GB824460A - Hydrocarbon polymers; processes for preparing said polymers; and compositions containing said polymers - Google Patents

Hydrocarbon polymers; processes for preparing said polymers; and compositions containing said polymers

Info

Publication number
GB824460A
GB824460A GB27109/57A GB2710957A GB824460A GB 824460 A GB824460 A GB 824460A GB 27109/57 A GB27109/57 A GB 27109/57A GB 2710957 A GB2710957 A GB 2710957A GB 824460 A GB824460 A GB 824460A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alpha
olefins
molecule
hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27109/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB824460A publication Critical patent/GB824460A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)

Abstract

A lubricating oil composition comprises a major proportion of a hydrocarbon lubricating oil and a minor proportion of a hydrocarbon polymer prepared by polymerizing one or more alpha-olefins having 10-22 carbon atoms in the molecule, alone or with one or more alpha-olefins having 5-8 carbon atoms in the molecule at below 80 DEG C. in the presence of a Ziegler type catalyst, the ratio of 10-22 carbon atom olefins to 5-8 carbon atom olefins when used being such that 5-15% of the alkyl side chains in the polymer will contain 3-6 carbon atoms. Specified lubricating oils are mineral oils and hydrocarbon lubricants from olefin polymerization, the hydrogenation of cracked wax olefins, and wax isomerization and they may be either waxy lubricating oils or partially or completely dewaxed hydrocarbon oils.ALSO:A mixture of alpha-olefins having 10-22 carbon atoms in the molecule is obtained by polymerizing an alpha-olefin having less than 10 carbon atoms in the molecule at a temperature between 100 DEG and 250 DEG C. and under a pressure above 500 lbs. per sq. inch in the presence of the reducing component of a Ziegler catalyst followed by removal of compounds containing less than ten carbon atoms in the molecule from the reaction product. Specified reducing components are organo-aluminium compounds such as aluminium triethyl or triisobutyl, zinc alkyls and Grignard compounds. Ethylene is the preferred starting material, and distillation the specified separating process. The reaction may be carried out in the presence of inert hydrocarbon diluents but this is not essential.ALSO:A hydrocarbon polymer is prepared by polymerizing one or more alpha-olefins having 10-22 carbon atoms in the molecule, alone or with one or more alpha-olefins having 5-8 carbon atoms in the molecule, at a temperature below 80 DEG C. in the presence of a Ziegler-type catalyst, the ratio of alpha-olefins of 10-22 carbon atoms to those of 5-8 in the polymerization mixture in the second case being such that 5-15% of the alkyl side chains in the resulting polymer will contain 3-6 carbon atoms. The polymerization may be carried out by polymerizing a "10-22" alpha-olefin, adding another "10-22" alpha-olefin and continuing the polymerization. The polymerization may be carried out in the presence of a saturated aliphatic, cycloaliphatic or aromatic liquid hydrocarbon diluent but this is not essential. The mixture of alpha-olefins having 10-22 carbon atoms may be prepared by polymerizing an alpha-olefin having less than 10 carbon atoms at between 100 DEG and 250 DEG C. and under a pressure above 500 pounds per square inch in the presence of a component B (e.g. organo-aluminium compounds) of a Ziegler catalyst followed by the removal of compounds containing less than ten carbon atoms in the molecule from the reaction product; such lower alpha-olefins may be those having less than six carbon atoms, e.g. ethylene.
GB27109/57A 1956-08-28 1957-08-28 Hydrocarbon polymers; processes for preparing said polymers; and compositions containing said polymers Expired GB824460A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US606536A US2895915A (en) 1956-08-28 1956-08-28 Polymeric pour point depressant compositions

Publications (1)

Publication Number Publication Date
GB824460A true GB824460A (en) 1959-12-02

Family

ID=24428366

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27109/57A Expired GB824460A (en) 1956-08-28 1957-08-28 Hydrocarbon polymers; processes for preparing said polymers; and compositions containing said polymers

Country Status (4)

