GB916529A - Treatment of natural or synthetic macromolecular substances - Google Patents

Treatment of natural or synthetic macromolecular substances

Info

Publication number
GB916529A
GB916529A GB8899/61A GB889961A GB916529A GB 916529 A GB916529 A GB 916529A GB 8899/61 A GB8899/61 A GB 8899/61A GB 889961 A GB889961 A GB 889961A GB 916529 A GB916529 A GB 916529A
Authority
GB
United Kingdom
Prior art keywords
polymers
epoxy group
bond
polymer
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8899/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Publication of GB916529A publication Critical patent/GB916529A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
    • D06M14/28—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/52—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin

Abstract

Organic compounds containing an epoxy group and a polymerizable double bond are graft polymerized on the surface of a natural or synthetic polymer, and the resulting graft polymer is treated with a compound containing active hydrogen which is capable of opening up the epoxy group. The epoxy group-containing compound may be one having the formula <FORM:0916529/IV(a)/1> in which R1, R2 and R3 are hydrogen atoms or alkyl or aryl groups and A is an ether bond, an ester bond or a urethane bond, e.g. vinyl glycidyl ether, glycidyl acrylate and methacrylate and vinyl glycidyl urethane. Polymers specified are polyethylene, polypropylene, polyvinyl chloride, polytetrafluoroethylene, polyesters, polyamides, polyurethanes, polysulphides, polyacetals, diene polymers and polymers containing silicon or titanium. The polymers may be used in the form of a fibre, film or other shaped article. Grafting may take place under the influence of gamma rays or ultra-violet light, or the polymer may be activated by treatment with ozone. The grafting monomer may be used as such, in solution in a solvent which may or may not swell the base material, or in admixture with another monomer. The compound used to react with the epoxy groups of the graft polymer is preferably an amine, hydroxyamine, or an amino-acid. Lists of such compounds are provided, preferred being diethylamine, ethylene diamine, monoethanolamine, diethanolamine, hydroxylamine, m-aminophenol, 2-(31-phenoxy-21-hydroxypropylamino) ethanol and the sodium salts of alanine, lysine and leucine. The resulting products show improved dyeability, printability and hygroscopicity as compared with the base materials.
GB8899/61A 1960-03-10 1961-03-10 Treatment of natural or synthetic macromolecular substances Expired GB916529A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP742760 1960-03-10

Publications (1)

Publication Number Publication Date
GB916529A true GB916529A (en) 1963-01-23

Family

ID=11665546

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8899/61A Expired GB916529A (en) 1960-03-10 1961-03-10 Treatment of natural or synthetic macromolecular substances

Country Status (2)

Country Link
DE (1) DE1494142A1 (en)
GB (1) GB916529A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0471993A2 (en) * 1990-07-24 1992-02-26 Mitsubishi Rayon Co., Ltd. Polyorganosiloxane graft copolymers
US5391648A (en) * 1990-07-24 1995-02-21 Mitsubishi Rayon Co., Ltd. Polyorganosiloxane graft copolymers
EP1051583A1 (en) * 1998-01-29 2000-11-15 Gate Technologies International, Inc. Method of and apparatus for optically enhancing chemical reactions

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0471993A2 (en) * 1990-07-24 1992-02-26 Mitsubishi Rayon Co., Ltd. Polyorganosiloxane graft copolymers
EP0471993A3 (en) * 1990-07-24 1992-03-11 Mitsubishi Rayon Co., Ltd. Polyorganosiloxane graft copolymers
US5391648A (en) * 1990-07-24 1995-02-21 Mitsubishi Rayon Co., Ltd. Polyorganosiloxane graft copolymers
EP1051583A1 (en) * 1998-01-29 2000-11-15 Gate Technologies International, Inc. Method of and apparatus for optically enhancing chemical reactions
EP1051583A4 (en) * 1998-01-29 2001-10-10 Gate Technologies Internationa Method of and apparatus for optically enhancing chemical reactions

Also Published As

Publication number Publication date
DE1494142A1 (en) 1969-12-18

Similar Documents

Publication Publication Date Title
KR900012599A (en) Nail racker
NO962751L (en) Workable materials of polyhydroxy acids, and their use
CO4560578A1 (en) POLYMERIC COMPOSITIONS
DE50002711D1 (en) Branched polymers containing imidazole groups, and their preparation and use
US3322661A (en) Graft copolymerization of a vinyl monomer onto a polyolefin with irradiation in the presence of oxygen and a reducing agent
DK302689A (en) SULPHONAMIDES AND PROCEDURES FOR PREPARING THEREOF AND MEDICINES CONTAINING THESE COMPOUNDS
GB916529A (en) Treatment of natural or synthetic macromolecular substances
SE8600495L (en) THERMOPLASTIC COMPOSITIONS, PROCEDURE FOR PREPARING THESE AND ARTICLES RECEIVED FROM THESE COMPOSITIONS
SE8204737L (en) PREPARATION OF FORMULAS FROM A POLYESTER OR VINYL ESTABLISHER CURTAIN / GLASS FIBER COMPOSITION AND CURTAIN PLASTIC COATING COMPOSITION FOR USE
GB916244A (en) Dye-receptive polymer compositions and method of making same
FI871664A0 (en) DISPERSIONSPOLYMERER, FOERFARANDE FOER DERAS FRAMSTAELLNING OCH DERAS ANVAENDNING.
ES448757A1 (en) Process for coating polyolefin films
GB803191A (en) Improvements in or relating to coated regenerated cellulose film
GB805549A (en) Production and use of anti-static compositions
NO20001383D0 (en) Crosslinked materials of thermoplastic fluoropolymers and crosslinking process
ATE103952T1 (en) SINGLE OR MULTILAYER PLASTIC FILM, PROCESS FOR THEIR PRODUCTION AND USE OF THE SAME.
ES2094767T3 (en) SYNTHETIC RESINS.
CH609715A5 (en) Composition stabilised against the ultraviolet
GB810721A (en) Improvements in or relating to coated thermoplastic polymeric films
CO4560588A1 (en) TREATED CARBONACEASE COMPOSITIONS AND IMPROVED POLYMER COMPOSITIONS
ATE89847T1 (en) EPOXY RESIN COMPOUNDS WITH IMPROVED STORAGE STABILITY.
FR1276005A (en) Method for oriented elongation of organic films of thermoplastic polymer
GB938041A (en) A process for preparing readily dyeable polypropylene fibers
FR1228463A (en) Copolymerization under the effect of ultra-violet light, of high solid polymers such as polythene containing peroxy groups
Bataille et al. Effects of irradiation on PVC compounds