GB823327A - Method of producing sodium borohydride or mono- or di-organo borines - Google Patents
Method of producing sodium borohydride or mono- or di-organo borinesInfo
- Publication number
- GB823327A GB823327A GB32374/57A GB3237457A GB823327A GB 823327 A GB823327 A GB 823327A GB 32374/57 A GB32374/57 A GB 32374/57A GB 3237457 A GB3237457 A GB 3237457A GB 823327 A GB823327 A GB 823327A
- Authority
- GB
- United Kingdom
- Prior art keywords
- borine
- ethyl
- organo
- boron
- mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000033 sodium borohydride Inorganic materials 0.000 title abstract 2
- 239000012279 sodium borohydride Substances 0.000 title abstract 2
- 229910000085 borane Inorganic materials 0.000 abstract 10
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 abstract 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 8
- 229910000104 sodium hydride Inorganic materials 0.000 abstract 8
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 abstract 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 6
- 239000002480 mineral oil Substances 0.000 abstract 6
- 235000010446 mineral oil Nutrition 0.000 abstract 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 6
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 abstract 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 4
- 229910000091 aluminium hydride Inorganic materials 0.000 abstract 4
- 229910052796 boron Inorganic materials 0.000 abstract 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 239000000725 suspension Substances 0.000 abstract 4
- 229910015844 BCl3 Inorganic materials 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001343 alkyl silanes Chemical class 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical group CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 2
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 2
- -1 phenoxy, tolyl Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000012312 sodium hydride Substances 0.000 abstract 2
- 230000003381 solubilizing effect Effects 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000008096 xylene Substances 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
Abstract
Sodium borohydride or mono- or di-organo-borines are prepared by reacting sodium hydride with boron trichloride, mono-organo-boron dichloride, or di-organo-boron chloride at 50-150 DEG C. in an inert solvent or suspension medium in the presence of a catalytically active mono-, di-, or tri-organo-borine or aluminium hydride, capable of dissolving or solubilizing NaH, in amount 0.1-50 molar per cent. Organic radicals in the boron chloride may be methyl, ethyl, propyl, butyl, or the corresponding iso- or oxy-radicals, phenyl, phenoxy, tolyl, or benzyl, and may be the same or different where two are used. The same radicals may be in the catalytically active compound. Solvents may be hexane, heptane, octane, benzene, toluene, xylene, technical benzine, mineral oil, alkyl silanes, or the organic borine to be produced. The catalytically active borine or aluminium hydride may be formed in the reaction mixture, e.g. by adding zinc diethyl, sodium ethyl, sodium ethylate, or ethyl-magnesium chloride, which reacts with the boron chloride or by adding aluminium trichloride and zinc dialkyl. In examples: (1) a mixture of ethyl borine and di-ethyl borine is prepared from NaH, a mixture of (C2H5)2BCl and C2H5BCl2 produced by introducing BCl3 into B(C2H5)3, and B(C2H5)3 in mineral oil, (2) (C2H5O)2BH is prepared by reacting (C2H5O)2BCl with a suspension of NaH in mineral oil containing boron trioxyethyl.ALSO:Mono- or di-organo-borines are prepared by reacting sodium hydride with mono-organo-boron dichloride, or di-organo-boron chloride at 50-150 DEG C. in an inert solvent or suspension medium in the presence of a catalytically active mono-, di-, or tri-organo-borine or aluminium hydride, capable of dissolving or solubilizing NaH, in amount 0.1-50 molar per cent. Organic radicals in the boron chloride may be methyl, ethyl, propyl, butyl, or the corresponding iso- or oxy-radicals, phenyl, phenoxy, tolyl, or benzyl, and may be the same or different where two are used. The same radicals may be in the catalytically active compound. Solvents may be hexane, heptane, octane, benzene, toluene, xylene, technical benzine, mineral oil, alkyl silanes, or the organic borine to be produced. The catalytically active borine or aluminium hydride may be formed in the reaction mixture, e.g. by adding zinc diethyl, sodium ethyl, sodium ethylate, or ethyl-magnesium chloride, which reacts with the boron chloride or by adding aluminium trichloride and zinc dialkyl. In examples: (1) a mixture of ethyl borine and di-ethyl borine is prepared from NaH, a mixture of (C2H5)2BCl and C2H5BCl2 produced by introducing BCl3 into B(C2H5)3, and B(C2H5)3 in mineral oil, (2) (C2H5O)2BH is prepared by reacting (C2H5O)2BCl with a suspension of NaH in mineral oil containing boron trioxyethyl.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE823327X | 1956-10-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB823327A true GB823327A (en) | 1959-11-11 |
Family
ID=6745959
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32374/57A Expired GB823327A (en) | 1956-10-27 | 1957-10-16 | Method of producing sodium borohydride or mono- or di-organo borines |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB823327A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3236598A (en) * | 1961-07-07 | 1966-02-22 | Bayer Ag | Processes for the production of diborane |
-
1957
- 1957-10-16 GB GB32374/57A patent/GB823327A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3236598A (en) * | 1961-07-07 | 1966-02-22 | Bayer Ag | Processes for the production of diborane |
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