GB856327A - Membrane materials and process for producing the same - Google Patents
Membrane materials and process for producing the sameInfo
- Publication number
- GB856327A GB856327A GB30541/57A GB3054157A GB856327A GB 856327 A GB856327 A GB 856327A GB 30541/57 A GB30541/57 A GB 30541/57A GB 3054157 A GB3054157 A GB 3054157A GB 856327 A GB856327 A GB 856327A
- Authority
- GB
- United Kingdom
- Prior art keywords
- matrix
- polymeric
- polyvinyl
- hydrophilic
- matrix material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2275—Heterogeneous membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/18—Homopolymers or copolymers of nitriles
- C08J2333/20—Homopolymers or copolymers of acrylonitrile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A membranaceous composition is characterized by a microporous film-like polymeric matrix formed of a material selected from the group consisting of polyvinyl chloride, polyvinyl butyral and copolymers of vinyl chloride with monomers selected from the group consisting of vinyl acetate, vinylidene chloride and acrylonitrile, said matrix having a finely divided solid hydrophilic polymeric material, which is characterized by the ability to swell in water and aqueous solutions uniformly dispersed therethrough and firmly held therein, the polymeric matrix material and hydrophilic polymeric material being present in proportions within the range of from 1 to 4 parts by weight hydrophilic material to each part by weight of matrix material. An inert synthetic fibrous material is also preferably present in the matrix material. Specified hydrophilic polymeric materials are non-ion-selective substances selected from polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide and water soluble natural gums, and ion-selective crosslinked polymeric substances, such as a copolymer of methacrylic acid and divinyl benzene, a polyamine type ion-exchange resin, a polystyrene sulphonic acid resin, a polystyrene phosphonic acid resin or a strong base type ion exchange resin High molecular weight aromatic hydrocarbons may be added as plasticizers. The microporous material is produced by incorporating finely divided particles of the hydrophilic polymeric material in a mixture of matrix material and a solvent therefor, sheeting the mixture, and then leaching out the solvent. Suitable solvents are methyl ethyl ketone, methyl isobutyl ketone, acetone, cyclopentanone, dimethyl formamide, glycol monoethyl ether and diethylene glycol monoethyl ether. In an Example (1) finely ground polyvinyl alcohol is mixed with a dimethyl formamide solution of a polyvinyl chlorideacrylonitrile copolymer, the mixture is coated on to a flat surface, solvent is removed by immersion in running water and the film remaining is dried. The products are useful as battery separators.ALSO:A membranceous composition is characterised by a microporous film-like polymeric matrix formed of a material selected from polyvinyl chloride, polyvinyl butyral and copolymers of vinyl chloride with monomers selected from vinyl acetate, vinylidene chloride and acrylonitrile, said matrix having a finely-divided solid hydrophilic material, which is characterised by its ability to swell in water and aqueous solutions uniformly dispersed therethrough and firmly held therein, the polymeric matrix material and hydrophilic polymeric material being present in proportions with the range of from 1 to 4 parts by weight of hydrophilic material to each part by weight of matrix material. An inert synthetic fibrous material is also preferably present in the matrix material. Specified hydrophilic polymeric materials are polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide and water-soluble natural gums and ion-selective cross-linked polymeric substances such as a copolymer of methacrylic acid and divinyl benzene, a polyamine type ion-exchange resin, a polystyrene sulphonic acid resin, a polystyrene phosphonic acid resin or a strong base type ion-exchange resin. The microporous material is produced by incorporating the finely divided particles of the hydrophilic polymeric material in a mixture of matrix material and a solvent therefor, sheeting the mixture, and then leaching out the solvent. Suitable solvents are methyl ethyl ketone, methyl isobutyl ketone, acetone, cyclopentanone, dimethyl formamide, glycol monoethyl ether and diethylene glycol monoethyl ether.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US856327XA | 1956-10-02 | 1956-10-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB856327A true GB856327A (en) | 1960-12-14 |
