GB895503A - Sulfur recovery process - Google Patents

Sulfur recovery process

Info

Publication number
GB895503A
GB895503A GB27851/58A GB2785158A GB895503A GB 895503 A GB895503 A GB 895503A GB 27851/58 A GB27851/58 A GB 27851/58A GB 2785158 A GB2785158 A GB 2785158A GB 895503 A GB895503 A GB 895503A
Authority
GB
United Kingdom
Prior art keywords
aqueous solution
organic solvent
water
absorbed
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27851/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FRANCIS MARK TOWNSEND
Original Assignee
FRANCIS MARK TOWNSEND
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FRANCIS MARK TOWNSEND filed Critical FRANCIS MARK TOWNSEND
Priority to GB27851/58A priority Critical patent/GB895503A/en
Priority to DET15635A priority patent/DE1110144B/en
Priority to FR1212350D priority patent/FR1212350A/en
Priority to US802980A priority patent/US3170766A/en
Publication of GB895503A publication Critical patent/GB895503A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/05Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21CNUCLEAR REACTORS
    • G21C3/00Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
    • G21C3/02Fuel elements
    • G21C3/04Constructional details
    • G21C3/16Details of the construction within the casing
    • G21C3/20Details of the construction within the casing with coating on fuel or on inside of casing; with non-active interlayer between casing and active material with multiple casings or multiple active layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Plasma & Fusion (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

Hydrogen sulphide and water vapour are removed from a gaseous mixture by contacting with sulphur dioxide in a 90-99% aqueous solution of an inert, neutral, stable, organic solvent having a vapour pressure not more than 10 mm's. Hg., and a solubility in water not less than 2%, at 20 DEG C., and containing at least 2 atoms of at least one element other than C and H, at least one of which is O or S, and not more than 2 vicinal OH radicals. The water is absorbed by the solution and S particles are precipitated. A number of organic solvents are specified including the glycols, e.g. diethylene, triethylene, or propylene glycol, or the ether or ester derivatives thereof. The H2S-containing gases, e.g. sour natural gas, may be reacted with SO2 in the presence of the aqueous solution of the organic solvent in various ways, e.g. the SO2 may be dispersed in the sour natural gas in an absorption tower and the combined gaseous mixture absorbed in a descending stream of the aqueous solution of organic solvent, or the SO2 may be dissolved in the aqueous solution of organic solvent and the resulting solution, which should preferably contain less than 10% wt. of SO2, is contacted with a stream of sour gas ascending the absorption tower, or various combinations of such processes may be employed. The Specification refers to several plants for the removal of H2S from gaseous mixtures in detail with reference to accompanying drawings. The suspension of sulphur may be agglomerated by heating to melt the S, and the S is removed from the spent aqueous solution by decantation. Spent aqueous solution, after regeneration to remove SO2 and excess water absorbed, is recycled to the process. The SO2 may be formed by oxidizing one-third of the H2S in the gas mixture.
GB27851/58A 1958-08-29 1958-08-29 Sulfur recovery process Expired GB895503A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB27851/58A GB895503A (en) 1958-08-29 1958-08-29 Sulfur recovery process
DET15635A DE1110144B (en) 1958-08-29 1958-09-16 Process for removing hydrogen sulphide from gas mixtures
FR1212350D FR1212350A (en) 1958-08-29 1958-10-09 Process for removing hydrogen sulfide from gas mixtures
US802980A US3170766A (en) 1958-08-29 1959-03-30 Sulfur recovery apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB27851/58A GB895503A (en) 1958-08-29 1958-08-29 Sulfur recovery process

Publications (1)

Publication Number Publication Date
GB895503A true GB895503A (en) 1962-05-02

Family

ID=10266337

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27851/58A Expired GB895503A (en) 1958-08-29 1958-08-29 Sulfur recovery process

Country Status (2)

Country Link
FR (1) FR1212350A (en)
GB (1) GB895503A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2532292A2 (en) * 1982-08-25 1984-03-02 Raffinage Cie Francaise PROCESS FOR REMOVING HYDROGEN SULFIDE FROM A GASEOUS MIXTURE
FR2928563B1 (en) * 2008-03-14 2011-12-30 Total Sa PROCESS FOR DRYING AND DEMERCAPTANIZING GASEOUS MIXTURES
CN115304033B (en) * 2022-06-27 2023-09-29 江西理工大学 Process for recovering elemental sulfur from zinc oxygen pressure leaching slag

Also Published As

Publication number Publication date
FR1212350A (en) 1960-03-23

Similar Documents

Publication Publication Date Title
SE8505463D0 (en) SET TO SELECTIVELY REMOVE WHEAT SULFIDE FROM GAS MIXTURES, WHICH ALSO INCLUDE CARBON Dioxide
GB1403638A (en) Method of removing mercury from gases contaminated therewith
IE39138L (en) Recovering sulphur from gases
SE8702301D0 (en) PROCEDURE FOR SELECTIVELY REMOVING GAS SULFUR ASSOCIATIONS, WHICH ALSO CONTAIN CARBON Dioxide
US3516793A (en) Process for purifying sulfide containing gases and the recovery of sulfur therefrom
SA521430248B1 (en) Method and Apparatus for Treating A Sulfur Dioxide Containing Stream by Hydrogen Sulfide in Aqueous Conditions
ES437900A1 (en) Purification of sulphur-containing waste gases with hydrogen peroxide
US3363989A (en) Method of removing sulfur containing gases from gaseous mixtures and recovering sulfur therefrom
GB895503A (en) Sulfur recovery process
US3882222A (en) Process for purifying a gas containing oxygenated sulfur compounds and recovering sulfur using ammonia liquors
SE7504704L (en) WAY TO EXTRACT SULFUR FROM SULFUR DIOXIDE-RICH ABSORBENT SOLUTIONS.
CA2232962A1 (en) Natural gas treatment process
US3794710A (en) Gas desulfurization
US3875295A (en) Process for withdrawing hydrogen sulfide from an industrial gas with sulfur production
US4267162A (en) Process and apparatus for the exploitation of the sulfur compounds contained in gases containing oxygen and a high water vapor content
GB1087272A (en) A method of removing hydrogen sulphide from gas mixtures containing the same
SE8503032D0 (en) METHOD FOR REMOVING AND RECOVERING SULPHUR IN ELEMENTAL FORM FROM GASES CONTAINING SULPHUR DIOXIDE OR SULPHUR DIOXIDE AND HYDROGEN SULPHIDE
EP0082579A1 (en) Self-regulating process for removal of hydrogen sulfide from gases
GB811058A (en) Method of producing concentrated sulphuric acid and oleum from gases containing hydrogen sulphide
JPS602896B2 (en) Method for removing mercury from smelting exhaust gas
DE3370765D1 (en) Process for the removal of co2 and/or h2s from gases
DE3070687D1 (en) Method for removing hydrogen sulfide from gas streams
SU581618A1 (en) Absorbent for drying and purification of hydrocarbon gases from sulphurous compounds
US3773893A (en) Process for removing sulfur dioxide from gas streams using molten thiocyanates
GB947640A (en) Improvements in or relating to the removal of sulphur compounds from waste gases