GB876588A - Carbamic acid esters and means for producing the same - Google Patents
Carbamic acid esters and means for producing the sameInfo
- Publication number
- GB876588A GB876588A GB1981360A GB1981360A GB876588A GB 876588 A GB876588 A GB 876588A GB 1981360 A GB1981360 A GB 1981360A GB 1981360 A GB1981360 A GB 1981360A GB 876588 A GB876588 A GB 876588A
- Authority
- GB
- United Kingdom
- Prior art keywords
- trichloromethyl
- pent
- acid esters
- carbamic acid
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises carbamic acid esters of 2-trichloromethyl-pent-4-yn-2-ol and 3-trichloromethyl-pent-4-yn-3-ol and the preparation thereof by reacting the appropriate trichloromethyl-pentynol with an alkali metal, an alkali metal amide, an alkali metal hydride or an alkaline-earth metal hydride and treating the resulting metal salt successively with phosgene, to provide the corresponding chloroformate, and ammonia. The products are sedatives and hypnotics. 3-Trichloromethyl-pent-4-yn-3-ol is prepared by reacting 1,1,1-trichlorobutan-2-one with ethynyl magnesium bromide. 1,1,1-Trichlorobutan-2-one is prepared by reacting ethyl magnesium bromide and trichlorocetyl chloride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1981360A GB876588A (en) | 1960-06-03 | 1960-06-03 | Carbamic acid esters and means for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1981360A GB876588A (en) | 1960-06-03 | 1960-06-03 | Carbamic acid esters and means for producing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB876588A true GB876588A (en) | 1961-09-06 |
Family
ID=10135661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1981360A Expired GB876588A (en) | 1960-06-03 | 1960-06-03 | Carbamic acid esters and means for producing the same |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB876588A (en) |
-
1960
- 1960-06-03 GB GB1981360A patent/GB876588A/en not_active Expired
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