GB845846A - Process for the preparation of an ammonium borate perhydrate free from water of crystallisation - Google Patents
Process for the preparation of an ammonium borate perhydrate free from water of crystallisationInfo
- Publication number
- GB845846A GB845846A GB555459A GB555459A GB845846A GB 845846 A GB845846 A GB 845846A GB 555459 A GB555459 A GB 555459A GB 555459 A GB555459 A GB 555459A GB 845846 A GB845846 A GB 845846A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ammonium
- sulphate
- diperhydrate
- alkali metal
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 4
- 238000002425 crystallisation Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 8
- -1 fatty alcohol sulphate Chemical class 0.000 abstract 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 5
- 229910052783 alkali metal Inorganic materials 0.000 abstract 5
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 5
- 239000000194 fatty acid Substances 0.000 abstract 5
- 229930195729 fatty acid Natural products 0.000 abstract 5
- 150000004665 fatty acids Chemical class 0.000 abstract 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 4
- 238000005406 washing Methods 0.000 abstract 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 3
- 235000011180 diphosphates Nutrition 0.000 abstract 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 3
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 3
- 239000000391 magnesium silicate Substances 0.000 abstract 3
- 235000019792 magnesium silicate Nutrition 0.000 abstract 3
- 235000002639 sodium chloride Nutrition 0.000 abstract 3
- 239000011780 sodium chloride Substances 0.000 abstract 3
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 3
- 235000011152 sodium sulphate Nutrition 0.000 abstract 3
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 3
- MZQKADNPDLDGJD-UHFFFAOYSA-N 2,3,4,5-tetrapropylbenzenesulfonic acid Chemical compound CCCC1=CC(S(O)(=O)=O)=C(CCC)C(CCC)=C1CCC MZQKADNPDLDGJD-UHFFFAOYSA-N 0.000 abstract 2
- 238000004061 bleaching Methods 0.000 abstract 2
- 239000004327 boric acid Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000004140 cleaning Methods 0.000 abstract 2
- 239000012459 cleaning agent Substances 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 2
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 2
- 235000019353 potassium silicate Nutrition 0.000 abstract 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 2
- 235000017550 sodium carbonate Nutrition 0.000 abstract 2
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 2
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 abstract 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012452 mother liquor Substances 0.000 abstract 1
- 229940072033 potash Drugs 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/12—Peroxyhydrates; Peroxyacids or salts thereof containing boron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Ammonium metaborate diperhydrate, NH4 BO2 2H2O2, and ammonium perborate diperhydrate NH4 BO3 2H2O2 (see Group III) may be used in bleaching baths, and as washing, cleaning, and dispersing agents. Other constituents of compositions for these purposes are: fatty alcohol sulphate, tetrapropylbenzene sulphonate, fatty acid ethanolamide, waterglass, magnesium sulphate, sodium chloride, alkalimetal tri-polyphosphate, alkali-metal pyrophosphate, sodium sulphate, fatty acid amide, magnesium silicate, hydroxyquinoline, caustic soda, caustic potash, and sodium carbonate.ALSO:An ammonium borate perhydrate, free from water of crystallization, is prepared by reacting boric acid, at least 30% hydrogen peroxide, and ammonia in molar ratio 1:2-6:1.05-4. The reaction should be effected with 40-70% H2O2 at 0-30 DEG C. and the H2O2 and boric acid are mixed first. When aqueous, preferably concentrated, e.g. optimum saturation point at 0 DEG C., NH3 solution is added to the two mixed reactants ammonium metaborate diperhydrate NH4BO2,2H2O2 is formed. When gaseous NH3 is passed into the other mixed reactants ammonium perborate diperhydrate NH4BO3,2H2O2 is formed. The precipitated diperhydrates may be separated and dried in vacuo at 30-50 DEG C. The mother liquor may be reused in the process. Stabilizers, e.g. magnesium silicate, alkali metal, pyrophosphate, and hydroxy quinoline may be added to the diperhydrates, which may be used in bleaching baths, and as washing, cleaning, and dispersing agents, if desired, in combination with alkalies, (caustic soda, or potash, or sodium carbonate), detergents, alkali metal phosphates, and alkali metal silicates. In examples: (1) a coarse washing agent contains fatty alcohol sulphate from coconut oil fatty acids, alkylbenzene sulphonate, waterglass, magnesium sulphate, fatty acid ethanolamide from coconut oil fatty acids, sodium chloride, alkali metal tripolyphosphate, alkali metal pyrophosphate, sodium sulphate, ammonium metaborate-diperhydrate, an optical brightener, and water, with, or without, a dyestuff; (2) a fine washing agent contains C12-C18 fatty alcohol sulphate, tetrapropylbenzene sulphonate, fatty acid ethanolamide from coconut oil fatty acids, fatty acid amide from coconut oil fatty acids, common salt, sodium sulphate, ammonium perboratediperhydrate, magnesium silicate, an optical brightener, and water.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH32469A DE1058027B (en) | 1958-02-22 | 1958-02-22 | Process for the preparation of anhydrous ammonium metaborate diperhydrate |
| DEH32470A DE1058028B (en) | 1958-02-22 | 1958-02-22 | Process for the preparation of anhydrous ammonium perborate diperhydrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB845846A true GB845846A (en) | 1960-08-24 |
Family
ID=25979471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB555459A Expired GB845846A (en) | 1958-02-22 | 1959-02-18 | Process for the preparation of an ammonium borate perhydrate free from water of crystallisation |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE574672A (en) |
| CH (1) | CH372287A (en) |
| DE (2) | DE1058028B (en) |
| FR (1) | FR1218739A (en) |
| GB (1) | GB845846A (en) |
| NL (1) | NL236343A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4185960A (en) | 1977-04-08 | 1980-01-29 | Interox | Super-oxidized solid sodium perborate and processes for its manufacture |
-
1958
- 1958-02-22 DE DEH32470A patent/DE1058028B/en active Pending
- 1958-02-22 DE DEH32469A patent/DE1058027B/en active Pending
- 1958-12-23 CH CH6761958A patent/CH372287A/en unknown
-
1959
- 1959-01-13 BE BE574672D patent/BE574672A/xx unknown
- 1959-02-18 GB GB555459A patent/GB845846A/en not_active Expired
- 1959-02-20 NL NL236343A patent/NL236343A/xx unknown
- 1959-02-21 FR FR787385A patent/FR1218739A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4185960A (en) | 1977-04-08 | 1980-01-29 | Interox | Super-oxidized solid sodium perborate and processes for its manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1058027B (en) | 1959-05-27 |
| CH372287A (en) | 1963-10-15 |
| FR1218739A (en) | 1960-05-12 |
| BE574672A (en) | 1959-01-31 |
| NL236343A (en) | 1964-03-25 |
| DE1058028B (en) | 1959-05-27 |
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