GB912489A - Process for dry cleaning - Google Patents
Process for dry cleaningInfo
- Publication number
- GB912489A GB912489A GB2496859A GB2496859A GB912489A GB 912489 A GB912489 A GB 912489A GB 2496859 A GB2496859 A GB 2496859A GB 2496859 A GB2496859 A GB 2496859A GB 912489 A GB912489 A GB 912489A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- moles
- sulphonic acid
- product
- condensed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
Abstract
Dry-cleaning compositions comprise (a) a solvent, suitably perchlorethylene or Stoddard solvent, and (b) a substance represented by the formula <FORM:0912489/III/1> in which R1COOH is a fatty acid in which R1 has 12-18 carbon atoms and is saturated or unsaturated, and which has a titre not above 42 DEG C.; R2 is a C1-3-hydroxyalkyl group and R3 and R4 are of the same character or are hydrogen; S is a sulphonic acid, particularly a C12-20-alkylaryl sulphonic acid, or a sulphuric acid ester of a fatty alcohol, or a sulphated unsaturated fatty acid or an ester thereof; y is 1,3-3,8 x, but at least half of the alkanolamine present must be condensed with the fatty acid, and z is the molar quantity of acid S necessary to obtain a neutral product. Additive (b) is usually present to the extent of 0,5-2,5% by volume, and 0,3-1 oz. of water per lb. of fabric being cleaned is also preferably dispersed in the solvent; a favoured additive (b) is that obtained by condensing oleic acid with diethanolamine and neutralizing the product with dodecylbenzene sulphonic acid. U.S.A. Specifications 1,911,289, 2,024,981, 2,158,614, 2,471,667 and 2,599,391 are referred to.ALSO:Substances which are probably alkanolamide-alkanolamine salt mixtures and which are derived from reactants in the ratio represented by the formula <FORM:0912489/IV (b)/1> are obtained by condensing saturated or unsaturated fatty acid R1COOH (R1 being C12-18) with alkanolamine NR2R3R4 (R2 being a C1-3-hydroxyalkyl group, and R3 and R4 being groups of the same type or hydrogen) in such molar proportions that y is 1.3-3.8 x and in such a manner that at least half the alkanolamine present is actually condensed with the fatty acid, z being the molar quantity of S, which is a sulphonic acid, a sulphuric acid ester of a fatty alcohol or a sulphated unsaturated fatty acid or an ester thereof, which is then added to the condensate mixture to obtain a neutral product. In Examples (1) and (6) one mole of oleic acid is condensed with 1.8 moles diethanolamine and the product neutralized with 0.7 and 0.8 moles dodecylbenzene sulphonic acid respectively; (4) 0.67 moles of diethanolamine are condensed with 0.22 moles oleic acid in the presence of toluene, and the product neutralized with a mixture of 0.16 moles diethanolamine, 0.6 moles dodecylbenzene sulphonic acid, water and toluene; (5) 0.55 moles triethanolamine are condensed with 0.5 moles oleic acid in presence of toluene and the product neutralized with the reaction mixture of 0.35 moles triethanolamine and 0.4 moles of dodecylbenzene sulphonic acid in water; (7) the condensate of Example 6 is neutralized (a) with tridecylbenzene sulphonic acid and (b) with nonylbenzene sulphonic acid; and (8) the condensate of Example 6 is neutralized with petroleum sulphonic acid.ALSO:Dry-cleaning compositions which impart a soft hand and antistatic properties to textiles cleaned therewith comprise (a) a solvent such as perchlorethylene or Stoddard solvent, and (b) a substance represented by the formula <FORM:0912489/IV (b)/1> in which R1COOH is a C12-18 saturated or unsaturated fatty acid having a titre not above 42 DEG C.; R2 is a C1-3 hydroxyalkyl group and R3 and R4 are groups of the same type or hydrogen; S is a sulphonic acid, particularly a C12-20-alkylarylsulphonic acid, a sulphuric acid ester of a fatty alcohol, or a sulphated unsaturated fatty acid or an ester thereof; y is 1.3-3.8x, but at least half of the alkanolamine present must be condensed with the fatty acid, and z is the molar quantity of acid S necessary to obtain a neutral product. Additive (b) is normally present to the extent of 0.5-2.5% by volume, and 0.3-1 oz. of water per lb. of fabric being cleaned is usually dispersed in the solvent. A favoured additive (b) is that obtained by condensing oleic acid with diethanolamine and neutralizing the product with dodecylbenzene sulphonic acid. U.S.A. Specifications 1,991,289, 2,024,981, 2,158,614, 2,471,667 and 2,599,391 are referred to.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL101112D NL101112C (en) | 1959-07-21 | ||
FR1232035D FR1232035A (en) | 1959-07-21 | ||
NL241958D NL241958A (en) | 1959-07-21 | ||
GB2496859A GB912489A (en) | 1959-07-21 | 1959-07-21 | Process for dry cleaning |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2496859A GB912489A (en) | 1959-07-21 | 1959-07-21 | Process for dry cleaning |
Publications (1)
Publication Number | Publication Date |
---|---|
GB912489A true GB912489A (en) | 1962-12-05 |
Family
ID=10220108
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2496859A Expired GB912489A (en) | 1959-07-21 | 1959-07-21 | Process for dry cleaning |
Country Status (3)
Country | Link |
---|---|
FR (1) | FR1232035A (en) |
GB (1) | GB912489A (en) |
NL (2) | NL241958A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4267077A (en) * | 1978-02-15 | 1981-05-12 | Kao Soap Co., Ltd. | Detergent composition for dry cleaning |
-
0
- FR FR1232035D patent/FR1232035A/fr not_active Expired
- NL NL101112D patent/NL101112C/xx active
- NL NL241958D patent/NL241958A/xx unknown
-
1959
- 1959-07-21 GB GB2496859A patent/GB912489A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4267077A (en) * | 1978-02-15 | 1981-05-12 | Kao Soap Co., Ltd. | Detergent composition for dry cleaning |
Also Published As
Publication number | Publication date |
---|---|
NL101112C (en) | |
NL241958A (en) | |
FR1232035A (en) | 1960-10-05 |
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