GB899999A - Polymer-containing compositions - Google Patents

Polymer-containing compositions

Info

Publication number
GB899999A
GB899999A GB4144358A GB4144358A GB899999A GB 899999 A GB899999 A GB 899999A GB 4144358 A GB4144358 A GB 4144358A GB 4144358 A GB4144358 A GB 4144358A GB 899999 A GB899999 A GB 899999A
Authority
GB
United Kingdom
Prior art keywords
styrene
polymer
weight
methyl
rubbery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4144358A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Monsanto Chemical Co
Original Assignee
Monsanto Chemicals Ltd
Monsanto Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Chemicals Ltd, Monsanto Chemical Co filed Critical Monsanto Chemicals Ltd
Publication of GB899999A publication Critical patent/GB899999A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Polymer blends comprise (i) a rigid styrene polymer in admixture with (ii) a graft copolymer prepared by polymerizing styrene in an <PICT:0899999/IV (a)/1> aqueous dispersion of a rubbery diene polymer having a brittle temperature of 0 DEG C. or lower and consisting of: (a) 50 to 100% by weight of butadiene and/or a methyl substituted conjugated 1,3-diene, e.g. isoprene, (b) 50-0% by weight of one or more monovinylidene aromatic hydrocarbons, e.g. styrene, alphamethyl styrene or vinyl toluene, (c) up to 10% by weight of other polymerizable vinylidene monomers, e.g. acrylonitrile or acrylic or methacrylic esters, and (d) up to 1% by weight of a monomer containing a plurality of non-conjugated ethylenic linkages, e.g. divinyl benzene, the amount of dispersed styrene being such that the composition of the resulting graft polymer lies within the area bounded by curve A in Fig. 1, and the polymerization being carried out in the substantial absence of emulsifying agents other than those present during the production of the rubbery polymer, the proportions of polymers (i) and (ii) being such that the rubbery polymer employed in the production of (ii) is present in an amount corresponding to 5-40% by weight of the mixture. The rigid styrene polymer may be polystyrene or a copolymer of styrene containing up to 40% of one or more other monomers, e.g. alpha-methyl styrene, butadiene, isoprene, and the amides, nitriles and methyl, ethyl and butyl esters of acrylic and methacrylic acids.
GB4144358A 1957-12-26 1958-12-23 Polymer-containing compositions Expired GB899999A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70519757A 1957-12-26 1957-12-26

Publications (1)

Publication Number Publication Date
GB899999A true GB899999A (en) 1962-06-27

Family

ID=24832450

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4144358A Expired GB899999A (en) 1957-12-26 1958-12-23 Polymer-containing compositions

Country Status (1)

Country Link
GB (1) GB899999A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0155899A2 (en) * 1984-03-22 1985-09-25 The Goodyear Tire & Rubber Company Binder for chemical agents
EP0265142A2 (en) * 1986-10-21 1988-04-27 Rohm And Haas Company Core-shell polymers and compositions containing core-shell polymers

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0155899A2 (en) * 1984-03-22 1985-09-25 The Goodyear Tire & Rubber Company Binder for chemical agents
EP0155899A3 (en) * 1984-03-22 1987-07-15 The Goodyear Tire & Rubber Company Binder for chemical agents
EP0265142A2 (en) * 1986-10-21 1988-04-27 Rohm And Haas Company Core-shell polymers and compositions containing core-shell polymers
EP0265142A3 (en) * 1986-10-21 1990-03-07 Rohm And Haas Company Core-shell polymers and compositions containing core-shell polymers

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