GB908191A - Processes and compositions for coating glass fibres - Google Patents
Processes and compositions for coating glass fibresInfo
- Publication number
- GB908191A GB908191A GB15790/60A GB1579060A GB908191A GB 908191 A GB908191 A GB 908191A GB 15790/60 A GB15790/60 A GB 15790/60A GB 1579060 A GB1579060 A GB 1579060A GB 908191 A GB908191 A GB 908191A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- silane
- composition
- vinyl
- anchoring agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/323—Polyesters, e.g. alkyd resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/003—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/20—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics
- E04C2/22—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics reinforced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Mathematical Physics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Architecture (AREA)
- Wood Science & Technology (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
A composition suitable for coating glass fibres or strands, yarns, mats or fabrics made therefrom comprises an aqueous emulsion containing a first polyester resin which cures to give a tough, rigid polymer formed by condensation of a glycol with dicarboxylic acids or ester-forming derivatives thereof consisting at least in part of an unsaturated dicarboxylic acid or ester forming derivative thereof and a second polyester resin which cures to give a flexible polymer formed by condensation of a glycol with dicarboxylic acids or ester-forming derivatives thereof consisting at least in part of a saturated dicarboxylic acid or ester-forming derivative thereof, the first resin being of high viscosity relative to the second. The high viscosity polyester may be the reaction product of diethylene glycol, maleic anhydride and phthalic acid and the low viscosity polyester may be the reaction product of diethylene glycol, maleic anhydride and succinic acid. The treating composition may also contain an anchoring agent for binding the polyesters to glass surfaces, e.g. organo-silicon compounds having attached directly to the silicon atom an aliphatic organic radical which contains less than 8 carbon atoms and preferably has ethylenic unsaturation such as gamma amino propyl triethoxy silane, vinyl triacetoxy silane, vinyl trichloro silane, vinyl tri[(beta-methoxy) ethoxy] silane, allyl dichloro-silane, allyl trichlorosilane and the sodium derivative of vinyl silanol, tri(diethyl ethanolamine hydrochloride) stearyl silane, Werner complex compounds such as stearato chromic chloride and titanium salts such as titanium lactate. Surface active agents mentioned are polyvinyl alcohol, the reaction product of a diamine, ethylene oxide and lauric acid, phenolic or nonionic fatty acid derivatives of polyethylene glycols, the reaction product of tetraethylene pentamine epichlorhydrin and a fatty acid, polyalkylene oxide derivatives of sorbitan mono-oleate or palmitate and a condensate of ethylene oxide with a hydrophobic base formed by condensing propylene oxide with propylene glycol. The hydrocarbon comonomer having an unsaturated carbon-carbon linkage specified is styrene. Specified catalysts are benzoyl peroxide and cobalt naphthenate. The composition which may be adjusted to an acid pH by the addition of acetic, formic, hydrochloric or sulphuric acid preferably contains polyvinyl alcohol and anchoring agent in the weight ratio in the range 1:3 to 1:6. The composition may be applied to the glass fibres as they are formed or on to a mat of the fibres on a conveyer belt. Alternatively the fibres may be treated with the anchoring agent during forming and then treated with the composition without any anchoring agent. On heating to 300 DEG to 400 DEG C. the water evaporates and the two polyesters and the styrene copolymerize. Specifications 719,466, 748,391, 755,957, 769,194 and U.S.A. Specification 2,273,040 are referred to.ALSO:Glass fibres or strands, yarns, mats or fabrics made therefrom are coated with an aqueous emulsion containing a first polyester resin which cures to give a tough, rigid polymer formed by condensation of a glycol with dicarboxylic acids or ester-forming derivatives thereof consisting at least in part of an unsaturated dicarboxylic acid or ester forming derivative thereof and a second polyester resin which cures to give a flexible polymer formed by condensation of a glycol with dicarboxylic acids or ester-forming derivatives thereof consisting at least in part of a saturated dicarboxylic acid or esterforming derivative