GB853030A - Method of forming a uniformly, or substantially uniformly, porous body of p.t.f.e. - Google Patents
Method of forming a uniformly, or substantially uniformly, porous body of p.t.f.e.Info
- Publication number
- GB853030A GB853030A GB1523157A GB1523157A GB853030A GB 853030 A GB853030 A GB 853030A GB 1523157 A GB1523157 A GB 1523157A GB 1523157 A GB1523157 A GB 1523157A GB 853030 A GB853030 A GB 853030A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bronze
- phase
- porous
- interstices
- formed phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/26—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
Porous polytetrafluoroethylene is formed by introducing P.T.F.E. into the interstices of a uniformly porous pre-formed phase, sintering, e.g. at 327 DEG C. to 400 DEG C., to consolidate the P.T.F.E. and then removing the pre-formed phase. For example a porous P.T.F.E. body having intercommunicating spherical pores is produced by utilizing a pre-formed phase of coalesced spherical particles of bronze which are subsequently dissolved out with acid. Alternatively the porous body may itself comprise coalesced spheres in which case a pre-phase of similar construction, e.g. of bronze, starch, salt or plastic, has its interstices filled with a suitable material, e.g. polystyrene, polyethylene, polyvinyl chloride, epoxy resins and cellulose derivatives, to form the pre-formed phase, the interstices of which, after removal of the pre-phase, e.g. by dissolution, are filled with P.T.F.E., and the pre-formed phase, after consolidation of the P.T.F.E., is then removed by a solvent inert to the P.T.F.E. Preferably not more than 90% of the spherical particles of bronze, plastic &c., should vary in size by more than a factor of 2 and other metals and metal alloys, e.g. copper, iron, or cupro-nickel, may be used instead of bronze.ALSO:Porous polytetrafluoroethylene (P.T.F.E.) is formed by introducing P.T.F.E. into the interstices of a uniformly porous pre-formed phase, sintering, e.g. at 327 DEG C. to 400 DEG C., to consolidate the P.T.F.E. an then removing the pre-formed phase. For example a porous P.T.F.E. body having intercommunicating spherical pores is produced by utilizing a pre-formed phase of coalesced spherical particles of bronze which are subsequently dissolved out with acid. Alternatively the porous body may itself comprise coalesced spheres in which case a pre-phase of similar construction, e.g. of bronze, starch, salt or plastic, has its interstices filled with a suitable material, e.g. polystyrene, polyethylene, polyvinyl chloride, epoxy resins and cellulose derivatives to form the pre-formed phase, the interstices of which, after removal of the prephase, e.g. by dissolution, are filled with P.T.F.E., and the pre-formed phase, after consolidation of the P.T.F.E., is then removed with a solvent inert to the P.T.F.E. Preferably not more than 10% of the spherical particles of bronze, plastic &c., should vary in size by more than a factor of 2 and other metals and alloys, e.g. copper, iron and cupro-nickel, may be used instead of bronze.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1523157A GB853030A (en) | 1957-05-14 | 1957-05-14 | Method of forming a uniformly, or substantially uniformly, porous body of p.t.f.e. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1523157A GB853030A (en) | 1957-05-14 | 1957-05-14 | Method of forming a uniformly, or substantially uniformly, porous body of p.t.f.e. |
Publications (1)
Publication Number | Publication Date |
---|---|
GB853030A true GB853030A (en) | 1960-11-02 |
Family
ID=10055379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1523157A Expired GB853030A (en) | 1957-05-14 | 1957-05-14 | Method of forming a uniformly, or substantially uniformly, porous body of p.t.f.e. |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB853030A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2193214A (en) * | 1986-05-29 | 1988-02-03 | Thomas Ronald Thomas | Porous ptfe |
WO2000021905A1 (en) * | 1998-10-13 | 2000-04-20 | Alliedsignal Inc. | Three dimensionally periodic structural assemblies on nanometer and longer scales |
-
1957
- 1957-05-14 GB GB1523157A patent/GB853030A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2193214A (en) * | 1986-05-29 | 1988-02-03 | Thomas Ronald Thomas | Porous ptfe |
WO2000021905A1 (en) * | 1998-10-13 | 2000-04-20 | Alliedsignal Inc. | Three dimensionally periodic structural assemblies on nanometer and longer scales |
US6261469B1 (en) | 1998-10-13 | 2001-07-17 | Honeywell International Inc. | Three dimensionally periodic structural assemblies on nanometer and longer scales |
US6517763B1 (en) | 1998-10-13 | 2003-02-11 | Alliedsignal, Inc. | Three dimensionally periodic structural assemblies in nanometer and longer scales |
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