GB806182A - Improved process for the preparation of new organic monochloro derivatives - Google Patents

Improved process for the preparation of new organic monochloro derivatives

Info

Publication number
GB806182A
GB806182A GB38700/56A GB3870056A GB806182A GB 806182 A GB806182 A GB 806182A GB 38700/56 A GB38700/56 A GB 38700/56A GB 3870056 A GB3870056 A GB 3870056A GB 806182 A GB806182 A GB 806182A
Authority
GB
United Kingdom
Prior art keywords
aluminum
chloride
isopropoxy
phenoxy
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38700/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borax Europe Ltd
Original Assignee
Hardman and Holden Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hardman and Holden Ltd filed Critical Hardman and Holden Ltd
Publication of GB806182A publication Critical patent/GB806182A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises organic aluminum compounds of the general formula <FORM:0806182/IV (b)/1> where X and Y are alkoxy, phenoxy, acyloxy or hydroxyl groups, of which only an acyloxy group may occur twice, and a process for the manufacture thereof by reacting aluminum alkoxides, phenoxides, triacylates or alkoxy (or phenoxy) acylates with aluminum chloride or dry hydrogen chloride and if necessary reacting the product with a fatty acid (or a fatty acid anhydride) alone or together with water or with water alone. In preparing compounds containing one hydroxyl group, the amount of water added must not exceed the required equivalent quantity. In examples, aluminum isopropoxide is heated with aluminum chloride to form di-iso propoxy aluminum chloride which is reacted with stearic acid to form aluminum chloride distearate; aluminum isopropoxide is mixed with aluminum powder in hexane, stearic acid added and the mixture heated when aluminum chloride isopropoxy stearate is obtained which on reaction with water yields hydroxy aluminum chloride stearate; di-isopropoxy aluminum chloride dissolved in hexane is mixed with water containing an emulsifying agent and heated to yield aluminum hydroxy isopropoxy chloride; and aluminum di-isopropoxy monophenoxide, dissolved in an inert solvent is treated with dry hydrogen chloride to form aluminum isopropoxy phenoxy chloride, which on reaction with stearic acid is converted to aluminum phenoxy stearate chloride. Aluminum di-isopropoxy monophenoxide is prepared by heating aluminum isopropoxide with phenol.ALSO:Ointments, anti-perspirants and other cosmetic preparations may contain compounds of the following general formula <FORM:0806182/VI/1> where X and Y stand for alkoxy, phenoxy, acyloxy, or hydroxyl groups of which only an acyloxy group may occur twice, in organic media in order to impart thereto a certain degree of acidity.
GB38700/56A 1955-12-19 1956-12-19 Improved process for the preparation of new organic monochloro derivatives Expired GB806182A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL806182X 1955-12-19

Publications (1)

Publication Number Publication Date
GB806182A true GB806182A (en) 1958-12-23

Family

ID=19836610

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38700/56A Expired GB806182A (en) 1955-12-19 1956-12-19 Improved process for the preparation of new organic monochloro derivatives

Country Status (1)

Country Link
GB (1) GB806182A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3100787A (en) * 1960-05-10 1963-08-13 Jr Ludwig Adolph Staib Basic aluminum salts of acetylsalicylate acid and a non-toxic water soluble acid
US3200157A (en) * 1965-08-10 Buls etal alkylation process
US3247264A (en) * 1960-07-22 1966-04-19 Goodrich Gulf Chem Inc Method of manufacturing solid alcohols
US4434178A (en) 1980-10-03 1984-02-28 Hoffmann-La Roche, Inc. Antiperspirants

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3200157A (en) * 1965-08-10 Buls etal alkylation process
US3100787A (en) * 1960-05-10 1963-08-13 Jr Ludwig Adolph Staib Basic aluminum salts of acetylsalicylate acid and a non-toxic water soluble acid
US3247264A (en) * 1960-07-22 1966-04-19 Goodrich Gulf Chem Inc Method of manufacturing solid alcohols
US4434178A (en) 1980-10-03 1984-02-28 Hoffmann-La Roche, Inc. Antiperspirants

Similar Documents

Publication Publication Date Title
Brown et al. Hydroboration. II. A Remarkably Fast Addition of Diborane to Olefins—Scope and Stoichiometry of the Reaction
ES432781A1 (en) Process for bonding and providing nonwovens with an antimicrobial finish
US2000252A (en) Production of acetals
GB806182A (en) Improved process for the preparation of new organic monochloro derivatives
CN108727229B (en) Novel process route for modifying fatty acid type PET reagent precursor
Livingston et al. Activation of the fluorescence of chlorophyll solutions
GB1079314A (en) Process for preparing n-vinyl compounds
US2345573A (en) Process for preparing beta-norborneol and its ether
Colclough et al. The aminolysis and esterification of unsymmetrical epoxides
US2948743A (en) Oxo-aluminum acylates, alkoxides and phenoxides
GB650002A (en) New or improved resinous polyesters and method for their manufacture
US2850512A (en) Titanium ester complexes
US4271317A (en) Alkylborane complexes
DE2151233C3 (en) Process for the reaction of trialkylboranes with proton-containing compounds
Simes et al. Tetraphenylbutadienes via (1, 1-diphenylallyl) lithium
Haynes et al. The alkaloids 8, 14-dihydrosalutaridine and 8, 14-dihydronorsalutaridine from Croton linearis Jacq.
CN115141125B (en) Synthesis method and application of modified long-chain fatty acid type PET reagent precursor
US2787620A (en) Salicylic acid esters
US4046817A (en) Method of synthesis of pyrogallol
GB812787A (en) Method of preparing alkyl boron compounds
GB770156A (en) Manufacture of organo-silicon compounds
ES451930A1 (en) Process for synthesis of coenzyme Q compounds
Parnes et al. One pot synthesis of sodium 14C‐formate
ES486377A1 (en) Process for the preparation of 5-mercapto-1,2,3-triazoles
GB664974A (en) Improvements in or relating to the synthesis of oxygenated organic compounds