GB828814A - Improvements in or relating to elastomeric addition products - Google Patents
Improvements in or relating to elastomeric addition productsInfo
- Publication number
- GB828814A GB828814A GB21163/56A GB2116356A GB828814A GB 828814 A GB828814 A GB 828814A GB 21163/56 A GB21163/56 A GB 21163/56A GB 2116356 A GB2116356 A GB 2116356A GB 828814 A GB828814 A GB 828814A
- Authority
- GB
- United Kingdom
- Prior art keywords
- styrene
- methyl
- iron
- addition product
- para
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/20—Incorporating sulfur atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L17/00—Compositions of reclaimed rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
An elastomeric addition product having a Mooney plasticity on the large motor at 100 DEG C. of not less than 35 is obtained by reacting in the presence of a catalyst system and in the absence of substantial amounts of oxygen (A), at least 30% of the double bonds present in at least one synthetic rubber latex containing an emulsion polymerized polymer of at least one conjugated diolefin having 4-6 carbon atoms with from none to an equal amount by weight of at least one monomer containing a reactive component selected from the group consisting of vinyl and vinylidene radicals which are polymerizable with the diolefin with (B) at least one aliphatic monomercaptan having 1-6 carbon atoms, removing unreacted mercaptan from the reaction mixture and isolating the addition product. The latex may be obtained by polymerizing butadiene, isoprene, dimethyl butadiene, methyl pentadiene, piperylene or 2-chlorobutadiene 1,3; or copolymers of these monomers with styrene, para methyl styrene, ortho-para dimethyl styrene, para methoxy styrene, chloro and bromo styrenes, alpha methyl styrene, alpha-para dimethyl styrene, acrylic and methacrylic acid, methyl and ethyl acrylate, methyl or ethyl methacrylate, vinyl pyridines, 2-vinyl pyridine, 2 - methyl - 5 - vinyl pyridine, vinylidene chloride, acrylonitrile and methacrylonitrile. The latices may be prepared according to the "hot rubber" processes using as emulsifying agent an ammonium or alkali metal salt of stearic, palmitic or oleic acids, or hydrogenated tallow acids or hydrogenated rosin acids or sodium salts of alkylated benzene, or naphthalene sulphonic acids and sodium lauryl sulphate, and using as catalyst potassium persulphate, alkali metal salts of perborates, benzoyl peroxide or hydrogen peroxide, octyl, dodecyl, hexadecyl, octadecyl or benzyl mercaptan, according to the "cold process" using as catalyst sodium formaldehyde sulphoxylate, an organic hydroperoxide and an iron salt, a mixture of a polyethylene polyamine, an iron salt and an organic hydroperoxide, a mixture of an iron-pyrophosphate complex and an organic hydroperoxide, or a mixture of an iron-ethylenediamine tetra-acetic acid complex and an organic hydroperoxide at 41-55 DEG F. The mercaptans used in the manufacture of the addition product may be methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl, isoamyl and hexyl mercaptans. The catalysts which may be used in the preparation of the addition product may be azodi-isobutyronitrile, dimethyl azo isobutyrate, or cumene hydroperoxide or para-menthane hydroperoxide alone or in admixture with (1) sodium formaldehyde sulphoxylate and an iron salt (2) a polyethylene polyamine (3) an iron-ethylene diamine tetra-acetic acid complex or (4) an iron-pyrophosphate complex. The addition is preferably effected at 50-65 DEG C. A processing oil may be used in an amount of 5 to 100 parts of the addition product, and natural rubber, reclaimed rubber, butadiene-styrene copolymer, butadiene-acrylonitrile copolymer and polymerized 2-chlorobutadiene, polystyrene resins, copolymers of styrene and monomethyl styrene, copolymers of styrene and anthracene, copolymers of styrene and actylonitrile, phenolformaldehyde resins and melamine resins may also be added. The compounded addition product may then be mixed with zinc oxide stearic acid, sulphur, mercaptobenzthiazole and styrenated phenol and the whole cured for 90 minutes at 275 DEG F.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US828814XA | 1955-10-28 | 1955-10-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB828814A true GB828814A (en) | 1960-02-24 |
Family
ID=22174049
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21163/56A Expired GB828814A (en) | 1955-10-28 | 1956-07-09 | Improvements in or relating to elastomeric addition products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB828814A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0213568A2 (en) * | 1985-09-03 | 1987-03-11 | Agfa-Gevaert AG | Electrostatographic suspension developer |
WO2018075175A1 (en) * | 2016-10-19 | 2018-04-26 | Contitech Usa, Inc. | Severely hydrotreated naphthenic distillate containing rubber compositions |
-
1956
- 1956-07-09 GB GB21163/56A patent/GB828814A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0213568A2 (en) * | 1985-09-03 | 1987-03-11 | Agfa-Gevaert AG | Electrostatographic suspension developer |
EP0213568A3 (en) * | 1985-09-03 | 1988-07-27 | Agfa-Gevaert Ag | Electrostatographic suspension developer |
WO2018075175A1 (en) * | 2016-10-19 | 2018-04-26 | Contitech Usa, Inc. | Severely hydrotreated naphthenic distillate containing rubber compositions |
US10597519B2 (en) | 2016-10-19 | 2020-03-24 | Contitech Usa, Inc. | Severely hydrotreated naphthenic distillate containing rubber compositions |
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