GB898651A - Polymers containing polyamide-acid recurring units and their production - Google Patents
Polymers containing polyamide-acid recurring units and their productionInfo
- Publication number
- GB898651A GB898651A GB3181159A GB3181159A GB898651A GB 898651 A GB898651 A GB 898651A GB 3181159 A GB3181159 A GB 3181159A GB 3181159 A GB3181159 A GB 3181159A GB 898651 A GB898651 A GB 898651A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diamine
- bis
- dimethyl
- tetracarboxylic
- phenylene diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1003—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1003—Preparatory processes
- C08G73/1007—Preparatory processes from tetracarboxylic acids or derivatives and diamines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyamides (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
Polyamide-acids having the recurring unit:- <FORM:0898651/IV (a)/1> or <FORM:0898651/IV (a)/2> where R is a tetravalent radical containing at least 2 carbon atoms, no more than 2 carbonyl groups of each polyamide-acid unit being attached to any one carbon atom of said tetravalent radical, R1 is a divalent radical containing at least 2 carbon atoms, the amide groups of adjacent polyamide-acid units each attached to separate carbon atoms of said divalent radical, said polyamide-acid having an inherent viscosity measured at 30 DEG C. at a concentration of 0,5% by weight of the polymer are made by reacting at least one diamine of the formula H2N-R1-NH2 with at least one tetracarboxylic acid dianhydride having the structural formula <FORM:0898651/IV (a)/3> in an organic solvent for the product and at least one of the reactants whose functional groups do not react with either of the reactants to a greater extent than the reactants do with each other, under substantially anhydrous conditions at a temperature below 60 DEG C. The polyamide-acid may be separated from the reaction mixture by precipitating in a non-solvent such as cyclohexane, dioxane or benzene. Many diamines are specified, examples being m-phenylene diamine, p-phenylene diamine, benzidine, hexamethylene diamine, 3-methoxyhexamethylene diamine, 2:11-diaminododecane and piperazine. Specified tetracarboxylic acid dianhydrides are pyromellitic, 2,3,6,7-naphthalene tetracarboxylic, 3,31,4,41-diphenyl tetracarboxylic, 1,2,5,6-naphthalene tetracarboxylic, 2,21,3,31-diphenyl tetracarboxylic, 2,2-bis(3,4-dicarboxyphenyl)propane, 3,4-dicarboxyphenyl sulphone, perylene 3,4,9,10-tetracarboxylic, bis(3,4-dicarboxyphenyl) ether and ethylene tetracarboxylic dianhydride. Specified solvents are N,N-dimethyl formamide, N, N-dimethyl acetamide, N,N-diethyl formamide, N,N-diethylacetamide, N,N-dimethyl methoxy acetamide, N-methyl caprolactam, dimethyl sulphoxide, N-methyl-2-pyrrolidone, tetramethylene urea, pyridine, dimethyl sulphone, hexamethyl phosphoramide, tetramethylene sulphone, formamide, N-methyl formamide and N-acetyl-2-pyrrolidone alone or in combination with benzene, benzonitrile, dioxane, butyrolactone, xylene, toluene and cyclohexane. In the Examples:- (1), (7), (11) to (13), (22) and (23) m-phenylene diamine; (2) p-phenylene diamine; (3) and (14) benzidine; (4) m-phenylene diamine, p-phenylene diamine and benzidine; (5) 2,2-bis(4-aminophenyl)propane; (6) m-phenylene diamine and bis(4-aminophenyl)methane; (8) bis(4-aminophenyl) methane; (9) m-phenylene diamine and hexamethylene diamine; (10) 4,41-diaminodiphenyl methane and hexamethylene diamine; (15) m-xylylene diamine; (16) 2:11-dodecane diamine; (17) hexamethylene diamine; (18) 4,4-dimethylheptamethylene diamine; (19) and (20) bis(p-aminophenyl) ether; (21) 4,41-diaminodiphenyl methane; (24) diaminodiphenyl sulphide; (25) bis(4-aminophenyl) sulphone