GB923109A - Improvements in and relating to sugar purification - Google Patents

Improvements in and relating to sugar purification

Info

Publication number
GB923109A
GB923109A GB16790/61A GB1679061A GB923109A GB 923109 A GB923109 A GB 923109A GB 16790/61 A GB16790/61 A GB 16790/61A GB 1679061 A GB1679061 A GB 1679061A GB 923109 A GB923109 A GB 923109A
Authority
GB
United Kingdom
Prior art keywords
cellulose
substrate
bed
derivatives
sugar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16790/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PETER ARTHUR SOUTH CANHAM
Davco Pty Ltd
Original Assignee
PETER ARTHUR SOUTH CANHAM
Davco Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PETER ARTHUR SOUTH CANHAM, Davco Pty Ltd filed Critical PETER ARTHUR SOUTH CANHAM
Publication of GB923109A publication Critical patent/GB923109A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13BPRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00Purification of sugar juices
    • C13B20/14Purification of sugar juices using ion-exchange materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

In a process for the purification of sugar (see Group VI) an ion-exchange absorption material comprises a substrate of asbestos fibre or kieselguhr having a surface layer of a cellulose derivative containing basic amino, substituted amino or quaternary ammonium groups or heterocyclic nitrogen radicals.ALSO:A process for the purification of a sugar solution comprises passing the sugar solution or syrup through a bed or mat of an ion-exchange absorption material comprising a substrate of inert material having a surface thereon of a cellulose derivative which contains basic amino, substituted amino, quaternary ammonium groups or heterocyclic nitrogen radicals. The substrate may be of cellulosic, asbestos or synthetic fibre or of keiselguhr. When cellulose is the substrate, the surface layer may be obtained by chemical modification of the surface of the fibres to form amino-derivatives of cellulose, e.g. aminoalkyl cellulose or substituted aminoalkyl derivatives such as diethylaminoethyl, dimethylaminoethyl- and piperidinoalkyl cellulose. These derivatives may be treated with alkyl halides, sulphates or toluenesulphonates to form quaternary ammonium groups. Instead of forming the surface layer chemically, a cellulose derivative may be applied to the substrate to form a layer thereon. Regeneration of the bed or mat may be carried out by flushing with, e.g. potassium and sodium hydroxides and/or sodium chloride, and is economically effected by dividing the regenerant solution into two fractions, and rinsing the bed with hot water between treatment with each fraction. In an example, sugar solutions, e.g. "green syrup" are filtered through a 2 inch deep bed of cellulose fibres having a surface of the diethylaminoethyl derivative; 80 to 90% of the colour is removed. Colloidal material, e.g. proteins may also be removed. The process may be made selective by passing the sugar solutions successively through similar beds which have been regenerated in different ways.ALSO:A process for the purification of a sugar solution comprises passing the sugar solution or syrup through a bed or mat of an ion-exchange absorption material comprising a substrate of inert material having a surface thereon of a cellulose derivative which contains basic amino, substituted amino, quaternary ammonium groups or heterocyclic nitrogen radicals. The substrate may be of cellulosic, asbestos or synthetic fibre or of kieselguhr. When cellulose is the substrate, the surface layer may be obtained by chemical modification of the surface of the fibres to form aminoderivatives of cellulose e.g. aminoalkyl cellulose or substituted aminoalkyl derivatives such as diethylaminoethyl-, dimethylaminoethyl-and piperidinoalkyl cellulose. These derivatives may be treated with alkyl halides, sulphates or toluene-sulphonates to form quaternary ammonium groups. Instead of forming the surface layer chemically, a cellulose derivative may be applied to the substrate to form a layer thereon, Regeneration of the bed or mat may be carried out by flushing with e.g. potassium and sodium hydroxides and/or sodium chloride, and is economically effected by dividing the regenerant solution into two fractions, and rinsing the bed with hot water between treatment with each fraction. In an example, sugar solutions e.g. "green syrup" are filtered through a 2 inch deep bed of cellulose fibres having a surface of the diethylaminoethyl derivative; 80% to 90% of the colour is removed. Colloidal material e.g. proteins may also be removed. The process may be made selective by passing the sugar solutions successively through similar beds which have been regenerated in different ways.ALSO:A process for the purification of a sugar solution comprises passing the sugar solution or syrup through a bed or mat of an ion-exchange absorption material comprising a substrate of inert material having a surface thereon of a cellulose derivative which contains basic amino, substituted amino, quaternary ammonium groups or heterocyclic nitrogen radicals. The substrate may be of cellulosic, asbestos or synthetic fibre or of kieselguhr. When cellulose is the substrate, the surface layer may be obtained by chemical modification of the surface of the fibres to form amino-derivatives of cellulose e.g. aminoalkyl cellulose or substituted aminoalkyl derivatives such as diethylaminoethyl-, dimethylaminoethyl- and piperidinoalkyl cellulose. These derivatives may be treated with alkyl halides, sulphates or toluene-sulphonates to form quaternary ammonium groups. Instead of forming the surface layer chemically, a cellulose derivative may be applied to the substrate to form a layer thereon. Regeneration of the bed or mat may be carried out by flushing with e.g. potassium and sodium hydroxides and/or sodium chloride, and is economically effected by dividing the regenerant solution into two fractions, and rinsing the bed with hot water between treatment with each fraction. In an example, sugar solutions e.g. "green syrup," are filtered through a two-inch-deep bed of cellulose fibres having a surface of the diethylaminoethyl derivative; 80% to 90% of the colour is removed. Colloidal material e.g. proteins, may also be removed. The process may be made selective by passing the sugar solutions successively through similar beds which have been regenerated in different ways.
GB16790/61A 1960-05-10 1961-05-09 Improvements in and relating to sugar purification Expired GB923109A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA601924 1960-05-10

Publications (1)

Publication Number Publication Date
GB923109A true GB923109A (en) 1963-04-10

Family

ID=25560511

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16790/61A Expired GB923109A (en) 1960-05-10 1961-05-09 Improvements in and relating to sugar purification

Country Status (1)

Country Link
GB (1) GB923109A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2490676A1 (en) * 1980-09-19 1982-03-26 Rhone Poulenc Ind PROCESS FOR PURIFYING SUGAR CANE JUICE
GB2151599A (en) * 1983-11-11 1985-07-24 Atomic Energy Authority Uk Composite materials having thiol groups
FR2999606A1 (en) * 2012-12-18 2014-06-20 Lesaffre & Cie PROCESS FOR PURIFYING BEET JUICE

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2490676A1 (en) * 1980-09-19 1982-03-26 Rhone Poulenc Ind PROCESS FOR PURIFYING SUGAR CANE JUICE
GB2151599A (en) * 1983-11-11 1985-07-24 Atomic Energy Authority Uk Composite materials having thiol groups
FR2999606A1 (en) * 2012-12-18 2014-06-20 Lesaffre & Cie PROCESS FOR PURIFYING BEET JUICE
WO2014096656A1 (en) * 2012-12-18 2014-06-26 Lesaffre Et Compagnie Process for purifying beet juice
JP2016502841A (en) * 2012-12-18 2016-02-01 ルサッフル・エ・コンパニーLesaffre Et Compagnie Method for purifying beet soup
AU2013366210B2 (en) * 2012-12-18 2017-05-11 Lesaffre Et Compagnie Process for purifying beet juice
US9765410B2 (en) 2012-12-18 2017-09-19 Lesaffre Et Compagnie Process for purifying beet juice

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