GB832619A - Improvements in or relating to a method of separating phthalic anhydride entrained in gases - Google Patents
Improvements in or relating to a method of separating phthalic anhydride entrained in gasesInfo
- Publication number
- GB832619A GB832619A GB4481/56A GB448156A GB832619A GB 832619 A GB832619 A GB 832619A GB 4481/56 A GB4481/56 A GB 4481/56A GB 448156 A GB448156 A GB 448156A GB 832619 A GB832619 A GB 832619A
- Authority
- GB
- United Kingdom
- Prior art keywords
- column
- phthalic anhydride
- anhydride
- hydrocarbon
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/573—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
<PICT:0832619/III/1> Gases containing entrained phthalic anhydride, such as the hot gases obtained from the synthesis of phthalic anhydride by catalytic oxidation, are washed with a liquid aliphatic hydrocarbon or a mixture of liquid aliphatic hydrocarbons having a boiling-point higher than 200 DEG C., whereby the anhydride passes from the gas into the liquid hydrocarbon to form a solution; this solution is distilled using a fractionating column and a vapour mixture comprising the anhydride and hydrocarbon leaves the head of the column; the vapour is condensed and the condensate is cooled to a temperature at which it separates into two phases-one of which is rich in anhydride. A petroleum fraction boiling between 260 DEG and 265 DEG C. may be used as washliquid. Penta- or tetradecane may also be used. The distillation is preferably carried out under reduced pressure. The anhydride-rich phase of the condensate may be separated in either the liquid state or the solid state. A gas, at a temperature of 140 DEG C., containing 50 grams of finely-divided phthalic anhydride per cubic meter is passed through pipe 1 into the lower part of plate-type column A; and a mixture of straight-chain hydrocarbons, boiling between 260 and 265 DEG C., is introduced into the top of the column through pipe 3. The temperature in column A is maintained at 140 DEG C. The gases leaving the column through pipe 2 are practically free from phthalic anhydride; these gases are cooled to recover any hydrocarbon carried over. The solution leaving column A through pipe 4 contains 9% phthalic anhydride; and this solution is distilled in column C, the base of which is maintained at a temperature of 180 DEG C. while the head of the column is maintained under an absolute pressure of 60 mm. Hg. The vapour from the head of the column contains 25% phthalic anhydride, and is condensed in condenser C1, which is maintained at 130 DEG C. The condensate flows into decanter D, which is also maintained at 130 DEG C., where it separates into two liquid layers. The lower layer, which comprises phthalic anhydride containing a small amount of dissolved hydrocarbon, is withdrawn from decanter D and is stripped in plate-type column E, which is heated to 180 DEG C and is maintained at an absolute pressure of 50 mm. Hg. Substantially pure phthalic anhydride is withdrawn from the base of column E. The hydrocarbon vapour leaving the head of column E is condensed in condenser C2; and the condensate is returned to the decanter. The hydrocarbon layer from decanter D is returned to column C as reflux. Any naphthoquinones, present in the initial gas, accumulate together with hydrocarbons in the base of column C. The naphthoquinones are separated from the hydrocarbons in refrigerator F; and the hydrocarbons are then pumped back to the top of column A after being re-heated to 140 DEG C.ALSO:Gases containing entrained phthalic anhydride, such as the hot gases obtained from the synthesis of phthalic anhydride by catalytic oxidation, are washed with a liquid aliphatic hydrocarbon or a mixture of liquid aliphatic hydrocarbons having a boiling point higher than 200 DEG C., whereby the anhydride passes from the gas into the liquid hydrocarbon to form a solution; this solution is distilled using a fractionating column and a vapour mixture comprising anhydride and hydrocarbon leaves the head of the column; the vapour is condensed and the condensate is cooled to a temperature at which it separates into two phases, one of which is rich in phthalic anhydride. A petroleum fraction boiling between 260 DEG and 265 DEG C. may be used as wash-liquid, Pentaor tetra-decane may also be used. The distillation is preferably carried out under reduced pressure. The anhydride-rich phase of the condensate may be separated in either the liquid state or the solid state. Suitable apparatus for carrying out the method of the invention is described (see Group III).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR832619X | 1955-02-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB832619A true GB832619A (en) | 1960-04-13 |
