS FOR RADIATION RES
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JAPANESE ASS FOR RADIATION RES filed Critical JAPANESE ASS FOR RADIATION RES
Publication of GB923154A publication Critical patent/GB923154A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/02Polymerisation initiated by wave energy or by particle radiation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10Polymerisation of cyclic oligomers of formaldehyde

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Trioxane, containing at most 2% of water, in the solid phase is subjected to the irradiation of ionizing rays at -78 DEG to 60 DEG C., less than 20% of the total reagents of a solvent which is non-reactive with regard to the trioxane may also be present, e.g. benzene, heptane, acetone and methylene chloride. The trioxane may be in the form of macroscopic crystals and the polymer may be heated at near 60 DEG C.
GB2446361A 1960-07-12 1961-07-06 Method for the manufacture of polymeric trioxane Expired GB923154A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3087660 1960-07-12

Publications (1)

Publication Number Publication Date
GB923154A true GB923154A (en) 1963-04-10

Family

ID=12315918

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2446361A Expired GB923154A (en) 1960-07-12 1961-07-06 Method for the manufacture of polymeric trioxane

Country Status (3)

Country Link
BE (1) BE605982A (en)
DE (1) DE1247020B (en)
GB (1) GB923154A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1243390B (en) * 1963-06-14 1967-06-29 Grace W R & Co Process for the production of high molecular weight polyoxymethylenes
US3202597A (en) * 1963-06-24 1965-08-24 Grace W R & Co Irradiation polymerization of compressed particulate trioxane

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1214169A (en) * 1958-07-23 1960-04-07 Houilleres Bassin Du Nord New process for the preparation of polyformaldehydes

Also Published As

Publication number Publication date
DE1247020B (en) 1967-08-10
BE605982A (en)

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