GB813453A - Silica pigments - Google Patents
Silica pigmentsInfo
- Publication number
- GB813453A GB813453A GB35104/55A GB3510455A GB813453A GB 813453 A GB813453 A GB 813453A GB 35104/55 A GB35104/55 A GB 35104/55A GB 3510455 A GB3510455 A GB 3510455A GB 813453 A GB813453 A GB 813453A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silica
- polysiloxane
- pigment
- sio2
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/001—Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3081—Treatment with organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Nanotechnology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Abstract
A silica pigment for rubber reinforcement is prepared by mixing an ethylenically or acetylenically unsaturated organopolysiloxane with finely divided hydrated silica-containing pigment having an ultimate particle size below 0.1 m and a surface area of 25-250 sq. m/grm., which pigment contains at least 75 per cent SiO2 and bound water in an amount corresponding to the formula H2O(SiO2)x, where x is 3-85. The organopolysiloxane, in amount 1-20 per cent, should have an R/Si ratio of at least 0.5, where R is an aliphatically unsaturated hydrocarbon or corresponding halogen substituted hydrocarbon radical, e.g. vinyl-, allyl-, methallyl-, 2-chloroallyl-, divinyl-, diallyl-, vinyl phenyl-, allyl phenyl-, cyclohexenyl-and propargyl-polysiloxane, polymers of vinyl ethoxysilanol, or copolymers with dimethyl silanol. The silica-pigment may be coated with the organopolysiloxane before incorporation in the rubber, in which case it is stated that the silica has a chemically bound coating of polysiloxane. The silica may be treated by adding the polysiloxane resin to a slurry of silica and water or organic solvent, e.g. benzene or toluene, or by tumbling the silica while a gas, e.g. nitrogen, containing volatile polysiloxane is passed through, or by adding a small amount of silica to a large amount of polysiloxane and blending with untreated silica, or by spraying liquid polysiloxane or a solution of polysiloxane in a volatile solvent on to silica with agitation and drying at 110 DEG C. Alternatively, the silica and polysiloxane may be milled together with the rubber composition. The silica may contain less than 2 per cent Na2O, and up to 1 mol. per 3 mols. SiO2 of oxides of Ca, Ba, Sr, Mg, Al or Zn, e.g. calcium silicate CaO(SiO2)3.3 and sodium aluminium silicate containing at least 75 per cent SiO2. The silica may be produced by precipitation from sodium silicate solution at 25 DEG C. in the presence of sodium chloride by an acid or acid salt, e.g. carbon dioxide, ammonium or sodium bicarbonate, hydrochloric, sulphuric, phosphoric, sulphurous, or nitric acids, sodium acid sulphate or disodium acid phosphate. Alternatively, the silica may be produced by reacting acid with calcium silicate prepared from sodium silicate and calcium chloride in an aqueous medium containing sodium chloride. Magnesium, barium, strontium, or zinc silicates may alternatively be used in silica preparation. In examples: (4) aqueous silica slurry is homogenized with a toluene solution of vinyl polysiloxane and dried, and the dry pigment is mixed with natural rubber, zinc oxide, sulphur, stearic acid, phenyl-b -naphthylamine, benzothiazyl disulphide, di-o-tolyl guanidine, and triethanolamine; (5) silica is mixed into a paste with toluene, vinyl polysiloxane dissolved in toluene, and n-butanol containing triethanolamine are then added, solvents are evaporated on a steam bath, and the resulting pigment is mixed with the composition of Example (4) or with butadiene-styrene copolymer GR/S, zinc oxide, sulphur, di-o-tolyl guanidine, and 2-mercaptothiazoline.ALSO:A silica pigment for rubber reinforcement is prepared by mixing an ethylenically or acetylenically unsaturated organopolysiloxane with finely-divided hydrated silica-containing pigment having an ultimate particle size below 0.1 m and a surface area of 25-250 sq. m./g., which pigment contains at least 75 per cent of SiO2, and bound water in an amount corresponding to the formula H2O(SiO2)x, where x is 3-85. The organopolysiloxane, in amount 1-20 per cent, should have an R/Si ratio of at least 0.5, where R is an aliphatically unsaturated hydrocarbon or corresponding halogen substituted hydrocarbon radical, e.g. vinyl-, allyl-, methallyl-, 