GB829023A - Method of coating a surface with poly-per-halocarbon resin and article formed thereby - Google Patents

Method of coating a surface with poly-per-halocarbon resin and article formed thereby

Info

Publication number
GB829023A
GB829023A GB3540256A GB3540256A GB829023A GB 829023 A GB829023 A GB 829023A GB 3540256 A GB3540256 A GB 3540256A GB 3540256 A GB3540256 A GB 3540256A GB 829023 A GB829023 A GB 829023A
Authority
GB
United Kingdom
Prior art keywords
resin
poly
resins
per
halocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3540256A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PIERRE ROBERT WELCH
Original Assignee
PIERRE ROBERT WELCH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PIERRE ROBERT WELCH filed Critical PIERRE ROBERT WELCH
Priority to GB3540256A priority Critical patent/GB829023A/en
Publication of GB829023A publication Critical patent/GB829023A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B05D7/26Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials synthetic lacquers or varnishes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Abstract

A surface is coated by applying thereto at least one coat of a composition comprising a uniform aqueous or non-aqueous dispersion of a normally solid poly-per-halocarbon resin having a particle size in the range of 0.1 to 3 microns, and a non-poly-per-halocarbon extender resin compatible therewith and suspended or dissolved in an organic solvent, the poly-per-halo-carbon resin comprising 5 to 70% and the extender resin 95 to 30% by weight of the total resin content, pre-baking the coat at substantially below the fusion temperature of the poly-per-halocarbon resin, applying at least one further coating of similar composition but with a greater proportion of poly-per-halocarbon resin, and heating sufficiently to fuse the last-mentioned resin and form a film strongly adhering to the underlying film. An initial coat, the resin content of which is substantially pure extender resin, and a final coat, of which it is substantially pure poly-per-halocarbon resin, may be applied; or coats containing both types of resin may be alternated with coats containing only poly-per-halocarbon resin. Poly-per-halocarbon resins mentioned include polytetrafluoroethylene, polytrifluorochloroethylene, polydifluorodichloroethylene, and similar resins wherein chlorine is replaced by bromine or iodine; polypolyhalocyclobutenes such as polypentafluorochlorocyclobutene and polytetrafluorodichlorocyclobutene; and the pyrolysis products of unsaturated polyfluoro- or polyfluorochloro-ethylenes. The extender resins may be (a) condensation polymers of epichlorhydrin and bisphenol, which may be modified with high molecular weight fatty acids, resin acids or polybasic acids; (b) phenol aldehyde resins, which may be modified with, e.g. rosin, rosin esters, or polybasic acid esters; (c) silicones and modified silicones, e.g. silicone alkyd resins; (d) furane resins; (e) polyvinyl compounds such as polymers and copolymers of vinyl acetate and vinyl chloride, or of polyvinyl alcohol and polyvinyl chloride with modifying agents such as polybasic acids or anhydrides; (f) urea-formaldehyde and alcohol-modified urea-formaldehyde resins; (g) condensation products of a polybasic acid or anhydride and a polyhydroxy-alcohol such as glycerol, which may be modified by rosin esters or fatty acids; (h) resins formed by condensing melamine and urea, melamine and formaldehyde, or melamine, formaldehyde and urea, which may be modified by esterifying compounds such as higher alcohols. The mixtures of poly-per-halocarbon resins and extender resins may be produced by (a) milling a mixture of the solid resins with a suspending agent or (b) preparing separately suspensions of poly-per-halocarbon resins and either suspensions or solutions of the extender resin, and mixing them. Plasticizers such as poly-per-halocarbon oils or waxes and pigments and fillers, may be included. The compositions may be applied by spraying or brushing to the interior of pipes, reaction vessels, fume ducts, storage tanks, vats and the like, or to smaller articles by dipping. Valves wire, panels, antifriction bearings and baking tins may also be coated. The surface to be coated, which may be iron, steel, ferrous alloy, aluminium, copper, stone, ceramic or plastic (if sufficiently heat-resistant), may be pre-treated by sand-blasting or acid etching, and may be primed with a primer suitable for use with the extender resin. One or more coatings of a baking resin, which is preferably the same as the extender resin, may be applied and pre-baked, preferably below its curing temperature; coats of compositions comprising increasing proportions of polyhalocarbon resin are then applied, with drying, and pre-baking, to a temperature above the fusion point of the poly-per-halocarbon resin, where this amounts to more than 25% of the resin content, are then applied. Finally, coatings containing 100% of poly-per-halocarbon resin are applied, and the article