Family
ID=9296112
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4481/56A Expired GB832619A (en) | 1955-02-11 | 1956-02-13 | Improvements in or relating to a method of separating phthalic anhydride entrained in gases |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB832619A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4568427A (en) * | 1982-02-27 | 1986-02-04 | Basf Aktiengesellschaft | Continuous isolation of phthalic anhydride and maleic anhydride from reaction gases |
WO1998023572A1 (en) * | 1996-11-29 | 1998-06-04 | Exxon Chemical Patents Inc. | Solvent assisted process for recovery of phthalic anhydride in the liquid phase by distillation |
CN111486662A (en) * | 2020-03-31 | 2020-08-04 | 北京三泰天洁气体净化技术有限公司 | Method and device for low-temperature separation of synthesis gas and preparation of ammonia synthesis gas |
-
1956
- 1956-02-13 GB GB4481/56A patent/GB832619A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4568427A (en) * | 1982-02-27 | 1986-02-04 | Basf Aktiengesellschaft | Continuous isolation of phthalic anhydride and maleic anhydride from reaction gases |
WO1998023572A1 (en) * | 1996-11-29 | 1998-06-04 | Exxon Chemical Patents Inc. | Solvent assisted process for recovery of phthalic anhydride in the liquid phase by distillation |
CN111486662A (en) * | 2020-03-31 | 2020-08-04 | 北京三泰天洁气体净化技术有限公司 | Method and device for low-temperature separation of synthesis gas and preparation of ammonia synthesis gas |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2551593A (en) | Extractive distillation of alcohols from close-boiling aqueous mixtures | |
US3745092A (en) | Recovery and purification of ethylene oxide by distillation and absorption | |
US1963809A (en) | Process of obtaining constituents of air having a higher boiling point than oxygen | |
GB943817A (en) | Improvements relating to processes for obtaining pure methanol from crude synthetic methanol | |
US2236964A (en) | Separation of acetylene from mixtures | |
GB833230A (en) | An improved method of recovering the anhydrides of organic diacids from gases | |
US2679472A (en) | Separation of hydrocarbons by azeotropic distillation | |
US2250949A (en) | Process for the separation of hydrocarbons from gases containing them | |
JPS60104026A (en) | Distillation post-treatment of 6-20 c atom higher alcohol containing water and methanol | |
KR980000524A (en) | Preparation of a mixture of dimethyl ether and chloromethane and fractionation method using water as extractant | |
US4508928A (en) | Ethanol extraction process | |
GB832619A (en) | Improvements in or relating to a method of separating phthalic anhydride entrained in gases | |
US1866800A (en) | Process of increasing the concentration of olefines in a mixture containing same | |
US2356986A (en) | Process for separating hydrocarbons | |
US2327134A (en) | Extraction of hydrocarbons from gas mixtures which, besides hydrocarbons, contain carbon dioxide | |
US3745093A (en) | Process for separating hexafluoroacetone from hydrogen fluoride | |
US2264878A (en) | Separation of gaseous mixtures | |
US2379696A (en) | Recovery of olefinic hydrocarbons | |
US1877291A (en) | Continuous method of producing esters from olefins | |
US3390534A (en) | Method for separation of multicomponent mixtures | |
US2974174A (en) | Solvent extraction process | |
US2467197A (en) | Azeotropic distillation of styrene | |
US1360853A (en) | Apparatus and method for separating the constituents of air or other gaseous mixtures | |
GB901079A (en) | Purifying furfural | |
US2299283A (en) | Treatment of enriched benzol wash oil or the like |