2-chloroallyl-, divinyl-, di-allyl-, vinyl phenyl-, allyl phenyl-, cyclo-hexenyl- and propargyl-polysiloxane, polymers of vinyl ethoxysilonol, or copolymers with dimethyl silanol. The silica pigment may be coated with the organopolysiloxane before incorporation in the rubber, in which case it is stated that the silica has a chemicallybound coating of polysiloxane. The silica may be treated by adding the polysiloxane resin to a slurry of silica and water or organic solvent, e.g. benzene or toluene, or by tumbling the silica while a gas, e.g. nitrogen, containing volatile polysiloxane is passed through, or by adding a small amount of silica to a large amount of polysiloxane and blending with untreated silica, or by spraying liquid polysiloxane or a solution of polysiloxane in a volatile solvent on to silica with agitation and drying at 110 DEG C. Alternatively, the silica and polysiloxane may be milled together with the rubber composition. The silica may contain less than 2 per cent of Na2O, and up to 1 mol. per 3 mols. SiO2 of oxides of Ca, Ba, Sr, Mg. Al or Zn, e.g. calcium silicate CaO(SiO2)3.3 and sodium aluminium silicate containing at least 75 per cent of SiO2. In examples: (4) aqueous silica slurry is homogenized with a toluene solution of vinyl polysiloxane and dried, and the dry pigment is mixed with natural rubber, zinc oxide, sulphur, stearic acid, phenyl-b -naphthylamine, benzothiazyl disulphide, di-o-tolyl guanidine, and triethanolamine; (5) silica is mixed into a paste with toluene, vinyl polysiloxane dissolved in toluene, and n-butanol containing triethanolamine are then added, solvents are evaporated on a stream bath, and the resulting pigment is mixed with the composition of Example (4) or with butadiene-styrene copolymer GR-S, zinc oxide, sulphur, di-o-tolyl guanidine, and 2-mercaptothiazoline.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US813453XA | 1954-12-14 | 1954-12-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB813453A true GB813453A (en) | 1959-05-13 |
Family
ID=22163568
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35104/55A Expired GB813453A (en) | 1954-12-14 | 1955-12-07 | Silica pigments |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH347821A (en) |
FR (1) | FR1143701A (en) |
GB (1) | GB813453A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1281733A1 (en) * | 2001-08-04 | 2003-02-05 | Degussa AG | Hydrophobic not annealed precipitated silica with high whiteness |
US7022375B2 (en) | 2001-08-04 | 2006-04-04 | Degussa Ag | High-whiteness hydrophobic precipitated silica with ultralow moisture absorption |
US7074457B2 (en) | 2001-08-04 | 2006-07-11 | Degussa Ag | Process for preparing high-whiteness hydrophobic precipitated silica with ultralow moisture absorption |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2729244A1 (en) * | 1977-06-29 | 1979-01-04 | Degussa | FELLING SILICIC ACID |
EP0008613B2 (en) * | 1978-06-12 | 1987-09-09 | Ppg Industries, Inc. | Process for treating pellets of silica and coating compositions containing the soft-settling flatting agent thus obtained |
CN111747423B (en) * | 2020-06-22 | 2023-03-17 | 安徽龙泉硅材料有限公司 | Preparation method of ultrapure sodium silicate |
-
1955
- 1955-12-07 GB GB35104/55A patent/GB813453A/en not_active Expired
- 1955-12-13 FR FR1143701D patent/FR1143701A/en not_active Expired
- 1955-12-14 CH CH347821D patent/CH347821A/en unknown
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1281733A1 (en) * | 2001-08-04 | 2003-02-05 | Degussa AG | Hydrophobic not annealed precipitated silica with high whiteness |
US6899951B2 (en) | 2001-08-04 | 2005-05-31 | Degussa Ag | High-whiteness, non-heat-treated hydrophobic precipitated silica |
US7022375B2 (en) | 2001-08-04 | 2006-04-04 | Degussa Ag | High-whiteness hydrophobic precipitated silica with ultralow moisture absorption |
US7074457B2 (en) | 2001-08-04 | 2006-07-11 | Degussa Ag | Process for preparing high-whiteness hydrophobic precipitated silica with ultralow moisture absorption |
US7220449B2 (en) | 2001-08-04 | 2007-05-22 | Degussa Ag | High-whiteness hydrophobic precipitated silica with ultralow moisture absorption |
Also Published As
Publication number | Publication date |
---|---|
CH347821A (en) | 1960-07-31 |
FR1143701A (en) | 1957-10-04 |
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