GB904549A - Preparation of epoxy ethers and formation of cured resinous products therefrom - Google Patents

Preparation of epoxy ethers and formation of cured resinous products therefrom

Info

Publication number
GB904549A
GB904549A GB1548659A GB1548659A GB904549A GB 904549 A GB904549 A GB 904549A GB 1548659 A GB1548659 A GB 1548659A GB 1548659 A GB1548659 A GB 1548659A GB 904549 A GB904549 A GB 904549A
Authority
GB
United Kingdom
Prior art keywords
epoxy
vinyl
polyether
cyclohexane
cured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1548659A
Inventor
Victor Francis George Cooke
James Lincoln
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Priority to GB1548659A priority Critical patent/GB904549A/en
Publication of GB904549A publication Critical patent/GB904549A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Glass Compositions (AREA)

Abstract

A cured epoxy polyether resin is made by mixing an epoxy polyether, obtained by epoxidizing a polyether of a vinyl epoxy cyclohexane or a copolyether of a vinyl epoxycyclohexane and an alkylene oxide, with a polyamine, a polycarboxylic acid or anhydride, a polyhydric phenol, a polyhydric alcohol or a polyamide, and causing or allowing the mixture to harden to form a cross-linked resinous product. In examples, (1) an epoxidized copolymer of 1-vinyl-3,4-epoxycyclohexane and propylene oxide is mixed with diethylene triamine and cured at 100 DEG C. for 40 minutes; a 50% solution of the epoxy polyether in butanol/toluene mixture is treated with diethylene triamine and the solution cast as a film on glass and cured at 100 DEG C.; (2) an epoxy polyether of 1-vinyl-3,4-epoxy-cyclohexane is cured separately with diethylene triamine, with a polyamide based on a dimerized vegetable oil acid and ethylene diamine, and with diaminodiphenyl methane; (3) an epoxy polyether of 1-vinyl-3,4-epoxycyclohexane is cured with triethylene tetramine.ALSO:Epoxy polyether compounds are made by epoxidising a polyether of a vinyl epoxy cyclohexane or a copolyether of a vinyl epoxy cyclohexane and an alkylene oxide. The epoxidation may be effected using a peracid, preferably peracetic acid, at ordinary temperatures but preferably at 30 DEG C. to 50 DEG C. The polether starting material may be made from the vinyl epoxy cyclohexane by heating in the presence of a strong alkali catalyst, e.g. potassium hydroxide, and 5 to 10 mol % of a glycol, polyol, an organic carboxylic acid, an amine, or an anhydride of a di or polycarboxylic acid. The reaction is conveniently carried out at temperatures of 100 DEG C. or over, e.g. 110 DEG to 140 DEG C. under a reflux condenser for 10 to 15 hours in an inert atmosphere such as nitrogen. Similar conditions may be used for copolyethers from vinyl epoxycyclohexane and an alkylene oxide, such as propylene oxide. Examples describe the preparation and epoxidation of the polyether of 1-vinyl-3,4-epoxy - cyclohexane and its copolyether with propylene oxide.
GB1548659A 1959-05-06 1959-05-06 Preparation of epoxy ethers and formation of cured resinous products therefrom Expired GB904549A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1548659A GB904549A (en) 1959-05-06 1959-05-06 Preparation of epoxy ethers and formation of cured resinous products therefrom

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1548659A GB904549A (en) 1959-05-06 1959-05-06 Preparation of epoxy ethers and formation of cured resinous products therefrom

Publications (1)

Publication Number Publication Date
GB904549A true GB904549A (en) 1962-08-29

Family

ID=10059982

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1548659A Expired GB904549A (en) 1959-05-06 1959-05-06 Preparation of epoxy ethers and formation of cured resinous products therefrom

Country Status (1)

