GB851789A - Improvements in or relating to the resolution of tropic acid - Google Patents
Improvements in or relating to the resolution of tropic acidInfo
- Publication number
- GB851789A GB851789A GB10912/59A GB1091259A GB851789A GB 851789 A GB851789 A GB 851789A GB 10912/59 A GB10912/59 A GB 10912/59A GB 1091259 A GB1091259 A GB 1091259A GB 851789 A GB851789 A GB 851789A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resolution
- acid
- tropic acid
- relating
- threo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/42—Unsaturated compounds containing hydroxy or O-metal groups
- C07C59/48—Unsaturated compounds containing hydroxy or O-metal groups containing six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises a process for the resolution of racemic tropic acid by reacting an optically active form of threo-1-(p-nitrophenyl)-2-amino-1:3 propanediol with the tropic acid and separating the resulting diastereoisomeric salts, by difference in solubility thereof, e.g. by treating with a base such as ammonia, and then with an acid such as hydrochloric acid. The compounds D(-) -threo-1-(p nitrophenyl)-2-amino-1:3 propanediol-L(-)-tropate and the corresponding L(+) dextrotatory isomer are described and claimed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU851789X | 1958-03-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB851789A true GB851789A (en) | 1960-10-19 |
Family
ID=10980640
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10912/59A Expired GB851789A (en) | 1958-03-31 | 1959-03-31 | Improvements in or relating to the resolution of tropic acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB851789A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103387534A (en) * | 2012-05-09 | 2013-11-13 | 北大方正集团有限公司 | Method for separating tropicamide raceme |
-
1959
- 1959-03-31 GB GB10912/59A patent/GB851789A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103387534A (en) * | 2012-05-09 | 2013-11-13 | 北大方正集团有限公司 | Method for separating tropicamide raceme |
CN103387534B (en) * | 2012-05-09 | 2015-02-18 | 北大方正集团有限公司 | Method for separating tropicamide raceme |
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