GB858072A - Improvements in or relating to pigments - Google Patents

Improvements in or relating to pigments

Info

Publication number
GB858072A
GB858072A GB10663/58A GB1066358A GB858072A GB 858072 A GB858072 A GB 858072A GB 10663/58 A GB10663/58 A GB 10663/58A GB 1066358 A GB1066358 A GB 1066358A GB 858072 A GB858072 A GB 858072A
Authority
GB
United Kingdom
Prior art keywords
pigment
copolymers
composition
ferric oxide
toluene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10663/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB858072A publication Critical patent/GB858072A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00Pigment pastes, e.g. for mixing in paints
    • C09D17/004Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C09D17/007Metal oxide
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/22Compounds of iron
    • C09C1/24Oxides of iron
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Coating compositions comprise (a) a hydrophobic iron oxide pigment composition which comprises a dispersion of iron oxide-containing particles which are not capable of scattering visible light (i.e. having a particle size less than about 30 millimicrons), in a water-immiscible volatile organic liquid, said particles having a molecularly thin surface coating of at least one aliphatic monocarboxylic acid which is soluble in the organic liquid and contains at least 6 carbon atoms (see Group III), (b) an organic film-forming vehicle and (c) a solvent for said vehicle. The invention is described in relation to particles of ferric oxide, but is equally applicable to ferric oxide which has been prepared by coprecipitation with hydrous oxides of ferrous iron, chromium, aluminium, manganese and nickel. The pigment compositions may be dispersed by simple mixing in the hydrophobic organic film-forming material together with a volatile organic liquid which is a diluent and/or solvent therefor. Suitable film-forming materials are: cellulose nitrate, cellulose acetate, cellulose propionate, cellulose acetobutyrate, ethyl cellulose, polyester resins, oil-modified alkyd resins, urea/formaldehyde resins, melamine/formaldehyde resins, polyether resins such as those derived from bisphenol and epichlorohydrin, vinyl acetate homopolymer and copolymers, vinyl propionate homopolymer and copolymers, vinyl chloride homopolymers and copolymers, vinyl acetal polymers, methyl methacrylate polymers, butyl methacrylate polymers, ethyl acrylate polymers, acrylonitrile/acrylic ester copolymers, acrylonitrile/methacrylate ester copolymers, styrene/acrylic ester copolymers, 1, 3-butadiene homopolymer, 1, 3-butadiene/acrylonitrile copolymers, 1, 3-butadiene/styrene copolymers and polymeric dihydric alcohol diesters of methacrylic acid. The proportion of pigment to total organic film-forming material is preferably between about 1 and 4 to 10. The above-mentioned organic film-forming materials can be in admixture with compatible modifiers, such for example as plasticizers. The composition can also include other adjuvants at the conventional concentration, such as metallic driers, silicone fluid, fungicides, thixotropy agents, and ultra-violet screening agents. When the pigment composition contains an aromatic hydrocarbon, the volatile organic solvent or diluent for the film-forming material preferably contains initially a proponderance of volatile hydrocarbon. After uniform mixing, esters, ketones, alcohols and petroleum naphthas may be added. Aluminium flake pigment or bronze flake pigment may be added to the iron oxide compositions to provide metallic finishes and thereby enhance the brilliance and increase the two-tone effect. Specified monocarboxylic acids are: lauric acid, coconut oil fatty acids, capric, caprylic, caproic, myristic, palmitic, stearic, carnaubic, behenic, margaric, pentadecanoic, tridecanoic, undecanoic, pelargonic, nonadecanoic, arachidic, lignoceric, oleic, erucic, palmitoleic, linoleic, linolenic, dehydrated castor oil acids, and tall oil fatty acids. From 0,2 to 1,2 parts by weight of acid may be used per part of ferric oxide. Toluene, xylene, high solvency petroleum naphtha and mineral spirits are preferably used to dissolve the carboxylic acid. The following formulations suitable for use as automobile finishes or tinting enamels are exemplified, the portions indicated by numerals being mixed successively: (a) (i) a mixture of high solvency petroleum naphthas, blown castor oil, cellulose nitrate in isopropyl alcohol, methyl isobutyl carbinol, (ii) pigment composition according to the invention in xylene (iii) butyl acetate, methyl amyl acetate, methyl isobutyl ketone and (iv) methyl isobutyl ketone, methyl ethyl ketone, dibutyl phthalate, coconut oil modified alkyd resin solution in toluene, silicone solution in toluene, isopropyl alcohol; (b) (i) ferric oxide composition according to the invention in xylene, calcium naphthenate in mineral spirits and xylene and (ii) soya oil modified alkyd resin in hydrocarbon solvent; (c) (i) ferric oxide composition according to the invention in xylene, toluene, a solution in acetone and toluene of a methyl methacrylate/methacrylic acid copolymer resin (ii) the same acrylic resin solution in acetone and toluene, benzyl butyl phthalate and a dispersion of montmorillonite clay in methyl methacrylate homopolymer dissolved in xylene, toluene and acetone, (d) (i) ferric oxide composition according to the invention in xylene, (ii) coconut oil modified alkyd resin in toluene