Country Link
GB (1) GB904549A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0150850A2 (en) * 1984-01-30 1985-08-07 Daicel Chemical Industries, Ltd. Polyether compounds and processes for production thereof
JPS60161940A (en) * 1983-12-27 1985-08-23 Daicel Chem Ind Ltd Polyether compound
JPS60161939A (en) * 1983-12-27 1985-08-23 Daicel Chem Ind Ltd Production of polyether compound
EP0237255A2 (en) * 1986-03-07 1987-09-16 Hitachi, Ltd. Curable resin compositions and semiconductor devices coated and sealed with the same
EP0303759A2 (en) * 1987-08-17 1989-02-22 Daicel Chemical Industries, Ltd. Polyether compounds, epoxy resins and processes for production thereof
EP0331183A2 (en) * 1988-03-03 1989-09-06 Daicel Chemical Industries, Ltd. Compositions of polyether compounds, epoxy compounds and processes for production thereof
US5191027A (en) * 1989-05-12 1993-03-02 Daicel Chemical Industries, Ltd. Composition comprising an epoxy compound
EP0540027A2 (en) * 1991-10-31 1993-05-05 Daicel Chemical Industries, Ltd. Compositions, expoxidized compositions, a heat-curable resin composition, an epoxy resin composition, radically polymerized composition, a curable resin composition and a polymer having epoxy groups
WO2001072868A1 (en) * 2000-03-24 2001-10-04 Siemens Aktiengesellschaft Halogen free epoxy resin having a defined molecule mass
CN113003647A (en) * 2021-03-25 2021-06-22 深圳市南峰水处理服务有限公司 Environment-friendly degerming composite water treatment agent and preparation method thereof

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60161940A (en) * 1983-12-27 1985-08-23 Daicel Chem Ind Ltd Polyether compound
JPS60161939A (en) * 1983-12-27 1985-08-23 Daicel Chem Ind Ltd Production of polyether compound
JPH0474343B2 (en) * 1983-12-27 1992-11-26
EP0150850A2 (en) * 1984-01-30 1985-08-07 Daicel Chemical Industries, Ltd. Polyether compounds and processes for production thereof
EP0150850A3 (en) * 1984-01-30 1987-01-21 Daicel Chemical Industries, Ltd. Polyester compounds, epoxy resins, epoxy resin compositions, and processes for production thereof
EP0237255A2 (en) * 1986-03-07 1987-09-16 Hitachi, Ltd. Curable resin compositions and semiconductor devices coated and sealed with the same
EP0237255A3 (en) * 1986-03-07 1990-05-30 Hitachi, Ltd. Curable resin compositions and semiconductor devices coated and sealed with the same
EP0303759A2 (en) * 1987-08-17 1989-02-22 Daicel Chemical Industries, Ltd. Polyether compounds, epoxy resins and processes for production thereof
US4841017A (en) * 1987-08-17 1989-06-20 Daicel Chemical Industries, Ltd. Polyether compounds, epoxy resins and processes for production thereof
EP0303759A3 (en) * 1987-08-17 1989-07-19 Daicel Chemical Industries, Ltd. Polyether compounds, epoxy resins and processes for production thereof
EP0331183A3 (en) * 1988-03-03 1991-06-12 Daicel Chemical Industries, Ltd. Compositions of polyether compounds, epoxy compounds and processes for production thereof
US5122586A (en) * 1988-03-03 1992-06-16 Daicel Chemical Industries, Ltd. Compositions of polyether compounds, epoxy compounds and processes for production thereof based on 4-vinylcyclohexene-1-oxide
EP0331183A2 (en) * 1988-03-03 1989-09-06 Daicel Chemical Industries, Ltd. Compositions of polyether compounds, epoxy compounds and processes for production thereof
US5191027A (en) * 1989-05-12 1993-03-02 Daicel Chemical Industries, Ltd. Composition comprising an epoxy compound
US5494977A (en) * 1991-01-31 1996-02-27 Daicel Chemical Industries, Ltd. Compositions, epoxized compositions, a heat curable resin composition, an epoxy resin composition, radically polymerized compositions, a curable resin composition and a polymer having epoxy groups
EP0540027A2 (en) * 1991-10-31 1993-05-05 Daicel Chemical Industries, Ltd. Compositions, expoxidized compositions, a heat-curable resin composition, an epoxy resin composition, radically polymerized composition, a curable resin composition and a polymer having epoxy groups
EP0540027A3 (en) * 1991-10-31 1995-06-07 Daicel Chem
EP0859021A2 (en) * 1991-10-31 1998-08-19 Daicel Chemical Industries, Ltd. Epoxidised compositions
EP0859021A3 (en) * 1991-10-31 1998-11-11 Daicel Chemical Industries, Ltd. Epoxidised compositions
WO2001072868A1 (en) * 2000-03-24 2001-10-04 Siemens Aktiengesellschaft Halogen free epoxy resin having a defined molecule mass
CN113003647A (en) * 2021-03-25 2021-06-22 深圳市南峰水处理服务有限公司 Environment-friendly degerming composite water treatment agent and preparation method thereof
CN113003647B (en) * 2021-03-25 2022-08-26 深圳市南峰水处理服务有限公司 Environment-friendly degerming composite water treatment agent and preparation method thereof

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