GB849522A - Improvements in or relating to a process for the treatment of cellulose materials - Google Patents

Improvements in or relating to a process for the treatment of cellulose materials

Info

Publication number
GB849522A
GB849522A GB3847056A GB3847056A GB849522A GB 849522 A GB849522 A GB 849522A GB 3847056 A GB3847056 A GB 3847056A GB 3847056 A GB3847056 A GB 3847056A GB 849522 A GB849522 A GB 849522A
Authority
GB
United Kingdom
Prior art keywords
acid
specified
formaldehyde
acids
carboxylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3847056A
Inventor
Walter Paul Ericks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Upson Co
Original Assignee
Upson Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upson Co filed Critical Upson Co
Priority to GB3847056A priority Critical patent/GB849522A/en
Priority to DEU4269A priority patent/DE1052231B/en
Publication of GB849522A publication Critical patent/GB849522A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Cellulosic materials, to stabilise them against dimensional changes due to varying humidity conditions, are treated with an aqueous solution of an ammonium or volatile amine salt of a carboxylic acid containing, besides the carboxyl group, at least one more carboxyl group and/or at least one hydroxyl group and heating to drive off the ammonia or amine, the treatment leaving an amount of the salt of from 2 to 50% by weight of the dried material. Heating temperatures of 100 DEG to 150 DEG C. are specified. Among the acids specified are adipic, malic, maleic, azelaic, phthalic, isosebacic, dihydroxystearic and salicylic acids and the acid di-esters from 2 mols of dibasic acids with one mol of a dihydroxy compound such as ethylene glycol, propylene glycol, polyethylene glycols, polypropylene glycols, or of glycerol. Also specified are di-esters of such polyhydric compounds with the adduct of maleic acid and abietic acid. Also specified are polyesters prepared, for example, from excess of one of the previously mentioned dicarboxylic acids (or their anhydrides) and one of the previously mentioned polyhydric alcohols. Amine bases specified are methyl-, dimethyl-, trimethyl-, ethyl-, diethyl- and triethyl- and propyl-amines. The treating composition may also contain an emulsion of a microcrystalline or other wax, a rubber latex, polyethylene glycol 1500, or a phenol-formaldehyde, cresol formaldehyde, melamine-formaldehyde or urea-formaldehyde resin precondensate or the resin obtained by reacting cresylic acid, formalin and di-ethylamine. The material treated may be regenerated cellulose cloth, regenerated cellulose film, paper pulp, paper, fibre board or wood. A resin which may be included in the treating composition may be obtained by boiling together phenol, formaldehyde and potassium hydroxide and adding water, ammonium dichromate and ammonium hydroxide to precipitate a resin. Another resin may be obtained by heating together cresylic acid, formalin and diethylamine until 84 DEG C. is reached. A resin separates on cooling. Specification 846,098 is referred to.ALSO:Ammonium and lower aliphatic amines salts of organic compounds containing a carboxylic group and at least one additional carboxylic and/or hydroxy group are prepared by reaction of the base with the acid. Specified amines are the methylamines, ethylamines and propyl amines. The carboxylic acid compounds may be aliphatic or aromatic polycarboxylic acids, including those obtained by the Diels-Alder reaction of maleic acid or its anhydride and analogous compounds with compounds containing conjugated double bonds and which themselves may contain carboxylic groups and reaction products of aliphatic polyhydric alcohols, including polyoxy alkylene glycols, with poly carboxylic acids, the products containing free carboxylic groups or both carboxylic and hydroxyl groups. Numerous examples of such carboxylic acid compounds are given, such as eleostearic acid, iso sebacic acid, salicylic acid and the adduct of maleic anhydride with eleostearic acid, polyethylene glycol 200-adipic acid mono ester, 2-butyne-1, 4-diol phthalic acid monoester, and diethylene glycolmaleic acid di-ester. The preparation of a number of these carboxylic acid compounds is described and typically: (10) an adduct is prepared by heating eleostearic acid with maleic anhydride at 130 DEG C.; (27) water soluble acid-esters are obtained on heating a mixture of polyethylene glycol 200, maleic and phthalic anhydrides and adipic acid; (29) 2-ethyl hexanediol-1, 3 is added to molten phthalic anhydride and heated to give the acid mono ester; (30) ethylene glycol is esterified with a mixture of azelaic and undecanedioic acids; (55) glycerol is reacted with adipic acid and the glycerol diadipate is converted into its triethylamine salt.ALSO:Cellulosic materials, to stabilize them against dimensional changes due to varying humidity conditions, are treated with an aqueous solution of an ammonium or volatile amine salt of a carboxylic acid containing, besides the carboxyl group, at least one more carboxyl group and/or at least one hydroxyl group and heating to drive off the ammonia or amine, the treatment leaving an amount of the salt of 2 to 50% by weight of the dried material. Heating temperatures of 100 DEG to 150 DEG C. are specified. Among the acids specified are adipic, malic, maleic, azelaic, phthalic, isosebacic, dihydroxystearic and salicylic acids and the acid di-esters from 2 mols of dibasic acids with one mol of a dihydroxy compound such as ethylene glycol, propylene glycol, polyethylene glycols, polypropylene glycols, or of glycerol. Also specified are di-esters of such polyhydric compounds with the adduct of maleic acid and abietic acid. Amine bases specified are methyl-, dimethyl-, trimethyl-, ethyl-, diethyl-and triethyl- and propyl-amines. The treating composition may also contain an emulsion of a microcrystalline or other wax, a rubber latex or a phenol-formaldehyde, cresol formaldehyde, melamine-formaldehyde or urea-formaldehyde resin precondensate or the resin obtained by reacting cresylic acid, formalin and di-ethylamine. The material treated may be regenerated cellulose cloth. In Example 26, a regenerated cellulose cloth is impregnated with an aqueous solution containing the ammonium salt of glycerolsebacic acid monoester, the ammonium salt of ethylene-glycol-sebacic acid monoester, a water soluble melamine formaldehyde resin and polyethylene glycol 1500, dried and heated. Specification 846,098 is referred to.
GB3847056A 1956-12-17 1956-12-17 Improvements in or relating to a process for the treatment of cellulose materials Expired GB849522A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB3847056A GB849522A (en) 1956-12-17 1956-12-17 Improvements in or relating to a process for the treatment of cellulose materials
DEU4269A DE1052231B (en) 1956-12-17 1956-12-20 Process for stabilizing the dimensions of cellulosic materials against fluctuations in humidity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3847056A GB849522A (en) 1956-12-17 1956-12-17 Improvements in or relating to a process for the treatment of cellulose materials

Publications (1)

Publication Number Publication Date
GB849522A true GB849522A (en) 1960-09-28

Family

ID=10403660

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3847056A Expired GB849522A (en) 1956-12-17 1956-12-17 Improvements in or relating to a process for the treatment of cellulose materials

Country Status (1)

Country Link
GB (1) GB849522A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104404755A (en) * 2014-11-04 2015-03-11 苏州经贸职业技术学院 Anti-wrinkle silk fabric preparation method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104404755A (en) * 2014-11-04 2015-03-11 苏州经贸职业技术学院 Anti-wrinkle silk fabric preparation method

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