GB875796A - Emulsion polymerisation apparatus - Google Patents

Emulsion polymerisation apparatus

Info

Publication number
GB875796A
GB875796A GB20990/56A GB2099056A GB875796A GB 875796 A GB875796 A GB 875796A GB 20990/56 A GB20990/56 A GB 20990/56A GB 2099056 A GB2099056 A GB 2099056A GB 875796 A GB875796 A GB 875796A
Authority
GB
United Kingdom
Prior art keywords
inlet
rotating member
vessel
series
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20990/56A
Inventor
Francis John Long
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB20990/56A priority Critical patent/GB875796A/en
Publication of GB875796A publication Critical patent/GB875796A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/93Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with rotary discs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1806Stationary reactors having moving elements inside resulting in a turbulent flow of the reactants, such as in centrifugal-type reactors, or having a high Reynolds-number
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/19Stirrers with two or more mixing elements mounted in sequence on the same axis
    • B01F27/191Stirrers with two or more mixing elements mounted in sequence on the same axis with similar elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094Jackets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/185Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

<PICT:0875796/IV (a)/1> A mixing apparatus for polymerizing emulsions of polymer components is provided with a vertically mounted rotating member, preferably a cone, cylinder or a series of discs mounted on a shaft, the co-acting liquid components being discharged close to the surface of the rotating member, at the top and bottom respectively. The monomer fed into the bottom, is formed into fine particles by the rotating member and rises in counter-current with the emulsion forming and polymerizing components flowing downwards. A suitable apparatus consists of a jacketted vessel 1, having a central shaft 5 on which a series of spaced discs are mounted. An inlet for the monomer at 6 discharges adjacent the lowest disc, and an inlet 7 for the second component is similarly disposed against the top disc. The polymer is discharged at 8. A reflux condenser is mounted at 9. The apparatus may be operated at normal, lower or higher pressures. The dimensions and stirring speed are co-related, e.g. with a cylindrical stirrer 4in. diameter and vessel 6in. diameter stirring speed should be 440-880 r.p.m. In examples, monomers polymerized include styrene, vinyl acetate, vinyl and vinylidene p chloride, acrylonitrile, esters of acrylic acid or methacrylic acid, olefines, and co-polymer mixtures, e.g. styrene-butadiene, methyl methacrylate-butatiene. In operation, vessel 1 is charged with an aqueous mixture containing ammonium polymethacrylate and the sodium salt of sulphonated methyl oleate, heated to 80 DEG C. and stirred at 600 r.p.m. An aqueous mixture of sulphonated methyl oleate and hydrogen peroxide passes through the top inlet 7, and methyl methacrylate monomer through the bottom inlet 6. After 1 hour a further addition of hydrogen peroxide is admitted through inlet 7. After a further few hours a creamy emulsion containing 48% of solids flows through discharge 8.ALSO:A mixing apparatus for polymerizing emulsions of polymer components is provided with a vertically mounted rotating member, preferably a cylinder, cone or series of discs mounted on a shaft, the co-acting liquid components being discharged close to the surface of the rotating member, one at the top thereof, and the other at the bottom. The monomer fed into the bottom, is formed into fine particles by the rotating member, and rises in counter-current with emulsion forming and polymerizing component flowing downwards. At the steady state "Taylor" rings of liquid are formed in vertical series, as segmented layers promoting mass transfer of liquid between <PICT:0875796/III/1> the segments. A suitable apparatus consists of a jacketted vessel 1, having a central axis 5 on which a series of spaced discs 2 are mounted. An inlet for the monomer at 6 discharges adjacent the lowest disc, and an inlet 7 for the second component is similarly disposed against the top disc. The polymer is discharged at 8. A reflux condenser is mounted at 9. The apparatus may be operated at normal, or sub- or superatmospheric pressures. In a modification the central rotating member is a cylinder, as illustrated in the Figure accompanying the Provisional Specification. The dimensions and stirring speed are correlated, e.g. with a cylindrical stirrer 4 inches diam. and a vessel 6 inches diam. stirring speed should be 440 to 880 r.p.m. In examples monomers polymerized include styrene, vinyl and vinylidene chloride, acrylonitrile, esters of acrylic or methacrylic acid, olefines and co-polymer mixtures, e.g. styrene-butadiene, methyl methacrylate-butadiene.
GB20990/56A 1956-07-06 1956-07-06 Emulsion polymerisation apparatus Expired GB875796A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB20990/56A GB875796A (en) 1956-07-06 1956-07-06 Emulsion polymerisation apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB20990/56A GB875796A (en) 1956-07-06 1956-07-06 Emulsion polymerisation apparatus

Publications (1)

Publication Number Publication Date
GB875796A true GB875796A (en) 1961-08-23

Family

ID=10155297

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20990/56A Expired GB875796A (en) 1956-07-06 1956-07-06 Emulsion polymerisation apparatus

Country Status (1)

Country Link
GB (1) GB875796A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000000280A1 (en) * 1998-06-27 2000-01-06 Basf Coatings Ag TAYLOR REACTOR FOR MATERIALS CONVERSION IN THE COURSE OF WHICH A CHANGE IN VISCOSITY ξ OF THE REACTION MEDIUM OCCURS
US6399031B1 (en) 1996-08-26 2002-06-04 Basf Aktiengesellschaft Continuous flow reactor having a plurality of alternating bends
US7651670B2 (en) 2001-10-04 2010-01-26 Basf Coatings Ag Method for continuously polymerizing in mass quantities and taylor reactor for carrying out this method
CN109908851A (en) * 2017-12-12 2019-06-21 巴斯夫新材料有限公司 Polymer reactor

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6399031B1 (en) 1996-08-26 2002-06-04 Basf Aktiengesellschaft Continuous flow reactor having a plurality of alternating bends
WO2000000280A1 (en) * 1998-06-27 2000-01-06 Basf Coatings Ag TAYLOR REACTOR FOR MATERIALS CONVERSION IN THE COURSE OF WHICH A CHANGE IN VISCOSITY ξ OF THE REACTION MEDIUM OCCURS
US7122161B1 (en) 1998-06-27 2006-10-17 Basf Coatings Ag Taylor reactor for materials conversion in the course of which a change in viscosity of the reaction medium occurs
US7651670B2 (en) 2001-10-04 2010-01-26 Basf Coatings Ag Method for continuously polymerizing in mass quantities and taylor reactor for carrying out this method
CN109908851A (en) * 2017-12-12 2019-06-21 巴斯夫新材料有限公司 Polymer reactor

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