and 26) 4,41-diaminodiphenyl ether are reacted with:- (1) to (11), (15) to (19) and (21) to (26) pyromellitic dianhydride; (12) pyromellitic dianhydride and phthalic anhydride; (13), (14) and (25) 2,2-bis(dicarboxyphenyl) propane in the presence of:- (1), (2), (12) to (16), (19) and (26) N:N-dimethyl acetamide; (3) to (11), (17), (18), (21), (22) and (25) N:N-dimethyl formamide (20) pyridine; (23) dimethyl sulphoxide and (24) pyridine and dimethyl formamide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US76196858A | 1958-09-19 | 1958-09-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB898651A true GB898651A (en) | 1962-06-14 |
Family
ID=25063747
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3181159A Expired GB898651A (en) | 1958-09-19 | 1959-09-18 | Polymers containing polyamide-acid recurring units and their production |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH424259A (en) |
DE (2) | DE1420706C3 (en) |
DK (1) | DK107258C (en) |
GB (1) | GB898651A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3349061A (en) * | 1964-01-10 | 1967-10-24 | Du Pont | Amide-ester isomers |
US4470944A (en) * | 1982-02-23 | 1984-09-11 | Toray Industries, Inc. | Process for producing an aromatic polyimide film |
EP0859023A2 (en) * | 1997-02-15 | 1998-08-19 | Dr.Beck & Co. Aktiengesellschaft | Mixtures of solutions of polyamidocarboxylic acids and solutions of polyimid precusors |
DE102014104223A1 (en) | 2014-03-26 | 2015-10-01 | Elantas Italia S.R.L. | New solvent for polyamide-imides and polyimides |
WO2019038154A1 (en) | 2017-08-23 | 2019-02-28 | Heraeus Noblelight Gmbh | Method and device for producing a polyimide coating on a substrate |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4269968A (en) * | 1979-11-13 | 1981-05-26 | International Business Machines Corporation | Synthesis of polyamic acid |
-
1959
- 1959-09-17 DE DE19591420706 patent/DE1420706C3/en not_active Expired
- 1959-09-17 DE DE19591795611 patent/DE1795611C3/en not_active Expired
- 1959-09-18 GB GB3181159A patent/GB898651A/en not_active Expired
- 1959-09-18 CH CH7836059A patent/CH424259A/en unknown
- 1959-09-18 DK DK334859A patent/DK107258C/en active
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3349061A (en) * | 1964-01-10 | 1967-10-24 | Du Pont | Amide-ester isomers |
US4470944A (en) * | 1982-02-23 | 1984-09-11 | Toray Industries, Inc. | Process for producing an aromatic polyimide film |
EP0859023A2 (en) * | 1997-02-15 | 1998-08-19 | Dr.Beck & Co. Aktiengesellschaft | Mixtures of solutions of polyamidocarboxylic acids and solutions of polyimid precusors |
EP0859023A3 (en) * | 1997-02-15 | 1999-04-21 | Dr.Beck & Co. Aktiengesellschaft | Mixtures of solutions of polyamidocarboxylic acids and solutions of polyimid precusors |
US6074757A (en) * | 1997-02-15 | 2000-06-13 | Schenectady Europe Gmbh | Mixtures of solutions of polyamidocarboxylic acids and solutions of polyimide-forming starting materials |
DE102014104223A1 (en) | 2014-03-26 | 2015-10-01 | Elantas Italia S.R.L. | New solvent for polyamide-imides and polyimides |
WO2015144663A1 (en) | 2014-03-26 | 2015-10-01 | Elantas Italia S. R. L. | Novel solvent for polyamide imides and polyimides |
WO2019038154A1 (en) | 2017-08-23 | 2019-02-28 | Heraeus Noblelight Gmbh | Method and device for producing a polyimide coating on a substrate |
Also Published As
Publication number | Publication date |
---|---|
DK107258C (en) | 1967-05-08 |
DE1420706A1 (en) | 1968-10-10 |
DE1795611C3 (en) | 1975-11-06 |
DE1795611A1 (en) | 1972-01-27 |
DE1420706B2 (en) | 1971-08-19 |
DE1795611B2 (en) | 1975-03-06 |
CH424259A (en) | 1966-11-15 |
DE1420706C3 (en) | 1974-05-09 |
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