GB814610A - Cracking heavy hydrocarbon oils to produce olefins, motor fuels and coke - Google Patents

Cracking heavy hydrocarbon oils to produce olefins, motor fuels and coke

Info

Publication number
GB814610A
GB814610A GB34354/55A GB3435455A GB814610A GB 814610 A GB814610 A GB 814610A GB 34354/55 A GB34354/55 A GB 34354/55A GB 3435455 A GB3435455 A GB 3435455A GB 814610 A GB814610 A GB 814610A
Authority
GB
United Kingdom
Prior art keywords
particles
line
reactor
coke
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34354/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB814610A publication Critical patent/GB814610A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/28Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material

Abstract

<PICT:0814610/III/1> <PICT:0814610/III/2> Heavy hydrocarbon oils are cracked to produce motor fuels, C2-C4 olefines and coke by adding the oil in a finely-divided form to a suspension of inert solid particles at a temperature above 1300 DEG F. in a non-hydrocarbon inert gas (e.g. superheated steam, nitrogen or flue gas) and passing the mixture through an elongated reaction zone wherein the total pressure is maintained from 12 to 50 p.s.i.a., and the hydrocarbon partial pressure is maintained below 85 per cent of the total pressure; the mixture is discharged into a vapour/solids separation zone after a contact-time of less than 2 seconds, and the vapours are rapidly cooled by at least 200 DEG F., preferably down to 600-700 DEG F., the separation and quenching being accomplished within an average time of less than 2 seconds. Coke particles at a temperature of about 1500 DEG F. are supplied from standpipe 11 via U-bend 13 into leg 15. The particles are carried at a velocity of about 16 feet per second, by steam introduced through nozzles 19, 21, 23 and 25, into reactor 17, which is 20-50 feet long and is maintained at a temperature of about 1350 DEG F. Reduced crude oil is sprayed through annular multiple-nozzle device 29 into the stream of hot particles as it enters the reactor. The proportion of steam in the mixture comprises 130 weight per cent of the oil feed. The feed produces sufficient gas upon vaporization and cracking to raise the velocity to 60 feet per second at the reactor outlet. The total pressure in the reactor is 12 p.s.i.a. and the hydrocarbon partial pressure is 5 p.s.i.a. The nominal gas time in the reactor is about 0.25 seconds. The suspension of solid particles in vapours and gases is discharged into a cyclone which has a downwardly converging outer wall 31 (Fig. 2) which causes the suspension to rotate and converge as it moves downwards and, due to centrifugal force, causes the solid particles to flow down the inner wall of the cyclone. The vapours pass through perforations 37 in the frusto-cone 33, and enter line 35. These vapours are cooled to about 700 DEG F. in about 0.25 seconds by contact with a hydrocarbon oil of boiling range 430-650 DEG F. which is introduced into the apparatus through line 39. Part of the quench liquid is sprayed, through nozzle ring 41, upwards into line 35; but part is also sprayed through nozzles 45 inside cone 33. The quenched vapours pass through line 51 into scrubbing-tower 53 which contains baffles 55. Heavy oil is withdrawn from the base of the tower, and may be returned to reactor 17, if desired. The scrubbed vapours pass upwards through fractionating plates 59, liquid being removed from plate 61 via line 63 and returned to a higher plate via line 65. A C5-430 DEG F. stream, comprising about 17 per cent of the oil feed, is removed as a side-stream from the upper portion 67 of the fractionator; and the desired quench liquid is taken off as another side-stream. Gases are withdrawn from the top of the fractionator; these contain ethylene (10 per cent by weight of the feed), propylene (8.5 per cent), and butadiene (2 per cent). The coke particles separated in cyclone 31 are collected in zone 81, where they are maintained as a fluidized bed by stripping gas introduced through line 83. The stripped solids are conveyed up line 93, by high-velocity steam introduced through jets 95, 97 and 99, with simultaneous reduction in particle size. The solids then enter burner 105; and air is supplied through inlet 107. Fuel oil or gas is also supplied through line 107, if it is not desired to burn any of the coke. The burner is so proportioned and the velocity of flow are such that the particles pass completely through the burner in less than 1.5 seconds. The re-heated particles