GB827522A - New organic cobalt compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds - Google Patents
New organic cobalt compounds and solutions and mixtures containing the same, and processes for the preparation of such compoundsInfo
- Publication number
- GB827522A GB827522A GB1008357A GB1008357A GB827522A GB 827522 A GB827522 A GB 827522A GB 1008357 A GB1008357 A GB 1008357A GB 1008357 A GB1008357 A GB 1008357A GB 827522 A GB827522 A GB 827522A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cobalt
- complex
- chloride
- alkali metal
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/235—Saturated compounds containing more than one carboxyl group
- C07C59/245—Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
- C07C59/265—Citric acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A water-soluble alkali metal (or ammonium) cobalt citrate complex compound is obtained by de-ionizing or de-activating cobalt (Co) from cobaltic chloride or cobaltous chloride or other known cobalt salt or compound by causing the said salt or compound to react with citric acid in the presence of water and of sodium hydroxide or other alkali metal hydroxide or ammonium hydroxide so as to form in solution an alkali metal (or ammonium) cobalt citrate complex compound. The complex formed from cobaltic chloride or other cobaltic salt or compound has the probable structure <FORM:0827522/IV (b)/1> where R is the cation of the alkali employed and the complex obtained from cobaltous chloride or other cobaltous salt or compound has the probable structure <FORM:0827522/IV (b)/2> where R is as defined above. Each type of complex may be recovered by crystallizing out from the solution or by evaporating the solution to dryness. When cobaltic chloride is used 9 gram molecules of alkali and 3 gram molecules of citric acid are required for each gram atom of cobalt and in this case 3 gram molecules of alkali chloride are also obtained but this salt need not be removed from the complex. When cobaltous chloride is used 6 gram molecules of alkali and 3 gram molecules of citric acid are required per gram atom of cobalt and in this case 2 gram molecules of alkali chloride are also formed. Other cobalt compounds which may be used are the sulphates, nitrates, carbonates, oxides and (to a lesser extent) the phosphates of cobalt. Examples are given for the preparation of complexes from (1) cobaltic chloride, citric acid and sodium hydroxide; and (2) from cobaltous chloride, citric acid and sodium hydroxide. The reaction product which is recovered in each case by evaporating the reaction solution to dryness contains some sodium chloride. The complexes may be used in compositions suitable for use as a source of cobalt for correcting cobalt deficiencies in animals, plants, or other living organisms (see Groups I and VI).ALSO:A composition suitable for application to the soil comprises a mixture of one or more water-soluble alkali metal (or ammonium) cobalt citrate complexes admixed with a suitable solvent or medium, e.g. irrigation water, soil and a fertilizer, e.g. superphosphate, the said complex being obtained by reacting cobaltic or cobaltous chloride or other known cobalt salt of compound with citric acid in the presence of water and of an alkali metal hydroxide or ammonium hydroxide (see Group IV(b)). The composition may additionally contain the alkali metal (or ammonium)-copper citrate complex and/or-copper tartrate complex disclosed in Specifications 827,521 and 827,523 respectively.ALSO:A composition serving as a source of cobalt for correcting cobalt deficiencies in animals (including humans) or other living organisms comprises a solution or mixture of one or more water-soluble alkali metal (or ammonium) cobalt citrate complexes, said solutions and mixtures being obtained by adding a predetermined quantity of the complex or complexes to a medium or solvent which will serve as a vehicle for the complex or complexes without interfering with the assimilation or utilization of the cobalt by the organism, the said complex being obtained by reacting cobaltic or cobaltous chloride or other known cobalt salt or compound with citric acid in the presence of water and of an alkali metal hydroxide or ammonium hydroxide (see Group IV (b)). The medium used for the composition may be one from which the living organism draws, or is intended to draw, sustenance or nutrition, e.g. drinking water in the case of animals. The drinking water for animals may suitably contain from 0.25 to 25 grams, e.g. about 1.5 grams, of the complex per 1000 litres of water. The composition may additionally contain the alkali metal (or ammonium) copper citrate complex and/or copper tartrate complex disclosed in in Specifications 827,521 and 827,523 respectively.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1008357A GB827522A (en) | 1957-03-27 | 1957-03-27 | New organic cobalt compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1008357A GB827522A (en) | 1957-03-27 | 1957-03-27 | New organic cobalt compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB827522A true GB827522A (en) | 1960-02-03 |
Family
ID=9961146
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1008357A Expired GB827522A (en) | 1957-03-27 | 1957-03-27 | New organic cobalt compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB827522A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2502143A1 (en) * | 1981-03-21 | 1982-09-24 | Kreussler Chem Fab | ACTIVE SUBSTANCE AND PROCESS FOR REDUCING THE TISSUE TERMINATION OF TEXTILE MATERIAL DURING WASHING OR CHEMICAL CLEANING |
-
1957
- 1957-03-27 GB GB1008357A patent/GB827522A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2502143A1 (en) * | 1981-03-21 | 1982-09-24 | Kreussler Chem Fab | ACTIVE SUBSTANCE AND PROCESS FOR REDUCING THE TISSUE TERMINATION OF TEXTILE MATERIAL DURING WASHING OR CHEMICAL CLEANING |
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