GB835137A - Film-forming compositions, ion selective permeable membranes made therefrom and method of preparation thereof - Google Patents
Film-forming compositions, ion selective permeable membranes made therefrom and method of preparation thereofInfo
- Publication number
- GB835137A GB835137A GB619757A GB619757A GB835137A GB 835137 A GB835137 A GB 835137A GB 619757 A GB619757 A GB 619757A GB 619757 A GB619757 A GB 619757A GB 835137 A GB835137 A GB 835137A
- Authority
- GB
- United Kingdom
- Prior art keywords
- film
- poly
- polystyrene
- cast
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Abstract
Ion selective permeable membranes of cast homogeneous polymer mixtures of water-in-soluble, acid and alkali-resistant, thermoplastic, film-forming polymers soluble in organic solvents and substantially linear water-soluble polyelectrolytes, the proportion of polyelectrolyte being at least 10% by weight of the polymer mixture and the membrane being cast in the form of a finely porous film at least 0.001 inch thick, may be prepared by casting a film of the polymer mixture from an organic solvent solution thereof and contacting the film with a polar liquid. The film-forming polymer may be a homopolymer of vinyl chloride or vinylidene chloride, a polyvinyl acetal, e.g. polyvinyl butyral, or a copolymer of vinyl chloride and acrylonitrile or vinylidene chloride. The polyelectrolyte may be polystyrene sulphonic acid, polyacrylic acid, metal chelating polymers, poly N-methyl, 2-vinyl-pyridinium iodide, polystyrene o- and p-trimethyl ammonium iodide, poly (vinylbenzyl trimethyl ammonium chloride), quaternized poly-N-vinyl and poly-N-allyl amines and salts of polyamines containing primary, secondary or tertiary amino groups. The polymer mixture may be dissolved in a solvent for both, e.g. dimethyl formamide, but preferably in a mixture comprising a solvent for the film-forming polymer, e.g. acetone, nitromethane, nitroethane, dimethylformamide, cyclopentanone, cyclohexanone, dimethyl acetamide, N,N - dimethyl acetamide and N,N,N1,N1 - tetramethyloxamide, and a solvent for the polyelectrolyte, e.g. an aliphatic alcohol containing up to 6 carbon atoms such as methanol, ethanol and isopropanol. Films may be cast on glass plates or chromium-plated drums, and multi-layer films may be cast on rotating cylinders by allowing previously cast film to set and applying another coating. The casting solutions may be sprayed upon porous bases, supports or frameworks, e.g. plastic screens, porous ceramic materials and insulated metal screens. After drying the films may be treated with water, methanol or isopropanol. To facilitate the preparation of the casting solution the polyelectrolyte may be rendered more hydrophobic by using a small amount of a cross-linking comonomer, e.g. divinyl benzene, or by forming an ester, e.g. the methyl ester, or amine salt, e.g. with tetrabutyl ammonium hydroxide, tetramethyl ammonium hydroxide, aniline or dimethyl aniline, of an acid resin such as polystyrene sulphonic acid, and hydrolysing after the formation of the membrane. Polystyrene sulphonic acid may be prepared by heating polystyrene with concentrated sulphuric acid in the presence of silver sulphate and poly (vinylbenzyltrimethylammonium chloride) by chloromethylating polystyrene and aminating the product with trimethylamine. The membranes may be used on deionizing water, concentrating dilute salt solutions, separating ionic mixtures, the preparation and subsequent purification of organic acids and amines from their salts and in physical and biological research investigations.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB619757A GB835137A (en) | 1957-02-25 | 1957-02-25 | Film-forming compositions, ion selective permeable membranes made therefrom and method of preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB619757A GB835137A (en) | 1957-02-25 | 1957-02-25 | Film-forming compositions, ion selective permeable membranes made therefrom and method of preparation thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB835137A true GB835137A (en) | 1960-05-18 |
Family
ID=9810180
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB619757A Expired GB835137A (en) | 1957-02-25 | 1957-02-25 | Film-forming compositions, ion selective permeable membranes made therefrom and method of preparation thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB835137A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1202250B (en) * | 1960-10-10 | 1965-10-07 | Paul Kollsman | Process for reducing the polarization in electrodialysis processes and the membranes and cells used in this process |
CN116234835A (en) * | 2020-09-30 | 2023-06-06 | 富士胶片制造欧洲有限公司 | Film and method for producing the same |
-
1957
- 1957-02-25 GB GB619757A patent/GB835137A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1202250B (en) * | 1960-10-10 | 1965-10-07 | Paul Kollsman | Process for reducing the polarization in electrodialysis processes and the membranes and cells used in this process |
CN116234835A (en) * | 2020-09-30 | 2023-06-06 | 富士胶片制造欧洲有限公司 | Film and method for producing the same |
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