thereof, the first resin being of high viscosity relative to the second, and then heated, e.g. to 300 DEG -400 DEG F., to obtain a hard protective coating thereon. The high viscosity polyester may be the reaction product of diethylene glycol, maleic anhydride and phthalic acid and the low viscosity polyester may be the reaction product of diethylene glycol, maleic anhydride and succinic acid. The treating composition may also contain an anchoring agent for binding the polyesters to glass surfaces, e.g. organosilicon compounds having attached directly to the silicon atom an aliphatic organic radical which contains less than 8 carbon atoms and preferably has ethylenic unsaturation such as gamma amino propyl triethoxy silane, vinyl triacetoxy silane, vinyl trichloro silane, vinyl tri[(beta-methoxy) ethoxy] silanol, tri(diethyl ethanolamine hydrochlosilane and the sodium derivative of vinyl silanol, tri(diethyl ethanolamine hydrochloride) stearyl silane, Werner complex compounds such as stearato chromic chloride and titanium salts such as titanium lactate, polyvinyl alcohol, surface active agents, e.g. the reaction product of a diamine, ethylene oxide and lauric acid, phenolic or nonionic fatty acid derivatives of polyethylene glycols, polyalkylene oxide derivatives of sorbitan mono-oleate or palmitate and a condensate of ethylene oxide with a hydrophobic base formed by condensing propylene oxide with propylene glycol. The hydrocarbon comonomer having an unsaturated carboncarbon linkage specified is styrene. Specified catalysts are benzoyl peroxide and cobalt naphthenate. The composition which may be adjusted to an acid pH by the addition of acetic, formic, hydrochloric or sulphuric acid preferably contains polyvinyl alcohol and anchoring agent in the weight ratio in the range 1 : 3 to 1 : 6. The composition may be applied to the glass fibres as they are formed or on to a mat of the fibres on a conveyer belt. Alternatively the fibres may be treated with the anchoring agent during forming and then treated with the composition without any anchoring agent. The coated glass fibres or strands, yarns, mats or fabrics made therefrom may be combined with polyester or epoxy resins to produce glass fibre reinforced synthetic resin products. Specifications 719,466, 748,391, 755,957, 769,194 and U.S.A. Specifications 2,273,040 are referred to.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US627147A US2951772A (en) | 1956-12-10 | 1956-12-10 | Treatments for fibrous glass used to reinforce resins |
FR825832A FR1255793A (en) | 1960-04-29 | 1960-04-29 | Glass fiber treatment process for reinforced resins |
GB15790/60A GB908191A (en) | 1960-05-04 | 1960-05-04 | Processes and compositions for coating glass fibres |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB15790/60A GB908191A (en) | 1960-05-04 | 1960-05-04 | Processes and compositions for coating glass fibres |
Publications (1)
Publication Number | Publication Date |
---|---|
GB908191A true GB908191A (en) | 1962-10-17 |
Family
ID=10065505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15790/60A Expired GB908191A (en) | 1956-12-10 | 1960-05-04 | Processes and compositions for coating glass fibres |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB908191A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2433604A1 (en) * | 1978-08-14 | 1980-03-14 | Ppg Industries Inc | GLASS FIBER YARNS, PRIMED, NON-CROSSLINKABLE, COMPATIBLE WITH POLYOLEFINS AND STABLE IN STORAGE |
EP0182750A2 (en) * | 1984-11-23 | 1986-05-28 | Ciba-Geigy Ag | Prepreg fibre material coated with synthetic material and process for preparing such a precursor material |
EP2511324A1 (en) * | 2011-04-14 | 2012-10-17 | Universiteit van Amsterdam | Composite material comprising synthetic filler and specific polymer |
-
1960
- 1960-05-04 GB GB15790/60A patent/GB908191A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2433604A1 (en) * | 1978-08-14 | 1980-03-14 | Ppg Industries Inc | GLASS FIBER YARNS, PRIMED, NON-CROSSLINKABLE, COMPATIBLE WITH POLYOLEFINS AND STABLE IN STORAGE |
EP0182750A2 (en) * | 1984-11-23 | 1986-05-28 | Ciba-Geigy Ag | Prepreg fibre material coated with synthetic material and process for preparing such a precursor material |
EP0182750A3 (en) * | 1984-11-23 | 1988-09-21 | Ciba-Geigy Ag | Prepreg fibre material coated with synthetic material and process for preparing such a precursor material |
EP2511324A1 (en) * | 2011-04-14 | 2012-10-17 | Universiteit van Amsterdam | Composite material comprising synthetic filler and specific polymer |
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