GB797391A - Organotitanium compounds - Google Patents
Organotitanium compoundsInfo
- Publication number
- GB797391A GB797391A GB22123/56A GB2212356A GB797391A GB 797391 A GB797391 A GB 797391A GB 22123/56 A GB22123/56 A GB 22123/56A GB 2212356 A GB2212356 A GB 2212356A GB 797391 A GB797391 A GB 797391A
- Authority
- GB
- United Kingdom
- Prior art keywords
- titanate
- methylpentanediol
- acid
- diol
- stearoyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title 1
- -1 aromatic monocarboxylic acid Chemical class 0.000 abstract 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 7
- 150000002009 diols Chemical class 0.000 abstract 7
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 125000002252 acyl group Chemical group 0.000 abstract 4
- 125000004423 acyloxy group Chemical group 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- 150000007524 organic acids Chemical class 0.000 abstract 3
- 229920006395 saturated elastomer Polymers 0.000 abstract 3
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 abstract 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 2
- 125000000962 organic group Chemical group 0.000 abstract 2
- 239000008117 stearic acid Substances 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- KTXWGMUMDPYXNN-UHFFFAOYSA-N 2-ethylhexan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-] KTXWGMUMDPYXNN-UHFFFAOYSA-N 0.000 abstract 1
- ACOQOLIJGGKILA-UHFFFAOYSA-N 2-methylpentane-1,1-diol Chemical compound CCCC(C)C(O)O ACOQOLIJGGKILA-UHFFFAOYSA-N 0.000 abstract 1
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 238000010792 warming Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention comprises diol acyl esters of titanic acid comprising quadrivalent titanium co-valently bonded with organic groups only, the organic groups consisting of diol, acyloxy or alkoxy groups, the diol group consisting of saturated or unsaturated straight- or branched-chain groups, the two hydroxyl groups in the diol groups being attached to carbon atoms separated from each other by not more than 3 carbon atoms, the acyloxy group being derived from a saturated or unsaturated aliphatic or aromatic monocarboxylic acid having from 2 to 20 carbon atoms the alkoxy group containing from 2 to 18 carbon atoms and the diol acyl ester containing from 1 to 3 diol groups and from 1 to 3 acyloxy groups. "Titanic" acid is meant to include both orthotitanic acid and the condensed forms of orthotitanic acid, such, for example, as metatitanic acid. When more than one diol or acyloxy groups are present in the product they may be the same or different. The esters are prepared by reacting acyl titanates with diols. The acyl titanates may be prepared by the reaction between an alkyl titanate and an organic acid or by the reaction between a tetravalent titanium compound, such as TiCl4, and an organic acid or the sodium salt of an organic acid. The acyl group of the titanate employed is derived from an acid containing only one carboxylic group and from 2 to 20 carbon atoms and it may be saturated or unsaturated and aliphatic or aromatic. In the examples: (a) di (2-methylpentanediol-2,4) butyl stearoyl titanate is prepared by adding 2-methylpentanediol-2.4 to a butanol solution of tributyl stearoyl titanate obtained by adding stearic acid to butyl titanate; (b) a condensed 2-methylpentanediol-2.4-stearoyl titanate is prepared by warming a mixture of 2-methylpentanediol-2.4 and condensed distearoyl titanate obtained by reacting titanium tetrachloride with sodium stearate; (c) stearic acid is added to 2-ethylhexyl titanate and the tri-2-ethylhexyl stearoyl titanate so formed is added to 2-methylpentanediol-2.4 to give di(2-methylpentanediol-2.4)-2-ethylhexyl stearoyl titanate; and (d) tri - (2 - methylpentanediol - 2.4) stearoyl titanate; (e) di-(butanediol-1.4) butyl oleoyl titanate; (f) di-(propylene glycol) butyl stearoyl titanate; (g) di-(3.6-dimethyl-4-octynediol-3.6) butyl stearoyl titanate; (h) di-(2-methylpentanediol-2.4) butyl benzoyl stearate; (j) di-(2-ethylhexanediol-1.3) acetyl titanate; (k) di-(2.2.4-trimethylpentanediol-2.4) myristoyl titanate; (1) 2-methylpentanediol-2.4-butyl distearoyl titanate; (m) di-(2-methylpentanediol-2.4) distearoyl titanate; (n) di-(2.5-dimethylhexanediol-2.5) stearoyl titanate and di-(2.5-dimethyl-3-hexynediol-2.5) stearoyl titanate are all formed by analogous methods. The product of (d) is treated with water and heated to give a condensed diol acyl titanate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US797391XA | 1955-08-17 | 1955-08-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB797391A true GB797391A (en) | 1958-07-02 |
Family
ID=22152496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22123/56A Expired GB797391A (en) | 1955-08-17 | 1956-07-17 | Organotitanium compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB797391A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3432323A (en) * | 1964-08-21 | 1969-03-11 | Laporte Titanium Ltd | Polymeric organic titanate treated tio2 pigment |
| DE2623472A1 (en) * | 1975-09-30 | 1977-04-07 | Kenrich Petrochemicals | ORGANO-ALPHA, OMEGA-ALKYLENE TITANATE |
-
1956
- 1956-07-17 GB GB22123/56A patent/GB797391A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3432323A (en) * | 1964-08-21 | 1969-03-11 | Laporte Titanium Ltd | Polymeric organic titanate treated tio2 pigment |
| DE2623472A1 (en) * | 1975-09-30 | 1977-04-07 | Kenrich Petrochemicals | ORGANO-ALPHA, OMEGA-ALKYLENE TITANATE |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3056817A (en) | Ester synthesis | |
| US3396185A (en) | Polymeric organo tin mercaptides and carboxylates and the preparation thereof | |
| US3082189A (en) | Halogen resins stabilized with polyhydric alcohols phosphites | |
| ES399325A1 (en) | Process for preparing acid esters of 4-piperidinol derivatives and their use as stabilizers | |
| GB859644A (en) | Process for preparing polyesters from lactones | |
| GB859645A (en) | Process for preparing lactone adducts and polyesters | |
| GB815875A (en) | Improved composition for the stabilization of halogen-containing resins | |
| GB797391A (en) | Organotitanium compounds | |
| US3019247A (en) | New organotin derivatives | |
| US2938013A (en) | Vinyl chloride resin stabilized with dibutyl tin bis | |
| Pande et al. | Titanium salts of mono‐carboxylic acids. II. Reaction of Titanium Isopropoxide and ethoxide with acetic anhydride | |
| US2766266A (en) | Substituted 1, 5-pentanediol esters | |
| UST864003I4 (en) | Defensive publication | |
| GB921057A (en) | Process for the production of organo-tin compounds self-emulsifiable with water | |
| ES353920A1 (en) | Alpha,omega-bis(fluoroperhaloisopropoxy) - perfluoroalkanes and process for preparing them | |
| GB1408150A (en) | Process for preparing polyesters | |
| GB610138A (en) | Process for stabilising highly polymeric linear esters | |
| GB1392562A (en) | Antiperspirant compositions | |
| GB865967A (en) | Lactone adducts | |
| US2346202A (en) | Production of isocyanic acid esters | |
| US2821538A (en) | Novel carbonic acid diesters of an aliphatic alcohol and a polyglycol monoether | |
| US3243447A (en) | Preparation of spacial tetrameric acyloxy group iv metal oxides | |
| Hussain et al. | Synthesis and structural characterization of organotin (IV) complexes formed with [O, O] donor atoms of carboxylic acids | |
| UST862017I4 (en) | Defensive publication | |
| GB804278A (en) | Fuel composition |