and naphtha, (iii) melamine/formaldehyde resin in butyl alcohol and (iv) a second portion of melamine/formaldehyde resin in butyl alcohol. It is stated that aluminium flake or paste pre-dispersed in a similar composition in the place of the ferric oxide may be mixed therewith for the preparation of metallic finishes. Specification 622,978 and 630,334 are referred to.ALSO:A hydrophobic iron oxide pigment composition, suitable for use in coating compositions, comprises a dispersion of particles comprising iron oxide which are not capable of scattering visible light (i.e. having a particle size less than about 30 millimicrons), in a waterimmiscible volatile organic liquid, said particles having a molecularly thin surface coating of at least one aliphatic monocarwhich is soluble in the organic liquid and contains at least 6 carbon atoms. The composition is preferably prepared by treating a water-wet hydrous iron oxide pigment pulp having an average particle size less than 100 millimicrons with 0.2 to 1.2 parts by weight of said acid for each part by weight of iron oxide in solution in said organic liquid, removing water from the resulting composition and separating from the composition pigment particles whose size is such that they scatter visible light centrifugally by means of a centrifugal force of at least 6000 g. The invention is described in relation to hydrous ferric oxide, but is equally applicable to ferric oxide co-precipitated with hydrous oxides of ferrous iron, chromium, aluminium, manganese and nickel. A suitable pigment may be prepared by oxidising in solution a ferrous salt such as ferrous sulphate, precipitating ferric oxide with caustic soda and washing out water-soluble salts. The methods of Specifications 622,978 and 630,334 may be employed. Preferably the starting material has an average particle size between 10 and 30 millimicrons. Suitable monocarboxylic acids are saturated or ethylenically unsaturated and have from 6 to 24 carbon atoms per molecule; lauric acid and coconut oil fatty acids are preferred and capric, caprylic, caproic, myristic, palmitic, stearic, carnaubic, behenic, margaric, pentadecanoic, tridecanoic, undecanoic, pelargonic, nonadecanoic, arachidic, lignoceric, oleic, erucic, palmitoleic, linoleic and linolenic acids, dehydrated castor oil and tall oil fatty acids are specified. 0.2 to 1.2 parts by weight of acid may be used per part of ferric oxide. Toluene, xylene, high solvency petroleum naphthas and mineral spirits are preferably used to dissolve the carboxylic acid; 25 to 75% wt. of this solvent based on the total composition may be used. The water-wet pigment is preferably treated with the fatty acid solution at 50 to 70 DEG C., the major proportion of free water removed by decantation and the temperature then raised to remove the remaining free water by azeotropic distillation; the resulting dispersion is then centrifuged after addition of a further quantity of the organic liquid if desired. Centrifugal forces varying between 600 g. and 70,000 g. are referred to. The above compositions may be dispersed by a simple mixing in liquid compositions comprising hydrophobic organic film-forming material and a volatile organic liquid which is a diluent and/or solvent therefor. Suitable film-forming materials include cellulose nitrate, celulose acetate, cellulose propionate, cellulose acetobutyrate, ethyl cellulose, polyester resins, oil modified alkyd resins, urea/formaldehyde resins, melamine/formaldehyde resins, polyether resins such as those derived from bisphenol and epichlorohydrin, vinyl acetate homopolymer and copolymers, vinyl propionate homopolymer and copolymers, vinyl chloride homopolymers and copolymers, vinyl acetal polymers, methyl methacrylate polymers, butyl methacrylate polymers, ethyl acrylate polymers, acrylonitrile/acrylic ester copolymers, acrylonitrile/methacrylate ester copolymers, styrene/acrylic ester copolymers, 1,3-butadiene homopolymer, 1,3-butadiene/acrylonitrile copolymers, 1,3-butadiene/styrene copolymers, polymeric dihydric alcohol diesters of methacrylic acid, oleoresinous varnishes, and glyceride drying and semi-drying oils. These organic film-forming materials can be in admixture with plasticizers. The compositions can also include metallic driers, silicone fluid, fungicides, thixotropy agents, and ultra-violet screening agents. It is preferred that the proportion of pigment to total organic film-forming material should be between about 1 and 4 to 10. When the pigment composition contains an aromatic hydrocarbon the volatile organic solvent or diluent for the film-forming material preferably contains initially a preponderance of volatile hydrocarbon. After uniform mixing, esters, ketones, alcohols and petroleum naphthas may be added to obtain the desired solvent balance. Aluminium flake pigment or bronze flake pigment may be added to the iron oxide composition to provide metallic finishes and thereby enhance the brilliance and increase the two tone effect. The following formulations suitable for use as automobile finishes or tinting enamels are exemplified (the portions indicated are mixed successively):-(a) (i) a mixture of high solvency petroleum naphthas, blown castor oil, cellulose nitrate in isopropyl alcohol, methyl isobutyl carbinol, (ii) pigment composition ac
GB10663/58A 1957-04-15 1958-04-02 Improvements in or relating to pigments Expired GB858072A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US858072XA 1957-04-15 1957-04-15