Country Link
US (1) US2895915A (en)
BE (1) BE560366A (en)
FR (1) FR1189138A (en)
GB (1) GB824460A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3157624A (en) * 1961-06-28 1964-11-17 California Research Corp Copolymer of a straight chain olefin and a styrene
US3531419A (en) * 1961-05-24 1970-09-29 Exxon Research Engineering Co Catalyst comprising dialkyl aluminum difluoride and ticl4 olefins

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3129183A (en) * 1957-11-07 1964-04-14 Sun Oil Co Lubricating oil
US2999120A (en) * 1958-11-12 1961-09-05 Donovan R Wilgus Viscosity index improving agents
US3086942A (en) * 1960-02-01 1963-04-23 Exxon Research Engineering Co Lubricants containing various crosslinked substances as thickening agents
US3223638A (en) * 1961-03-03 1965-12-14 Shell Oil Co Lubricants containing cyclohydrocarbon polymers and method of preparing said polymers
US3252771A (en) * 1962-02-19 1966-05-24 Sinclair Research Inc Hydrocarbon fuel compositions
NL293316A (en) * 1962-05-28
BE647517A (en) * 1963-05-28 1964-08-31
US3355379A (en) * 1965-09-08 1967-11-28 Shell Oil Co Poly-alpha-olefin dewaxing aid
US3477957A (en) * 1967-03-08 1969-11-11 Geigy Chem Corp Polymeric pour point depressant compositions
US3876722A (en) * 1968-09-16 1975-04-08 Exxon Research Engineering Co Copolymer of c' 3 'to c' 8 'alpha-olefin and c' 22 'to c' 40 'alpha-olefin
US3513096A (en) * 1968-12-03 1970-05-19 Exxon Research Engineering Co Oil concentrate containing a compatible mixture of polyisobutylene and ethylene-alpha olefin copolymer
US4018695A (en) * 1974-03-04 1977-04-19 Gulf Research & Development Company Polymer-modified automatic transmission fluid
US4415714A (en) * 1979-01-02 1983-11-15 Conoco Inc. Catalyst and method for preparation of drag reducing substances
US4613342A (en) * 1982-08-09 1986-09-23 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4623684A (en) 1982-08-09 1986-11-18 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4575526A (en) * 1982-08-09 1986-03-11 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylaging agent derivative containing combinations, and fuels containing same
US4559155A (en) * 1982-08-09 1985-12-17 The Lubrizol Corporation Hydrocarbyl substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4564460A (en) * 1982-08-09 1986-01-14 The Lubrizol Corporation Hydrocarbyl-substituted carboxylic acylating agent derivative containing combinations, and fuels containing same
US4724273A (en) * 1985-02-13 1988-02-09 Studiengesellschaft Kohle Mbh Process for preparing alpha-olefin polymers and oligomers
US4912272A (en) * 1988-06-23 1990-03-27 Mobil Oil Corporation Lubricant blends having high viscosity indices
US5807949A (en) * 1992-03-19 1998-09-15 Exxon Chemical Patents Inc. Polymers and additive compositions

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2085525A (en) * 1935-11-08 1937-06-29 Shell Dev Process for stabilizing polymers
US2410885A (en) * 1943-03-25 1946-11-12 Standard Oil Dev Co Condensation products and methods of preparing and using same
US2534095A (en) * 1948-03-31 1950-12-12 Standard Oil Dev Co Hydrocarbon copolymers and use thereof as lube oil additive
GB676516A (en) * 1948-03-31 1952-07-30 Standard Oil Dev Co Olefin copolymers, preparation and uses thereof
US2525788A (en) * 1948-08-11 1950-10-17 Socony Vacuum Oil Co Inc Mineral oil lubricants containing polymers of 1-olefins
US2746925A (en) * 1951-09-27 1956-05-22 Exxon Research Engineering Co Lubricants and additives therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3531419A (en) * 1961-05-24 1970-09-29 Exxon Research Engineering Co Catalyst comprising dialkyl aluminum difluoride and ticl4 olefins
US3157624A (en) * 1961-06-28 1964-11-17 California Research Corp Copolymer of a straight chain olefin and a styrene

Also Published As

Publication number Publication date
BE560366A (en)
FR1189138A (en) 1959-09-29
US2895915A (en) 1959-07-21

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