GB916132A - Polymerization and copolymerization of ª--monoolefins and diolefins - Google Patents
Polymerization and copolymerization of ª--monoolefins and diolefinsInfo
- Publication number
- GB916132A GB916132A GB1148461A GB1148461A GB916132A GB 916132 A GB916132 A GB 916132A GB 1148461 A GB1148461 A GB 1148461A GB 1148461 A GB1148461 A GB 1148461A GB 916132 A GB916132 A GB 916132A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- isooctane
- ethylene
- benzene
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
Abstract
Olefins may be polymerized by contacting with a catalyst formed by mixing a compound of formula TOaXb-a where T is a metal of Group IVa, Va, VIa, VIIa or VIII of the periodic system, X is a halogen, a is 0, 1 or 2, b is 1 to 7 and b-a is at least 1, with a catalyst component formed by reacting at 0 DEG to 150 DEG C. an anhydrous, particulate, finely divided, inorganic solid having hydroxyl groups chemically bonded to atoms forming part of the surface thereof with a compound of formula AlM1vXnRy-n where M1 is a metal of Group I, v is 0 or 1, X is a halogen, n is 0, 1 or 2, R is a monovalent hydrocarbon radical or hydride radical, y is 2, 3 or 4 and y-n is at least 2. The aluminium compound may be contacted with the inorganic solid in the liquid state, as a solution or in the vapour state, e.g. by passing the vapour alone or mixed with an inert carrier gas through the solid in a fixed, moving or fluidized bed reactor. Polymerization may be effected batchwise or continuously in the gas phase or preferably in the presence of an inert liquid reaction medium, e.g. aliphatic, cycloaliphatic and aromatic hydrocarbons, many suitable compounds being listed. Polymerization may be effected in the presence of a chain transfer agent, e.g. hydrogen, and the olefin feed and reaction medium may be purified before the polymerization by treatment with a metal alkyl. Many suitable monomers, solvents, inorganic solids, aluminium compounds and metal halides are listed and the examples describe processes using (1) ethylene, isooctane, silica, triisobutyl aluminium and titanium tetrachloride; (3) ethylene, isooctane, titania, triisobutyl aluminium and titanium tetrachloride; (4) propylene, benzene, magnesia, triethyl aluminium and zirconium tetrachloride; (5) ethylene and propylene, xylene, thoria, dihexyl aluminium chloride and zirconium tetrachloride; (6) butadiene and butene-1 isooctane, titania, diisobutyl aluminium hydride and manganese dichloride; (7) styrene, benzene, ferric oxide, trimethyl aluminium and ferric bromide; (8) butene-1, isooctane, zirconia, triisobutyl aluminium and vanadium trichloride; (9) butadiene, hexane, corundum, potassium trioctyl aluminium fluoride and vanadium oxytrichloride; (10) propylene, benzene, alumina, triethyl aluminium and zirconium tetrachloride; (11) ethylene and propylene, benzene, silica, dihexyl aluminium bromide and zirconium tetrachloride; (12) styrene, isooctane, alumina, potassium trioctyl aluminium fluoride and titanium tetraiodide; (13) butadiene, isoprene and ethylene, carbon black, trimethyl aluminium and titanium tetrachloride; and (14) ethylene, hydrogen, isooctane, titania, triisobutyl aluminium and titanium tetrachloride. The products may be extruded, milled, cast and converted to sponges or latices. They may be halogenated, dehalogenated, sulphohalogenated, sulphonated and crosslinked. They may be compounded with antioxidants, stabilizers, fillers, e.g. silica and carbon black, extenders, plasticizers, pigments, insecticides and fungicides. They may be compounded with hydrocarbon oils and waxes, and used as additives for lubricating oils and gelling agents for hydrocarbon oils.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3007960A | 1960-05-19 | 1960-05-19 | |
US3258860A | 1960-05-31 | 1960-05-31 | |
US8194861A | 1961-01-11 | 1961-01-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB916132A true GB916132A (en) | 1963-01-23 |
Family
ID=27363592
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1148461A Expired GB916132A (en) | 1960-05-19 | 1961-03-29 | Polymerization and copolymerization of ª--monoolefins and diolefins |
Country Status (5)
Country | Link |
---|---|
ES (1) | ES266358A1 (en) |
GB (1) | GB916132A (en) |
IT (1) | IT649919A (en) |
LU (1) | LU40146A1 (en) |
NL (1) | NL263345A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2461893A1 (en) * | 1974-01-02 | 1975-07-10 | Monsanto Co | IMPROVED CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
EP0063459A1 (en) * | 1981-04-09 | 1982-10-27 | Imperial Chemical Industries Plc | Polymer composition, production and use |
EP0085208A2 (en) * | 1982-01-29 | 1983-08-10 | BP Chemicals Limited | Polymerisation catalyst |
US7927416B2 (en) | 2006-10-31 | 2011-04-19 | Sensient Colors Inc. | Modified pigments and methods for making and using the same |
US7964033B2 (en) | 2007-08-23 | 2011-06-21 | Sensient Colors Llc | Self-dispersed pigments and methods for making and using the same |
US9221986B2 (en) | 2009-04-07 | 2015-12-29 | Sensient Colors Llc | Self-dispersing particles and methods for making and using the same |
-
0
- IT IT649919D patent/IT649919A/it unknown
- NL NL263345D patent/NL263345A/xx unknown
-
1961
- 1961-03-29 GB GB1148461A patent/GB916132A/en not_active Expired
- 1961-04-06 ES ES0266358A patent/ES266358A1/en not_active Expired
- 1961-05-17 LU LU40146A patent/LU40146A1/xx unknown
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2461893A1 (en) * | 1974-01-02 | 1975-07-10 | Monsanto Co | IMPROVED CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
EP0063459A1 (en) * | 1981-04-09 | 1982-10-27 | Imperial Chemical Industries Plc | Polymer composition, production and use |
US4473672A (en) * | 1981-04-09 | 1984-09-25 | Imperial Chemical Industries Plc | Polymer composition, production and use |
EP0085208A2 (en) * | 1982-01-29 | 1983-08-10 | BP Chemicals Limited | Polymerisation catalyst |
EP0085208A3 (en) * | 1982-01-29 | 1983-09-21 | BP Chemicals Limited | Polymerisation catalyst |
US7927416B2 (en) | 2006-10-31 | 2011-04-19 | Sensient Colors Inc. | Modified pigments and methods for making and using the same |
US8147608B2 (en) | 2006-10-31 | 2012-04-03 | Sensient Colors Llc | Modified pigments and methods for making and using the same |
US8163075B2 (en) | 2006-10-31 | 2012-04-24 | Sensient Colors Llc | Inks comprising modified pigments and methods for making and using the same |
US7964033B2 (en) | 2007-08-23 | 2011-06-21 | Sensient Colors Llc | Self-dispersed pigments and methods for making and using the same |
US8118924B2 (en) | 2007-08-23 | 2012-02-21 | Sensient Colors Llc | Self-dispersed pigments and methods for making and using the same |
US9221986B2 (en) | 2009-04-07 | 2015-12-29 | Sensient Colors Llc | Self-dispersing particles and methods for making and using the same |
Also Published As
Publication number | Publication date |
---|---|
LU40146A1 (en) | 1962-05-17 |
NL263345A (en) | |
IT649919A (en) | |
ES266358A1 (en) | 1961-11-01 |
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