GB813453A - Silica pigments - Google Patents

Silica pigments

Info

Publication number
GB813453A
GB813453A GB35104/55A GB3510455A GB813453A GB 813453 A GB813453 A GB 813453A GB 35104/55 A GB35104/55 A GB 35104/55A GB 3510455 A GB3510455 A GB 3510455A GB 813453 A GB813453 A GB 813453A
Authority
GB
United Kingdom
Prior art keywords
silica
polysiloxane
pigment
sio2
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35104/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Columbia Southern Chemical Corp
Original Assignee
Columbia Southern Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Columbia Southern Chemical Corp filed Critical Columbia Southern Chemical Corp
Publication of GB813453A publication Critical patent/GB813453A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/001Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28Compounds of silicon
    • C09C1/30Silicic acid
    • C09C1/3081Treatment with organo-silicon compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • C01P2006/82Compositional purity water content
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/90Other properties not specified above

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Nanotechnology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

A silica pigment for rubber reinforcement is prepared by mixing an ethylenically or acetylenically unsaturated organopolysiloxane with finely divided hydrated silica-containing pigment having an ultimate particle size below 0.1 m and a surface area of 25-250 sq. m/grm., which pigment contains at least 75 per cent SiO2 and bound water in an amount corresponding to the formula H2O(SiO2)x, where x is 3-85. The organopolysiloxane, in amount 1-20 per cent, should have an R/Si ratio of at least 0.5, where R is an aliphatically unsaturated hydrocarbon or corresponding halogen substituted hydrocarbon radical, e.g. vinyl-, allyl-, methallyl-, 2-chloroallyl-, divinyl-, diallyl-, vinyl phenyl-, allyl phenyl-, cyclohexenyl-and propargyl-polysiloxane, polymers of vinyl ethoxysilanol, or copolymers with dimethyl silanol. The silica-pigment may be coated with the organopolysiloxane before incorporation in the rubber, in which case it is stated that the silica has a chemically bound coating of polysiloxane. The silica may be treated by adding the polysiloxane resin to a slurry of silica and water or organic solvent, e.g. benzene or toluene, or by tumbling the silica while a gas, e.g. nitrogen, containing volatile polysiloxane is passed through, or by adding a small amount of silica to a large amount of polysiloxane and blending with untreated silica, or by spraying liquid polysiloxane or a solution of polysiloxane in a volatile solvent on to silica with agitation and drying at 110 DEG C. Alternatively, the silica and polysiloxane may be milled together with the rubber composition. The silica may contain less than 2 per cent Na2O, and up to 1 mol. per 3 mols. SiO2 of oxides of Ca, Ba, Sr, Mg, Al or Zn, e.g. calcium silicate CaO(SiO2)3.3 and sodium aluminium silicate containing at least 75 per cent SiO2. The silica may be produced by precipitation from sodium silicate solution at 25 DEG C. in the presence of sodium chloride by an acid or acid salt, e.g. carbon dioxide, ammonium or sodium bicarbonate, hydrochloric, sulphuric, phosphoric, sulphurous, or nitric acids, sodium acid sulphate or disodium acid phosphate. Alternatively, the silica may be produced by reacting acid with calcium silicate prepared from sodium silicate and calcium chloride in an aqueous medium containing sodium chloride. Magnesium, barium, strontium, or zinc silicates may alternatively be used in silica preparation. In examples: (4) aqueous silica slurry is homogenized with a toluene solution of vinyl polysiloxane and dried, and the dry pigment is mixed with natural rubber, zinc oxide, sulphur, stearic acid, phenyl-b -naphthylamine, benzothiazyl disulphide, di-o-tolyl guanidine, and triethanolamine; (5) silica is mixed into a paste with toluene, vinyl polysiloxane dissolved in toluene, and n-butanol containing triethanolamine are then added, solvents are evaporated on a steam bath, and the resulting pigment is mixed with the composition of Example (4) or with butadiene-styrene copolymer GR/S, zinc oxide, sulphur, di-o-tolyl guanidine, and 2-mercaptothiazoline.ALSO:A silica pigment for rubber reinforcement is prepared by mixing an ethylenically or acetylenically unsaturated organopolysiloxane with finely-divided hydrated silica-containing pigment having an ultimate particle size below 0.1 m and a surface area of 25-250 sq. m./g., which pigment contains at least 75 per cent of SiO2, and bound water in an amount corresponding to the formula H2O(SiO2)x, where x is 3-85. The organopolysiloxane, in amount 1-20 per cent, should have an R/Si ratio of at least 0.5, where R is an aliphatically unsaturated hydrocarbon or corresponding halogen substituted hydrocarbon radical, e.g. vinyl-, allyl-, methallyl-, 2-chloroallyl-, divinyl-, di-allyl-, vinyl phenyl-, allyl phenyl-, cyclo-hexenyl- and propargyl-polysiloxane, polymers of vinyl ethoxysilonol, or copolymers with dimethyl silanol. The silica pigment may be coated with the organopolysiloxane before incorporation in the rubber, in which case it is stated that the silica has a chemicallybound coating of polysiloxane. The silica may be treated by adding the polysiloxane resin to a slurry of silica and water or organic solvent, e.g. benzene or toluene, or by tumbling the silica while a gas, e.g. nitrogen, containing volatile polysiloxane is passed through, or by adding a small amount of silica to a large amount of polysiloxane and blending with untreated silica, or by spraying liquid polysiloxane or a solution of polysiloxane in a volatile solvent on to silica with agitation and drying at 110 DEG C. Alternatively, the silica and polysiloxane may be milled together with the rubber composition. The silica may contain less than 2 per cent of Na2O, and up to 1 mol. per 3 mols. SiO2 of oxides of Ca, Ba, Sr, Mg. Al or Zn, e.g. calcium silicate CaO(SiO2)3.3 and sodium aluminium silicate containing at least 75 per cent of SiO2. In examples: (4) aqueous silica slurry is homogenized with a toluene solution of vinyl polysiloxane and dried, and the dry pigment is mixed with natural rubber, zinc oxide, sulphur, stearic acid, phenyl-b -naphthylamine, benzothiazyl disulphide, di-o-tolyl guanidine, and triethanolamine; (5) silica is mixed into a paste with toluene, vinyl polysiloxane dissolved in toluene, and n-butanol containing triethanolamine are then added, solvents are evaporated on a stream bath, and the resulting pigment is mixed with the composition of Example (4) or with butadiene-styrene copolymer GR-S, zinc oxide, sulphur, di-o-tolyl guanidine, and 2-mercaptothiazoline.
GB35104/55A 1954-12-14 1955-12-07 Silica pigments Expired GB813453A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US813453XA 1954-12-14 1954-12-14