are separated from the combustion gases in cyclone 109. The solids are stripped in collecting vessel 113 by gas introduced through inlets 115, 117. A portion of the particles is withdrawn as product coke through outlet 1171; and the remainder is recycled to the reactor.ALSO:<PICT:0814610/IV (b)/1> <PICT:0814610/IV (b)/2> Heavy hydrocarbon oils are cracked to produce motor fuels, C2-C4 olefines and coke by adding the oil in a finely-divided form to a suspension of inert solid particles at a temperature above 1300 DEG F. in a non-hydrocarbon inert gas (e.g. superheated steam, nitrogen or flue gas) and passing the mixture through an elongated reaction zone wherein the total pressure is maintained from 12 to 50 p.s.i.a., and the hydrocarbon partial pressure is maintained below 85 per cent of the total pressure; the mixture is discharged into a vapour/solids separation zone after a contact time of less than 2 seconds, and the vapours are rapidly cooled by at least 200 DEG F., preferably down to 600-700 DEG F., the separation and quenching being accomplished within an average time of less than 2 seconds. Coke particles at a temperature of about 1500 DEG F. are supplied from standpipe 11 via U-bend 13 into leg 15. The particles are carried at a velocity of about 16 feet per second, by steam introduced through nozzles 19, 21, 23 and 25, into reactor 17, which is 20-50 feet long and is maintained at a temperature of about 1350 DEG F. Reduced crude oil is sprayed through annular multiplenozzle device 29 into the stream of hot particles as it enters the reactor. The proportion of steam in the mixture comprises 130 weight per cent of the oil feel. The feed produces sufficient gas upon vaporization and cracking to raise the velocity to 60 feet per second at the reactor outlet. The total pressure in the reactor is 12 p.s.i.a.; and the hydrocarbon partial pressure is 5 p.s.i.a. The nominal gas time in the reactor is about 0.25 second. The suspension of solid particles in vapours and gases is discharged into a cyclone which has a downwardly converging outer wall 31 (Fig. 2) which causes the suspension to rotate and converge as it moves downwards and, due to centrifugal force, causes the solid particles to flow down the inner wall of the cyclone. The vapours pass through perforations 37 in the frusto-cone 33, and enter line 35. These vapours are cooled to about 700 DEG F. in about 0.25 second by contact with a hydrocarbon oil of boiling range 430-650 DEG F. which is introduced into the apparatus through line 39. Part of the quench liquid is sprayed, through nozzle-ring 41, upwards into line 35; but part is also sprayed through nozzles 45 inside cone 33. The quenched vapours pass through line 51 into scrubbing-tower 53 which contains baffles 55. Heavy oil is withdrawn from the base of the tower, and may be returned to reactor 17, if desired. The scrubbed vapours pass upwards through fractionating plates 59, liquid being removed from plate 61 via line 63 and returned to a higher plate via line 65. A C5-430 DEG F. stream, comprising about 17 per cent of the oil feed, is removed as a side-stream from the upper portion 67 of the fractionator; and the desired quench-liquid is taken off as another side-stream. Gases are withdrawn from the top of the fractionator; these contain ethylene (10 per cent by weight of the feed), propylene (8.5 per cent), and butadiene (2 per cent). The coke particles separated in cyclone 31 are collected in zone 81, where they are maintained as a fluidized bed by stripping gas introduced through line 83. The stripped solids are conveyed up line 93 by high-velocity steam introduced through jets 95, 97 and 99, with simultaneous reduction in particle size. The solids then enter burner 105; and air is supplied through inlet 107. Fuel oil or gas is also supplied through line 107, if it is not desired to burn any of the coke. The burner is so proportioned and the velocity of flow are such that the particles pass completely through the burner in less than 1.5 seconds. The reheated particles are separated from the combustion gases in cyclone 109. The solids are stripped in collecting vessel 113 by gas introduced through inlets 115, 117. A portion of the particles is withdrawn as product coke through outlet 1171; and the remainder is recycled to the reactor.
GB34354/55A 1954-12-17 1955-11-30 Cracking heavy hydrocarbon oils to produce olefins, motor fuels and coke Expired GB814610A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US814610XA 1954-12-17 1954-12-17

