GB834575A - Vinyl compounds - Google Patents

Vinyl compounds

Info

Publication number
GB834575A
GB834575A GB21063/56A GB2106356A GB834575A GB 834575 A GB834575 A GB 834575A GB 21063/56 A GB21063/56 A GB 21063/56A GB 2106356 A GB2106356 A GB 2106356A GB 834575 A GB834575 A GB 834575A
Authority
GB
United Kingdom
Prior art keywords
formula
group
compounds
hydrogen
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21063/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB834575A publication Critical patent/GB834575A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14—Monomers containing only one unsaturated aliphatic radical
    • C08F16/28—Monomers containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils

Abstract

The invention comprises esters of the formula <FORM:0834575/IV (b)/1> wherein #f represents an ortho- or para-phenylene group or a group -Z-CR1R11- (Z being a C1-7 alkylene group and R1 and R11 representing hydrogen or C1-4 alkyl groups), n is 1 or 2, R represents hydrogen or an alkyl, alkenyl, benzyl or cyclohexyl group and R0 represents a monovalent or divalent residue of an ester-forming hydroxy compound when n is 1 or 2 respectively. R0 may represent an alkyl, alkenyl, chloroalkyl, nitroalkyl, alkoxyalkyl, aryloxyalkyl, cycloalkyl, aralkyl, aryl, chloroaryl, nitroaryl, alkylene, polyglycol or polythioglycol residue. The compounds are prepared by reacting, in the presence of a hydrogen halide acceptor, a compound of the formula CH2=CH-S-#f-NHR with a halocarbonate of the formula XCOOR0 or XCOO-R0-OOCX, where X is chlorine or bromine. The compounds may be used to form homopolymers or copolymers. Compounds in which R is hydrogen yield the corresponding isocyanates when heated in presence of a base. Compounds of the formula CH2=CH-S-#f-NHR are prepared by reacting aminomercaptans of the formula HS-#f-NHR, or an aminoalkylisothiuronium salt of the formula <FORM:0834575/IV (b)/2> (where Y is an anion), with acetylene under pressure in the presence of a basic catalyst. Aminoalkylisothiuronium salts of the above general formula are obtained by heating compounds having the formula <FORM:0834575/IV (b)/3> with thiourea in an alcohol solvent.ALSO:Vinylthiocarbamates of the formula <FORM:0834575/IV (a)/1> wherein #f represents an ortho- or para-phenylene group or a group -Z-CR1R11- (Z being a C1-7 alkylene group and R1 and R11 representing hydrogen or C1-4 alkyl groups), n is 1 or 2, R represents hydrogen or an alkyl, alkenyl, benzyl or cyclohexyl group and R DEG represents a monovalent or divalent residue of an esterforming hydroxy compound when n is 1 or 2 respectively, are homopolymerized or are copolymerized with vinyl or acrylic co-monomers, such as methyl methacrylate, in the presence of benzoyl peroxide or a azo-type free radical polymerization catalyst, such as dimethyl azoisobutyrate. The polymers may be prepared in the form of gels or cast into sheets. They serve as adhesives for glass, as modifiers for alkyd resins and as textile finishing agents. The monomers of the above general formula may be used as plasticizers and stabilizers for polyvinyl chloride or vinyl chloride-vinyl acetate copolymers.
GB21063/56A 1953-04-10 1956-07-06 Vinyl compounds Expired GB834575A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US763636TA 1953-04-10 1953-04-10

Publications (1)

Publication Number Publication Date
GB834575A true GB834575A (en) 1960-05-11

Family

ID=31975684

Family Applications (2)

Application Number Title Priority Date Filing Date
GB9694/54A Expired GB763636A (en) 1953-04-10 1954-03-29 Improvements in or relating to vinyl ethers
GB21063/56A Expired GB834575A (en) 1953-04-10 1956-07-06 Vinyl compounds

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB9694/54A Expired GB763636A (en) 1953-04-10 1954-03-29 Improvements in or relating to vinyl ethers

Country Status (3)

Country Link
DE (1) DE1028343B (en)
FR (2) FR1097938A (en)
GB (2) GB763636A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1055525B (en) * 1955-07-15 1959-04-23 Rohm & Haas Process for the preparation of vinylthioalkyl carbamates
US3144468A (en) * 1961-11-10 1964-08-11 Du Pont Alpha-cyanatomethoxy ethers

Also Published As

Publication number Publication date
DE1028343B (en) 1958-04-17
FR1097938A (en) 1955-07-12
GB763636A (en) 1956-12-12
FR75114E (en) 1961-03-13

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