is given a final bake. In a modification, a sand-blasted steel panel is given twelve alternate coatings of a composition having a ratio of poly-per-halocarbon to extender resin of 60 : 40 and of 100% poly-per-halocarbon resin, with three final coats of the latter, with intermediate pre-bakings and a final bake. Heat-resistant fabrics of, e.g., glass, asbestos, synthetic resin or metal may be coated, e.g. polytetrafluoroethylene, an initial coating of an extender resin or a mixture thereof with a poly-per-halocarbon resin being first applied. For example, a mixture containing polytrifluorochloroethylene and an extender resin may first be applied by dipping, spraying or roller-coating, followed by coatings containing polytetrafluoroethylene and an extender resin and polytetrafluoroethylene alone, with intermediate bakings; the surface is then subjected to flaming. An adhesive, e.g. a phenolic, epoxy or "Hycar" (Registered Trade Mark) resin may be applied to the uncoated side. The resulting fabric may be applied to surfaces such as the interior of tanks, to protect them from corrosion.ALSO:A coating composition comprises a uniform aqueous or non-aqueous dispersion of a normally solid poly-per-halocarbon resin having a particle size in the range of 0.1 to 3 microns, and a non-poly-perhalocarbon extender resin compatible therewith and suspended or dissolved in an organic solvent, the poly-per-halocarbon resin comprising 5 to 70% and the extender resin 95 to 30% by weight of the total resin content. Poly-per-halocarbon resins mentioned include polytetrafluoroethylene, polytrifluorochloroethylene, polydifluorodichloroethylene and similar resins wherein chlorine is replaced by bromine or iodine; poly-polyhalocyclobutenes such as polypentafluorochlorocyclobutene and polytetrafluorodichlorocyclobutene; and the pyrolysis products of unsaturated polyfluoro- or polyfluorochloroethylenes. The extender resins may be (a) condensation polymers of epichlorhydrin and bisphenol, which may be modified with high molecular weight fatty acids, resin acids or polybasic acids; (b) phenol aldehyde resins, which may be modified with, e.g., rosin, rosin esters, or polybasic acid esters; (c) silicones and modified silicones, e.g. silicone alkyd resins; (d) furane resins; (e) polyvinyl compounds such as polymers and copolymers of vinyl acetate and vinyl chloride, or of polyvinyl alcohol and polyvinyl chloride with modifying agents such as polybasic acids or anhydrides; (f) urea-formaldehyde and alcohol-modified urea-formaldehyde resins; (g) condensation products of a polybasic acid or anhydride and a polyhydric alcohol such as glycerol, which may be modified by rosin esters or fatty acids; (b) resins formed by condensing melamine and urea, melamine and formaldehyde, or melamine, formaldehyde and urea, which may be modified by esterifying compounds such as higher alcohols. The mixtures of poly-per-halocarbon resins and extender resins may be produced by (a) milling a mixture of the solid resins with a suspending agent or (b) preparing separately suspensions of the poly-per-halocarbon resins and either suspensions or solutions of the extender resins, and mixing them. Specified solvents are toluene, xylene, acetone, diisobutyl ketone and butyl "Cellosolve" (Registered Trade Mark). Sulphuric and phosphoric acids are also included in some examples. Plasticizers such as poly-per-halocarbon oils or waxes, and pigments and fillers, e.g. chrome oxide, may be included.
GB3540256A 1956-11-20 1956-11-20 Method of coating a surface with poly-per-halocarbon resin and article formed thereby Expired GB829023A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3540256A GB829023A (en) 1956-11-20 1956-11-20 Method of coating a surface with poly-per-halocarbon resin and article formed thereby

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3540256A GB829023A (en) 1956-11-20 1956-11-20 Method of coating a surface with poly-per-halocarbon resin and article formed thereby

Publications (1)

Publication Number Publication Date
GB829023A true GB829023A (en) 1960-02-24

Family

ID=10377325

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3540256A Expired GB829023A (en) 1956-11-20 1956-11-20 Method of coating a surface with poly-per-halocarbon resin and article formed thereby

Country Status (1)

Country Link
GB (1) GB829023A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2135327A (en) * 1983-02-18 1984-08-30 Asahi Glass Co Ltd Curable fluoropolymer resin composition
GB2240288A (en) * 1990-01-25 1991-07-31 Usui Kokusai Sangyo Kk A thick-walled, small diameter metal tubing

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2135327A (en) * 1983-02-18 1984-08-30 Asahi Glass Co Ltd Curable fluoropolymer resin composition
GB2240288A (en) * 1990-01-25 1991-07-31 Usui Kokusai Sangyo Kk A thick-walled, small diameter metal tubing
GB2240288B (en) * 1990-01-25 1993-12-15 Usui Kokusai Sangyo Kk Thick-walled small diameter metal tubing

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