Publications (1)

Publication Number Publication Date
GB858072A true GB858072A (en) 1961-01-04

Family

ID=22194076

Family Applications (1)

Application Number Title Priority Date Filing Date
GB10663/58A Expired GB858072A (en) 1957-04-15 1958-04-02 Improvements in or relating to pigments

Country Status (1)

Country Link
GB (1) GB858072A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002034845A1 (en) * 2000-10-24 2002-05-02 Pennzoil-Quaker State Company Surface tinting composition and method of use
WO2003074614A1 (en) * 2002-03-02 2003-09-12 Merck Patent Gmbh Platelike effect pigments with a melamine formaldehyde resin coating
CN111377669A (en) * 2020-03-19 2020-07-07 深圳市纳路特建材科技有限公司 Environment-friendly chromatic-aberration-free wall cement mortar and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002034845A1 (en) * 2000-10-24 2002-05-02 Pennzoil-Quaker State Company Surface tinting composition and method of use
US6489393B1 (en) 2000-10-24 2002-12-03 Pennzoil-Quaker State Company Surface tinting composition and method of use
US7268180B2 (en) 2000-10-24 2007-09-11 Shell Oil Company Surface tinting composition and method of use
WO2003074614A1 (en) * 2002-03-02 2003-09-12 Merck Patent Gmbh Platelike effect pigments with a melamine formaldehyde resin coating
CN111377669A (en) * 2020-03-19 2020-07-07 深圳市纳路特建材科技有限公司 Environment-friendly chromatic-aberration-free wall cement mortar and preparation method thereof
CN111377669B (en) * 2020-03-19 2022-11-04 深圳市纳路特建材科技有限公司 Environment-friendly chromatic-aberration-free wall cement mortar and preparation method thereof

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