GB848919A - Monoacrylate and mono-(methyl substituted acrylate) esters and polymers thereof - Google Patents

Monoacrylate and mono-(methyl substituted acrylate) esters and polymers thereof

Info

Publication number
GB848919A
GB848919A GB420/57A GB42057A GB848919A GB 848919 A GB848919 A GB 848919A GB 420/57 A GB420/57 A GB 420/57A GB 42057 A GB42057 A GB 42057A GB 848919 A GB848919 A GB 848919A
Authority
GB
United Kingdom
Prior art keywords
esters
chain
group
methyl
alkylene oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB420/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodrich Corp
Original Assignee
BF Goodrich Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp
Publication of GB848919A publication Critical patent/GB848919A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/062—Polyethers

Abstract

The invention comprises monoacrylate (inccluding methyl-substituted-acrylate) esters of chain terminated monohydric polyoxyalkylene glycols having at least four alkylene oxide units, said ester containing only one unsaturated group per molecule and also their polymers and their copolymers with olefinic monomers. The monomeric esters have the general formula: <FORM:0848919/IV(a)/1> where R, R1 and R11 are hydrogen or methyl, A is a divalent alkylene group, n is at least 4 and T is a terminal group inert during esterification such at alkoxy, phenoxy, acyloxy, cyano, halogen, halomethylenoxy (-OCH2Hal), -OCHHal2 or -OCHal3. Preferred esters have at least three consecutively-connected carbon atoms between successive ether oxygen atoms. The monomeric esters function as internal plasticisers when copolymerised. Specified comonomers include vinyl and vinylidene chlorides, vinylidene cyanide, acrylic acids, esters, amides and nitriles, olefinic hydrocarbons, maleic anhydride and esters, fumaric acid and esters and polyallyl sucrose. Proportions of from 5 to 99% by weight of the esters are mentioned. Polymerisation may be effected in bulk, solution, aqueous suspension or aqueous emulsion. Per-type catalysts may be used.ALSO:The invention comprises monoacrylate (including methyl-substituted-acrylate) esters of chain terminated monohydric polyoxyalkylene glycols having at least four alkylene oxide units, said ester containing only one unsaturated group per molecule. The esters have the general formula: <FORM:0848919/IV(b)/1> where R, R1 and R11, are hydrogen or methyl, A is a divalent alkylene group, n is at least 4 and T is a terminal group inert during esterification such as alkoxy, phenoxy, acyloxy, cyano, halogen, halomethylenoxy (-OCH2Hal), - OCHHal2 or -OCHal3. They may be prepared by esterifying a chain-terminated polyoxyalkylene glycol (from an alkylene oxide and a chain terminator containing a reactive hydrogen atom) with an acrylic acid, acid chloride or anhydride or by reacting the acrylic acid or acid chloride with an alkylene oxide and subsequently treating the resulting ester with another (saturated) acid to react with the remaining hydroxy group. Preferred esters are obtained by condensing an alkylene monoxide such as tetrahydrofuran with an acrylic acid halide in the presence of a FriedelCraft's catalyst, the halogen atom forming the chain-terminating group (T). Preferred esters have at least three consecutively-connected carbon atoms between successive ether oxygen atoms.
GB420/57A 1956-01-09 1957-01-04 Monoacrylate and mono-(methyl substituted acrylate) esters and polymers thereof Expired GB848919A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US848919XA 1956-01-09 1956-01-09

Publications (1)

Publication Number Publication Date
GB848919A true GB848919A (en) 1960-09-21

Family

ID=22187870

Family Applications (1)

Application Number Title Priority Date Filing Date
GB420/57A Expired GB848919A (en) 1956-01-09 1957-01-04 Monoacrylate and mono-(methyl substituted acrylate) esters and polymers thereof

Country Status (1)

Country Link
GB (1) GB848919A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997014448A1 (en) * 1995-10-17 1997-04-24 Ajay Kumar Luthra Biocompatible lubricious hydrophilic materials for medical devices

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997014448A1 (en) * 1995-10-17 1997-04-24 Ajay Kumar Luthra Biocompatible lubricious hydrophilic materials for medical devices
US6287707B1 (en) 1995-10-17 2001-09-11 Ajay Kumar Luthra Biocompatible lubricious hydrophilic materials for medical devices

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