Publications (1)

Publication Number Publication Date
GB813453A true GB813453A (en) 1959-05-13

Family

ID=22163568

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35104/55A Expired GB813453A (en) 1954-12-14 1955-12-07 Silica pigments

Country Status (3)

Country Link
CH (1) CH347821A (en)
FR (1) FR1143701A (en)
GB (1) GB813453A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1281733A1 (en) * 2001-08-04 2003-02-05 Degussa AG Hydrophobic not annealed precipitated silica with high whiteness
US7022375B2 (en) 2001-08-04 2006-04-04 Degussa Ag High-whiteness hydrophobic precipitated silica with ultralow moisture absorption
US7074457B2 (en) 2001-08-04 2006-07-11 Degussa Ag Process for preparing high-whiteness hydrophobic precipitated silica with ultralow moisture absorption

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2729244A1 (en) * 1977-06-29 1979-01-04 Degussa FELLING SILICIC ACID
EP0008613B2 (en) * 1978-06-12 1987-09-09 Ppg Industries, Inc. Process for treating pellets of silica and coating compositions containing the soft-settling flatting agent thus obtained
CN111747423B (en) * 2020-06-22 2023-03-17 安徽龙泉硅材料有限公司 Preparation method of ultrapure sodium silicate

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1281733A1 (en) * 2001-08-04 2003-02-05 Degussa AG Hydrophobic not annealed precipitated silica with high whiteness
US6899951B2 (en) 2001-08-04 2005-05-31 Degussa Ag High-whiteness, non-heat-treated hydrophobic precipitated silica
US7022375B2 (en) 2001-08-04 2006-04-04 Degussa Ag High-whiteness hydrophobic precipitated silica with ultralow moisture absorption
US7074457B2 (en) 2001-08-04 2006-07-11 Degussa Ag Process for preparing high-whiteness hydrophobic precipitated silica with ultralow moisture absorption
US7220449B2 (en) 2001-08-04 2007-05-22 Degussa Ag High-whiteness hydrophobic precipitated silica with ultralow moisture absorption

Also Published As

Publication number Publication date
CH347821A (en) 1960-07-31
FR1143701A (en) 1957-10-04

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