GB910641A - Wear-and stain-resistant coated articles - Google Patents
Wear-and stain-resistant coated articlesInfo
- Publication number
- GB910641A GB910641A GB2001659A GB2001659A GB910641A GB 910641 A GB910641 A GB 910641A GB 2001659 A GB2001659 A GB 2001659A GB 2001659 A GB2001659 A GB 2001659A GB 910641 A GB910641 A GB 910641A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction product
- porcelain
- reactants
- agents
- additives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aminoalkyl silane Chemical compound 0.000 abstract 5
- 239000007795 chemical reaction product Substances 0.000 abstract 5
- 239000004593 Epoxy Substances 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 3
- 239000000919 ceramic Substances 0.000 abstract 3
- 239000000945 filler Substances 0.000 abstract 3
- 229910052573 porcelain Inorganic materials 0.000 abstract 3
- 239000000376 reactant Substances 0.000 abstract 3
- 239000005995 Aluminium silicate Substances 0.000 abstract 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 230000005070 ripening Effects 0.000 abstract 2
- 229910000077 silane Inorganic materials 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 235000019738 Limestone Nutrition 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 150000004645 aluminates Chemical class 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- 230000001680 brushing effect Effects 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 1
- 239000000920 calcium hydroxide Substances 0.000 abstract 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 1
- 239000001175 calcium sulphate Substances 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 239000004570 mortar (masonry) Substances 0.000 abstract 1
- 239000003380 propellant Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 239000004576 sand Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 239000000037 vitreous enamel Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4988—Organosilicium-organic copolymers, e.g. olefins with terminal silane groups
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/64—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/84—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4085—Curing agents not provided for by the groups C08G59/42 - C08G59/66 silicon containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/504—Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The surfaces of ceramic or cementilious articles are coated by brushing, wiping or spraying with the resinous reaction product of an epoxy compound and at least one aminoorganosilicon compound which is a hydrolysable aminoalkyl silane or a siloxane polymer or copolymer obtained therefrom, such as are described and claimed in Specifications 795,061, 874,150, 882,052, 882,052, 992,054, 882,060, 882,061, 882,069 and 882,096, (see Group IV(a)). The reactants are mixed together and may be applied as such or after allowing partial reaction (or ripening) to occur, with or without volatile organic diluents (liquid or solid), propellants and additives (in amount less than 85% by weight of the reaction product), such as antiblush agents, pigments, resins, dyes, fillers and anti-foam agents. The coatings are cured at ambient or elevated temperatures. In examples articles coated with the above reaction products are (1) a porcelain enamelled iron sink, (2) a porcelain sink, (3) an unglazed porcelain dish, (4) a mortar block, sandstone, limestone and an asbestos shingle, (6, 10) a porcelain enamel tray, (7) Terrazzo floor and (8) a Terra cotta tile. Other materials specified are the ceramics made by firing or baking kaolin or kaolin admixed with felspars, quartz, sand, mica, oxides of Fe, Ti, Mg, Ca, K or Na, silicates carbonates or aluminates, and cementilious materials comprising a hardened calcium hydroxide, carbonate or sulphate, alone or with known fillers. Reference has been directed by the Comptroller to Specification 810,284.ALSO:The surfaces of ceramic or cementitious articles are coated with the resinous reaction product of an epoxy compound and at least one amino-organosilicon compound which is a hydrolysable aminoalkyl silane or a siloxane polymer or copolymer obtained therefrom, such as are described and claimed in Specifications 795,061, 874,150, 882,052, 882,054, 882,060, 882,061, 882,069 and 882,096. Numerous examples of epoxy compounds are given. The reactants are mixed together and may be applied as such or after allowing partial reaction (or ripening) to occur, with or without volatile organic diluents (liquid or solid), propellents, and additives such as anti-blush agents, pigments, resins, dyes, fillers and anti-foam agents. The reactants are used, e.g. in amount to provide from 0,05 to 5,0 epoxy equivalents for each amino hydrogen equivalent of the amino-organosilicon compound, and the additives are used in amount of less than 85% by weight of the reaction product. The coatings are cured at ambient or elevated temperatures. Examples are given. Reference has been directed by the Comptroller to Specification 810,284.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74505758A | 1958-06-27 | 1958-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB910641A true GB910641A (en) | 1962-11-14 |
Family
ID=24995077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2001659A Expired GB910641A (en) | 1958-06-27 | 1959-06-11 | Wear-and stain-resistant coated articles |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB910641A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5092929A (en) * | 1973-12-21 | 1975-07-24 | ||
| EP0146803A1 (en) * | 1983-11-28 | 1985-07-03 | Toray Silicone Co., Ltd. | Thermosetting epoxy resin compositions |
| WO2003084898A1 (en) * | 2002-04-05 | 2003-10-16 | Reinhardt Beton Gmbh | Surface-treated cut stone and method for the production thereof |
-
1959
- 1959-06-11 GB GB2001659A patent/GB910641A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5092929A (en) * | 1973-12-21 | 1975-07-24 | ||
| EP0146803A1 (en) * | 1983-11-28 | 1985-07-03 | Toray Silicone Co., Ltd. | Thermosetting epoxy resin compositions |
| WO2003084898A1 (en) * | 2002-04-05 | 2003-10-16 | Reinhardt Beton Gmbh | Surface-treated cut stone and method for the production thereof |
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