GB842264A - Process for the production of polymerisable polyesters and mixtures of these polyesters with polymerisable monomeric vinyl compounds - Google Patents

Process for the production of polymerisable polyesters and mixtures of these polyesters with polymerisable monomeric vinyl compounds

Info

Publication number
GB842264A
GB842264A GB2649/57A GB264957A GB842264A GB 842264 A GB842264 A GB 842264A GB 2649/57 A GB2649/57 A GB 2649/57A GB 264957 A GB264957 A GB 264957A GB 842264 A GB842264 A GB 842264A
Authority
GB
United Kingdom
Prior art keywords
propane
dihydroxydiphenyl
diallyl
polycarbonate
addition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2649/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB842264A publication Critical patent/GB842264A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/04Aromatic polycarbonates
    • C08G64/045Aromatic polycarbonates containing aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/16Aliphatic-aromatic or araliphatic polycarbonates
    • C08G64/1691Aliphatic-aromatic or araliphatic polycarbonates unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

A polymerizable polyester is made by (a) polyesterifing a C-mono-or di-b - alkenyl substituted aromatic dihydroxy compound or a di-oxalkylated derivative thereof with a dicarboxylic acid (or an ester-forming derivative thereof) or with an ester-forming derivative of carbonic acid or (b) polyesterifying a C- mono-or di-b -alkenyl substituted aryl-di (oxocarboxylic acid) (or an ester-forming derivative thereof) with a dihydroxy compound. Suitable dihydroxy compounds for use in process (a) are mono- or di-allylhydroquinone, 3-mono- or 3,31-diallyl4,41-dihydroxydiphenyl and the 3-mono- or 3,31-diallyl compounds of (4,41-dihydroxydiphenyl)-methane, 2,2-(4,4-dihydroxydiphenyl)-ethane or 1,1-(4,41-dihydroxydiphenyl)-propane, -butane, -pentane, or -cyclohexane, or the corresponding mono- or dimethallyl ormono-or di-crotyl compounds, or the di-oxyethylated derivaties of these substituted dihydroxy compounds: suitable dicarboxylic acids are adipic, glutamic, pimelic, fumaric, maleic, phthalic or cyclo aliphatic dicarboxylic acids which may be used in the form of their esters with mono-hydroxy compounds and suitable ester-forming derivatives of carbonic acid are dialkyl or diaryl carbonates, phosgene, or bis-chlorocarbonic esters of aliphatic, cycloaliphatic or aromatic dihydroxy compounds. In process (a), other aromatic, cycloaliphatic or aliphatic dihydroxy compounds may be used as co-reactants. Suitable dicarboxylic compounds for process (b) are the reaction products of the above-mentioned c-mono- or di-b -alkenyl substituted dihydroxy compounds and chloroacetic acid and its esters and suitable dihydroxy compounds are aliphatic, cycloaliphatic or aromatic dihydroxy compounds. The polyesters dry in thin layers when exposed to air and drying may be accelerated by addition of the usual driers. Many are soluble in aromatic hydrocarbons, esters and chlorinated solvents. They dissolve in vinyl compounds, e.g. styrene, vinyl chloride, vinyl acetate, methyl methacrylate or glycol dimethacrylate to form, after addition of a peroxide or redox catalyst, masses suitable for the production of air-drying or stove-drying lacquers or of moulding or castings which may be reinforced with glass fibre. In Examples (1) A polycarbonate from 2,2-(3,31-diallyl-4,41-diphenoxoethanol) - propane and diphenyl carbonate is dissolved in styrene and the mixture copolymerized by heating after addition of benzoyl peroxide, and if desired glass fibres; (2) A polycarbonate from 2,2-(3,31-diallyl-4,41-diphenoxoethanol)-propane, hexanediol and diphenyl carbonate is dissolved in methylene chloride and benzoyl peroxide and cobalt naphthenate added to form a lacquer; (3) A polycarbonate from 2,2-(3,31-diallyl-4,41-diphenoxoethanol) -propane, diethylene glycol and diphenyl carbonate is dissolved in toluene to form a lacquer; (4) A polycarbonate from 2,2-(3,31diallyl-4,41-diphenoxoethanol)-propane and 2,2-(4,41-dihydroxydiphenyl)-propane-bis-phenyl carbonate is copolymerized with a mixture of styrene and methyl methacrylate after the addition of benzoyl peroxide; (5) A polyester from 2,2-(3,31-diallyl-4,41-diphenoxoacetic acid)-propane, adipic acid and diethylene glycol is copolymerized