GB882005A - Preparation of organo-metallic compounds - Google Patents

Preparation of organo-metallic compounds

Info

Publication number
GB882005A
GB882005A GB12771/60A GB1277160A GB882005A GB 882005 A GB882005 A GB 882005A GB 12771/60 A GB12771/60 A GB 12771/60A GB 1277160 A GB1277160 A GB 1277160A GB 882005 A GB882005 A GB 882005A
Authority
GB
United Kingdom
Prior art keywords
organo
grignard reagent
metal
anode
magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB12771/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ChampionX LLC
Original Assignee
Nalco Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Chemical Co filed Critical Nalco Chemical Co
Publication of GB882005A publication Critical patent/GB882005A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/13—Organo-metallic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

882,005. Making organo-metallic compounds, electrolytically. NALCO CHEMICAL CO. April 11, 1960 [May 6, 1959], No. 12771/60. Class 41. Organo-metallic compounds are made by electrolysis of a solution of a Grignard reagent in an anhydrous solvent using a sacrificial metal anode, and adding an organic halide of the same organic radical as the Grignard reagent, whereby there is formed a metal compound from the anode linked to hydrocarbon radicals. For example, a lead anode immersed in ethyl magnesium chloride dissolved in a solvent, e.g. diethyl or dibutyl glycol ether tri-hexylamine or pyridine, with added ethyl chloride forms lead tetraethyl which is separated from the electrolyte by distillation. Any magnesium metal formed at the inert cathode is reconverted to Grignard reagent by the ethyl chloride present. Voltage applied is 12 to 14V increasing to 24V, and at 35‹ to 60‹ C. or higher. Organo-metal compounds include methyl up to butyl and higher homologues; phenyl, and benzyl compounds of Pb, Ca, Zn, Hg, Mn, La, Te, Se, Tl, As and Bi. Magnesium halide also formed is removed to prevent resin formation, by adding dioxane or pyridine which forms complex insoluble substances. The process may be effected under pressure where volatile solvents are present.
GB12771/60A 1959-05-06 1960-04-11 Preparation of organo-metallic compounds Expired GB882005A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US811262A US3007858A (en) 1959-05-06 1959-05-06 Preparation of organo metallic compounds

Publications (1)

Publication Number Publication Date
GB882005A true GB882005A (en) 1961-11-08

Family

ID=25206049

Family Applications (1)

Application Number Title Priority Date Filing Date
GB12771/60A Expired GB882005A (en) 1959-05-06 1960-04-11 Preparation of organo-metallic compounds

Country Status (6)

Country Link
US (1) US3007858A (en)
BE (1) BE590453A (en)
DE (1) DE1171919B (en)
GB (1) GB882005A (en)
NL (1) NL251295A (en)
SE (1) SE306532B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3391067A (en) * 1959-05-06 1968-07-02 Nalco Chemical Co Electrolytic process for the preparation of mixed organic lead compounds and electrolyte therefor
US3391066A (en) * 1959-05-06 1968-07-02 Nalco Chemical Co Preparation of organic compounds of metals
LU39891A1 (en) * 1960-03-15 Merck & Co Inc
DE1141461B (en) * 1960-09-30 1962-12-20 Siemens Ag Method and device for the electrolytic production of high-purity gallium
US3234112A (en) * 1961-03-21 1966-02-08 Nalco Chemical Co Process of producing organic lead compounds
US3180810A (en) * 1961-07-31 1965-04-27 Standard Oil Co Electrolytic cell and method of operation
US3197392A (en) * 1961-11-30 1965-07-27 Du Pont Process for preparing organometal compounds
US3359291A (en) * 1964-10-05 1967-12-19 Nalco Chemical Co Purification of tetraalkyl lead
US3394197A (en) * 1964-10-12 1968-07-23 Ethyl Corp Preparation of divinylic magnesium compounds
US3572932A (en) * 1969-08-14 1971-03-30 Nalco Chemical Co Method of measuring active grignard concentration of a grignard electrolyte
US3925169A (en) * 1973-03-19 1975-12-09 Nalco Chemical Co Active grignard electrode and process
US4002548A (en) * 1973-03-19 1977-01-11 Nalco Chemical Company Active Grignard electrode

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE14891C (en) * A. MONCHABLON in Paris Machine for the production of felted yarn

Also Published As

Publication number Publication date
NL251295A (en)
SE306532B (en) 1968-12-02
US3007858A (en) 1961-11-07
BE590453A (en)
DE1171919B (en) 1964-06-11

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