GB861979A - A process for the production of cyclododecane derivatives - Google Patents

A process for the production of cyclododecane derivatives

Info

Publication number
GB861979A
GB861979A GB33448/58A GB3344858A GB861979A GB 861979 A GB861979 A GB 861979A GB 33448/58 A GB33448/58 A GB 33448/58A GB 3344858 A GB3344858 A GB 3344858A GB 861979 A GB861979 A GB 861979A
Authority
GB
United Kingdom
Prior art keywords
cyclododecane
hydroxymethyl
cyclododecatriene
boiling point
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33448/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Studiengesellschaft Kohle gGmbH
Original Assignee
Studiengesellschaft Kohle gGmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Studiengesellschaft Kohle gGmbH filed Critical Studiengesellschaft Kohle gGmbH
Publication of GB861979A publication Critical patent/GB861979A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/13—Monohydroxylic alcohols containing saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/28—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/413—Saturated compounds containing a keto group being part of a ring of a seven- to twelve-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention comprises mono-(hydroxy methyl) cyclododecane with a boiling point between 90 DEG and 91 DEG C. at 0.2 mm. and di-(hydroxymethyl) cyclododecane with a boiling point between 142 DEG and 144 DEG C. at 0.2 mm. and a process for the production of cyclododecane derivatives wherein a cyclododecatriene is reacted with carbon monoxide and hydrogen in the presence of an oxo synthesis catalyst, the aldehydes formed being optionally hydrogenated to alcohols. Catalysts specified include the covalt salts of fatty acids containing at least 6 carbon atoms and dicobalt octacarbonyl. Inert solvents may be employed in the process, e.g. hexane. In examples, the oxonation of cyclododecatriene is carried out in the presence of a cobalt salt of an organic acid and reduced cobalt supported on kieselguhr and the aldehydes produced are hydrogenated in the presence of the same catalysts. Additional hydrogenation is carried out, if necessary, in the presence of Raney nickel. Mono- and di-(hydroxymethyl) cyclododecanes are isolated from the reaction product and a residue, probably containing tri-(hydroxymethyl) compounds is obtained. Specifications 848,951, 849,236 and 858,257 is referred to.
GB33448/58A 1957-10-24 1958-10-20 A process for the production of cyclododecane derivatives Expired GB861979A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE861979X 1957-10-24

Publications (1)

Publication Number Publication Date
GB861979A true GB861979A (en) 1961-03-01

Family

ID=6796781

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33448/58A Expired GB861979A (en) 1957-10-24 1958-10-20 A process for the production of cyclododecane derivatives

Country Status (1)

Country Link
GB (1) GB861979A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240812A (en) * 1966-03-15 Preparation of omega-halo. undecylalkylketones
US3342878A (en) * 1962-01-18 1967-09-19 Inventa Ag Preparation of monohydroxymethylcyclododecane by hydroformylation of cyclododecatrienes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240812A (en) * 1966-03-15 Preparation of omega-halo. undecylalkylketones
US3342878A (en) * 1962-01-18 1967-09-19 Inventa Ag Preparation of monohydroxymethylcyclododecane by hydroformylation of cyclododecatrienes

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