with methyl methacrylate after the addition of benzoyl peroxide; (6) A polyester from 2,2-(3,31-diallyl-4,41-diphenoxoethanol)-propane and 2,2-(3,31-diallyl-4,41-diphenoxoacetic acid)-propane is dissolved in toluene and benzoyl peroxide and Co, Pb or Mn naphthenate added to form a lacquer, (7) A polyester from 2,2-(3,31-diallyl-4,41-diphenoxoethanol) -propane and adipic acid is dissolved in toluene to form a lacquer; (8) A polyester from 2,2-(3,31-diallyl-4,41-diphenoxoethanol)-propane and phthalic anhydride is copolymerized with glycolbis-methacrylate after the addition of benzoyl peroxide; (9) A polycarbonate is made from c-diallyl-hydroquinone, 1,1-(4,41-dihydroxydiphenyl)-cyclohexane and diphenyl carbonate and may be copolymerized with vinyl monomers after the addition of perhydroxy catalysts; (10) A polycarbonate from 2,2-(4,41-dihydroxydiphenyl) -propane, 2,2- (3,31-diallyl-4,41-diphenoxoethanol) -propane and phosgene is copolymerized with styrene after the addition of benzoyl peroxide; (11) A polycarbonate obtained by reacting a mixture of 2,2-(3,31-diallyl-4,41-diphenoxoethanol) -propane and 2,2-(4,41-dihydroxydiphenyl)-propane with phosgene in the presence of styrene is hardened by heating after the addition of benzoyl peroxide; (12) A polycarbonate from 2,2-(3,31-dimethallyl-4,41-diphenoxoethanol) -propane and diphenyl carbonate is copolymerized with styrene after the addition of benzoyl peroxide; (13) A polycarbonate from 3,31-dimethallyl-4,41-dihydroxydiphenyl, 1,6-hexanediol, 1,1-(4,41-dihydroxydiphenyl)-cyclohexane and diphenyl carbonate is copolymerized with styrene after the addition of benzoyl peroxide; (14) A polycarbonate from 3,31- dimethallyl-4,41-dihydroxydiphenyl, 1,1-(4,4-dihydroxydiphenyl)-cyclohexane and diphenyl carbonate is copolymerized with styrene after the addition of benzoyl peroxide; (15) A polycarbonate from 3,31-diallyl-4,41-dihydroxydiphenyl, 1,1-(4,41-dihydroxydiphenyl)-cyclohexane and diphenyl carbonate is copolymerized with styrene or a mixture of styrene and methyl methacrylate; (16) A polycarbonate from 2,2-(3,31-dimethallyl4,41-diphenoxoethanol) -propane, 2,2-(4,41-dihydroxydiphenyl), diethylene glycol and diphenyl carbonate is copolymerized with glycol dimethacrylate after the addition of benzoyl peroxide; (17) A polycarbonate from 1,1-(3,31-diallyl-4,41diphenoxoethanol) -cyclohexane, 2,2-(4,41-dihydroxydiphenyl)-propane and diphenyl carbonate is copolymerized with styrene after the addition of benzoyl peroxide; (18) A polyester from 2,2-(3,31-diallyl-4,41-diphenoxoethanol) -propane, phthalic anhydride, maleic anhydride and 1,3-butanediol is dissolved in styrene and cyclohexanone peroxide and cobalt naphthenate added for form a lacquer. (19) A polyester suitable as a stoving lacquer is made from 2,2-(3,31-diallyl4,41-diphenoxopropanol) -propane, phthalic anhydride and adipic acid.
GB2649/57A 1956-01-28 1957-01-24 Process for the production of polymerisable polyesters and mixtures of these polyesters with polymerisable monomeric vinyl compounds Expired GB842264A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE842264X 1956-01-28

Publications (1)

Publication Number Publication Date
GB842264A true GB842264A (en) 1960-07-27

Family

ID=6769326

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2649/57A Expired GB842264A (en) 1956-01-28 1957-01-24 Process for the production of polymerisable polyesters and mixtures of these polyesters with polymerisable monomeric vinyl compounds

Country Status (1)

Country Link
GB (1) GB842264A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0866083A1 (en) * 1995-12-04 1998-09-23 Idemitsu Kosan Company Limited Polycarbonate resin, crosslinked polycarbonate resin and electrophotographic photoreceptor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0866083A1 (en) * 1995-12-04 1998-09-23 Idemitsu Kosan Company Limited Polycarbonate resin, crosslinked polycarbonate resin and electrophotographic photoreceptor
EP0866083A4 (en) * 1995-12-04 1999-06-02 Idemitsu Kosan Co Polycarbonate resin, crosslinked polycarbonate resin and electrophotographic photoreceptor
US6043334A (en) * 1995-12-04 2000-03-28 Idemitsu Kosan Co., Ltd. Polycarbonate resin, crosslinked polycarbonate resin and electrophotographic photoreceptor

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