GB871145A - Improvements in or relating to oil-based compositions - Google Patents

Improvements in or relating to oil-based compositions

Info

Publication number
GB871145A
GB871145A GB39245/56A GB3924556A GB871145A GB 871145 A GB871145 A GB 871145A GB 39245/56 A GB39245/56 A GB 39245/56A GB 3924556 A GB3924556 A GB 3924556A GB 871145 A GB871145 A GB 871145A
Authority
GB
United Kingdom
Prior art keywords
salt
zinc
duomeen
oil
reactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB39245/56A
Inventor
John Scotchford Elliott
Eric Deschamp Edwards
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CC Wakefield and Co Ltd
Original Assignee
CC Wakefield and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CC Wakefield and Co Ltd filed Critical CC Wakefield and Co Ltd
Priority to GB39245/56A priority Critical patent/GB871145A/en
Priority to DEW22476A priority patent/DE1058674B/en
Priority to FR1188961D priority patent/FR1188961A/en
Publication of GB871145A publication Critical patent/GB871145A/en
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/18—Complexes with metals
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
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    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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    • C10M2207/10—Carboxylix acids; Neutral salts thereof
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    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2227/09—Complexes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/12—Groups 6 or 16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/14—Group 7
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/16—Groups 8, 9, or 10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/135—Steam engines or turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C10N2040/253—Small diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/26—Two-strokes or two-cycle engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

Oil-soluble complex ammino compounds employed as oil additives (see Group III), are formed between (a) a polyvalent metal salt of an organic acid and (b) a di- or poly-amine. The polyvalent metal of reactant (a) may be Zn, Cd, Sn, Pb, Ni, Cr, Cu, Fe(ferrous), Hg, Ag, Mn, Pt, Pd, Ru, Os or Ir, while salt of reactant (a) may be a carboxylate, a sulphonate or a salt of a mono- or di-ester of phosphoric acid. The salt may contain alkyl, cycloalkyl, aralkyl, alkaryl or aryl groupings and these may carry substituents such as hydroxyl or esterified carboxyl groups or halogen atoms. Suitable salts are the acetates, octoates, laurates, oleates, napthenates, benzoates, salicylates, petroleum sulphonates, alkylated aryl sulphonates and long chain alkyl and alkaryl phosphates. The amine (b) may be ethylenediamine, diethylene triamine, one or more polyethylene polyamines, pierazine, p-phenylene diamine, the diamines R11NHCH2 CH2CH2NH2 (where R11 is an alkyl group derived from a fatty acid) sold under the Registered Trade Mark "Duomeen" and the heterocyclic nitrogen compounds sold under the Registered Trade Mark "Bitran". In the examples, the preparation is described of complexes from (1) zinc naphthenate and diethylene triamine, (2) zinc napthenate and "Duomeen C", (3) zinc acetate and "Duomeen C", (4) zinc acetate, zinc napthenate and "Duomeen C" and (5) zinc salt of crude wool grease and "Duomeen C". According to the Provisional Specification reactant (a) employed in the formation of the complex ammino compound, may alternatively be a polyvalent metal phenate, mercaptide, enolate or salt of an inorganic acid (e.g. a phosphate, nitrate, borate, chromate or nitrite). Specifications 798,601 and 871,144 are referred to.ALSO:An oil-based composition, suitable as a lubricant or rust-preventing composition, comprises a major proportion of a mineral or synthetic oil and a minor proportion of an oil-soluble complex amino compound formed between (a) a polyvalent metal salt of an organic acid and (b) a di- or poly-amine. Synthetic oils mentioned are polyglycol ethers and diesters of dicarboxylic acids. The polyvalent metal of reactant (a) may be Zn, Cd, Sn, Pb, Ni, Cr, Cu, Fe (ferrous), Hg, Ag, Mn, Pt, Pd, Ru, Os or Ir, while the salt of reactant (a) may be a carboxylate, a sulphonate or a salt of a mono- or di-ester of phosphoric acid. The salt may contain alkyl cycloalkyl, aralkyl, alkaryl or aryl groupings and these may carry substituents such as hydroxyl or esterified carboxyl groups or halogen atoms. Suitable salts are the acetates, octoates, laurates, oleates, naphthenates, benzoates, salicylates, petroleum sulphonates, alkylated aryl sulphonates and long chain alkyl and alkaryl phosphates. The amine (b) may be ethylene diamine, diethylene triamine, one or more polyethylene polyamines, piperazine, p-phenylene diamine, the diamines R11NHCH2CH2CH2NH2 (where R11 is an alkyl group derived from a fatty acid) sold under the Registered Trade Mark "Duomeen" and the heterocyclic nitrogen compounds sold under the Registered Trade Mark "Bitran". The oilbased composition may contain additional ingredients such as detergents (e.g. metal salts of mahogany sulphonic acids) and antioxidants (e.g. zinc dialkyl dithiophosphates, metal alkyl phenol sulphides and phosphorized sulphurized terpenes). The oil-based composition may be a lubricant for steam turbines or for internal combustion engines (especially for small two-stroke engines or for the cylinders of marine diesel engines), or a storage oil or slushing composition. In examples, mineral lubricating oil compositions are described which contain (i) "Duomeen C" complexed with zinc naphthenate, zinc acetate, zinc oleate, nickel mahogany sulphonate, lead naphthenate, chromium caproate or cobalt stearate, (ii) zinc naphthenate complexed with diethylene triamine or "Bitran P" or (iii) lead naphthenate complexed with triethylene tetramine. In some examples, the compositions also contain sodium mahogany sulphonate or basic barium mahogany sulphonate. A composition is also described consisting of di(2-ethylhexyl) sebacate and the zinc naphthenate/"Duomeen C" complex. For comparison purposes, a mineral lubricating oil composition is described which contains zinc dihexyl dithiophosphate and basic barium mahogany sulphonate. According to the Provisional Specification reactant (a), employed in the formation of the complex amino compound, may alternatively be a polyvalent metal phenate, mercaptide, enolate or salt of an inorganic acid (e.g. a phosphate, nitrate, borate, chromate or nitrite). Specifications 798,601 and 871,144 are referred to.
GB39245/56A 1956-12-24 1956-12-24 Improvements in or relating to oil-based compositions Expired GB871145A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB39245/56A GB871145A (en) 1956-12-24 1956-12-24 Improvements in or relating to oil-based compositions
DEW22476A DE1058674B (en) 1956-12-24 1957-12-23 lubricant
FR1188961D FR1188961A (en) 1956-12-24 1957-12-24 Improvements to oil-based compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB39245/56A GB871145A (en) 1956-12-24 1956-12-24 Improvements in or relating to oil-based compositions