Family
ID=22192910
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30541/57A Expired GB856327A (en) | 1956-10-02 | 1957-09-30 | Membrane materials and process for producing the same |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB856327A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2364690A1 (en) * | 1976-09-17 | 1978-04-14 | Fujikura Ltd | PROCESS FOR THE MANUFACTURE OF SEPARATORS FOR ELECTROCHEMICAL CELLS |
EP1011158A1 (en) * | 1998-12-14 | 2000-06-21 | Sumitomo Electric Industries, Ltd. | Battery separator |
US6689421B2 (en) | 1998-03-06 | 2004-02-10 | Kodak Polychrome Graphics, Inc. | Method of preparing a microporous film, and imaging method |
EP2514514A1 (en) * | 2011-04-20 | 2012-10-24 | Samsung Electronics Co., Ltd. | Polyacrylonitrile co-polymer based membrane and its preparation |
CN115119672A (en) * | 2022-02-22 | 2022-09-30 | 南京林业大学 | Insect-proof ventilation mulching film and preparation method thereof |
-
1957
- 1957-09-30 GB GB30541/57A patent/GB856327A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2364690A1 (en) * | 1976-09-17 | 1978-04-14 | Fujikura Ltd | PROCESS FOR THE MANUFACTURE OF SEPARATORS FOR ELECTROCHEMICAL CELLS |
US6689421B2 (en) | 1998-03-06 | 2004-02-10 | Kodak Polychrome Graphics, Inc. | Method of preparing a microporous film, and imaging method |
EP1011158A1 (en) * | 1998-12-14 | 2000-06-21 | Sumitomo Electric Industries, Ltd. | Battery separator |
US6461772B1 (en) | 1998-12-14 | 2002-10-08 | Sumitomo Electric Industries, Ltd. | Battery diaphragm |
EP2514514A1 (en) * | 2011-04-20 | 2012-10-24 | Samsung Electronics Co., Ltd. | Polyacrylonitrile co-polymer based membrane and its preparation |
US9156009B2 (en) | 2011-04-20 | 2015-10-13 | Samsung Electronics Co., Ltd. | Membrane, method for manufacturing the same, and composite membrane including the same |
CN115119672A (en) * | 2022-02-22 | 2022-09-30 | 南京林业大学 | Insect-proof ventilation mulching film and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2681319A (en) | Permselective films of anionexchange resins | |
US2681320A (en) | Permselective films of cationexchange resins | |
FR2147269B1 (en) | ||
GB885719A (en) | Anion exchanger with sponge structure | |
JPS5439833A (en) | Diaphragm for galvanic cell | |
US3304272A (en) | Ion exchange materials prepared by absorbing styrene onto particulate polyethylene, introduction of ion exchange groups and shaping | |
GB856327A (en) | Membrane materials and process for producing the same | |
US2957206A (en) | Production of ion selective permeable membrane and composition therefor | |
US3720321A (en) | Radiation crosslinked, swelled semipermeable membranes | |
US2884387A (en) | Porous membrane materials and process for producing the same | |
KR830004345A (en) | Emulsion polymerization process to make vinyl dispersion resin | |
FR2194475B1 (en) | ||
US3069728A (en) | Production of ion selective permeable membrane | |
US3813354A (en) | Copolymers of alkenylsulfonates and cation permoselective membranes based thereon | |
JPS5578045A (en) | Polyvinyl chloride resin composition | |
GB872217A (en) | Improvements in or relating to ion exchange membranes | |
US3069340A (en) | Dialysis method and semi-permeable membrane thereof | |
US2948637A (en) | Process of sulfonating a plasticized polyvinyl chloride film to form a cation permselective membrane | |
JPS59304A (en) | Fpreparation of separation membrane | |
JPS5541804A (en) | Amphoteric ion exchanger and preparation thereof | |
US3433755A (en) | Ion-exchange material from halogenated polyethylene | |
JPS57190061A (en) | Water-resistant adhesive | |
JPS5618629A (en) | Production of foamable resin particle | |
GB954202A (en) | Microporous thermoplastic material | |
JPS55108413A (en) | Production of graft copolymer |