Publications (1)

Publication Number Publication Date
GB814610A true GB814610A (en) 1959-06-10

Family

ID=22164310

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34354/55A Expired GB814610A (en) 1954-12-17 1955-11-30 Cracking heavy hydrocarbon oils to produce olefins, motor fuels and coke

Country Status (1)

Country Link
GB (1) GB814610A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7726491B2 (en) 2002-09-19 2010-06-01 Suncor Energy Inc. Bituminous froth hydrocarbon cyclone
US7736501B2 (en) 2002-09-19 2010-06-15 Suncor Energy Inc. System and process for concentrating hydrocarbons in a bitumen feed
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8025341B2 (en) 2005-11-09 2011-09-27 Suncor Energy Inc. Mobile oil sands mining system
US8168071B2 (en) 2005-11-09 2012-05-01 Suncor Energy Inc. Process and apparatus for treating a heavy hydrocarbon feedstock
US8968580B2 (en) 2009-12-23 2015-03-03 Suncor Energy Inc. Apparatus and method for regulating flow through a pumpbox
US9016799B2 (en) 2005-11-09 2015-04-28 Suncor Energy, Inc. Mobile oil sands mining system
CN109694730A (en) * 2017-10-24 2019-04-30 中国石油化工股份有限公司 A kind of crude oil pyrolysis prepares the method and device of low-carbon alkene

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7726491B2 (en) 2002-09-19 2010-06-01 Suncor Energy Inc. Bituminous froth hydrocarbon cyclone
US7736501B2 (en) 2002-09-19 2010-06-15 Suncor Energy Inc. System and process for concentrating hydrocarbons in a bitumen feed
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8685210B2 (en) 2004-01-09 2014-04-01 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8225944B2 (en) 2005-11-09 2012-07-24 Suncor Energy Inc. System, apparatus and process for extraction of bitumen from oil sands
US8168071B2 (en) 2005-11-09 2012-05-01 Suncor Energy Inc. Process and apparatus for treating a heavy hydrocarbon feedstock
US8096425B2 (en) 2005-11-09 2012-01-17 Suncor Energy Inc. System, apparatus and process for extraction of bitumen from oil sands
US8480908B2 (en) 2005-11-09 2013-07-09 Suncor Energy Inc. Process, apparatus and system for treating a hydrocarbon feedstock
US8025341B2 (en) 2005-11-09 2011-09-27 Suncor Energy Inc. Mobile oil sands mining system
US8800784B2 (en) 2005-11-09 2014-08-12 Suncor Energy Inc. System, apparatus and process for extraction of bitumen from oil sands
US8968579B2 (en) 2005-11-09 2015-03-03 Suncor Energy Inc. System, apparatus and process for extraction of bitumen from oil sands
US9016799B2 (en) 2005-11-09 2015-04-28 Suncor Energy, Inc. Mobile oil sands mining system
US8968580B2 (en) 2009-12-23 2015-03-03 Suncor Energy Inc. Apparatus and method for regulating flow through a pumpbox
CN109694730A (en) * 2017-10-24 2019-04-30 中国石油化工股份有限公司 A kind of crude oil pyrolysis prepares the method and device of low-carbon alkene
CN109694730B (en) * 2017-10-24 2022-01-04 中国石油化工股份有限公司 Method and device for preparing low-carbon olefin by cracking crude oil

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