Publications (1)

Publication Number Publication Date
GB871145A true GB871145A (en) 1961-06-21

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB39245/56A Expired GB871145A (en) 1956-12-24 1956-12-24 Improvements in or relating to oil-based compositions

Country Status (3)

Country Link
DE (1) DE1058674B (en)
FR (1) FR1188961A (en)
GB (1) GB871145A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302573A (en) 1977-11-04 1981-11-24 Ciba-Geigy Corporation Metal salt/amine complexes as epoxy resin catalytic curing agents
US7879774B2 (en) 2004-07-19 2011-02-01 Afton Chemical Corporation Titanium-containing lubricating oil composition
CN114426900A (en) * 2020-10-29 2022-05-03 中国石油化工股份有限公司 Lead compound, preparation method and application thereof, and lubricating oil composition
CN115992026A (en) * 2021-10-18 2023-04-21 中国石油化工股份有限公司 Industrial gear oil composition and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111909771B (en) * 2020-08-24 2022-06-10 湖北省化学工业研究设计院 Water-based lubricant capable of automatically generating extreme pressure anti-wear agent in drawing process of galvanized steel wire and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1083354A (en) * 1952-11-03 1955-01-07 Lubrizol Corp Improvements to lubricants containing carbonate complexes

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302573A (en) 1977-11-04 1981-11-24 Ciba-Geigy Corporation Metal salt/amine complexes as epoxy resin catalytic curing agents
US7879774B2 (en) 2004-07-19 2011-02-01 Afton Chemical Corporation Titanium-containing lubricating oil composition
CN114426900A (en) * 2020-10-29 2022-05-03 中国石油化工股份有限公司 Lead compound, preparation method and application thereof, and lubricating oil composition
CN114426900B (en) * 2020-10-29 2022-10-21 中国石油化工股份有限公司 Lead compound, preparation method and application thereof, and lubricating oil composition
CN115992026A (en) * 2021-10-18 2023-04-21 中国石油化工股份有限公司 Industrial gear oil composition and preparation method thereof

Also Published As

Publication number Publication date
FR1188961A (en) 1959-09-28
DE1058674B (en) 1959-06-04

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