GB793532A - New monoazo dyestuffs and process for making them - Google Patents
New monoazo dyestuffs and process for making themInfo
- Publication number
- GB793532A GB793532A GB36384/54A GB3638454A GB793532A GB 793532 A GB793532 A GB 793532A GB 36384/54 A GB36384/54 A GB 36384/54A GB 3638454 A GB3638454 A GB 3638454A GB 793532 A GB793532 A GB 793532A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- dyestuffs
- phenyl
- pyrazolone
- aniline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
- C09B29/3647—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms
- C09B29/3652—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms containing a 1,2-diazoles or hydrogenated 1,2-diazoles
- C09B29/366—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms containing a 1,2-diazoles or hydrogenated 1,2-diazoles containing hydroxy-1,2-diazoles, e.g. pyrazolone
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises dyestuffs, preferably of the pyrazolone series, which contain a group of formula <FORM:0793532/IV (b)/1> where X is H or a hydrocarbon radicle, B is a b - or a -haloalkyl residue and when X is a hydrocarbon radicle there must be present a group imparting solubility in water, advantageously an SO3H group. Advantageously the halogen atom is in the a -position of the alkyl residue. X may be an aliphatic, cycloaliphatic, araliphatic or aromatic hydrocarbon radicle. Further specified substituents for the dyestuffs are COOH, SO3H, SONH2, MeSO2, NO2, halogen, acylamino, alkyl and alkoxy groups. A preferred series of dyestuffs has the formula <FORM:0793532/IV (b)/2> where R and R1 are benzene residues and one X is H and the other an -SO2-NHCOCH2Cl group. The dyestuffs may be made by acylating a sulphonamide group of an appropriate dyestuff using as acylating agent a halide or anhydride of an aliphatic halogen-carboxylic acid such as a - and b -chloro-propionic acid chloride, bromacetyl bromide and chloracetyl chloride and the corresponding anhydrides. The acylation is effected in conventional fashion in the presence of diluents and acid-binding agents and preferably with an excess of acylating agent. The starting dyestuffs may be made by conventional methods. Specified diazo components are aniline-2-, -3- and -4-sulphonamides and sulphon-methyl-, -ethyl-, -butyl-, -hexyl- and -phenyl-amides, 4-methyl-aniline-2- and -3- sulphonamides, 2-methoxy-aniline-3-, -4- and -5-sulphonamides, 2 - naphthylamine - 6 - sulphonamide, aniline, o-, m- and p-chloranilines, 2,5-dichloroaniline, nitranilines, toluidines, aniline-3-and -4-methyl sulphones and sulphonic acids and 1 - amino - 2 - naphthol - 4 - sulphonic acid. Specified coupling components are 2-amino- and -hydroxy - naphthalene - 6 - sulphonamide, 1 - (a - naphthyl) - 3 - methyl - 5 - pyrazolone, 1 - phenyl - 3 - methyl - 5 - pyrazolone - 21-, -31-and -41-sulphonamide and sulphonmethylamide, 1 - phenyl - 3 - methyl - 5 - pyrazolone - 21 - chloro - 51 - sulphonamide, 1 - phenyl -, -(21-, 31- and 41-chloro- and 41-nitro-phenyl)-3-methyl - 5 - pyrazolones, 1 - phenyl - 3 - methyl - 5-pyrazolone-31- and -41-sulphonic acids and 1 - phenyl - 5 - pyrazolone - 3 - carboxylic acid. The dyestuffs dye leather, silk, wool and super-poly-amides and -urethanes from weakly acid to weakly alkaline baths. Examples are provided illustrating the preparation of dyestuffs from certain of the above specified components and their use in dyeing wool in orange or yellow shades.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH793532X | 1953-12-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB793532A true GB793532A (en) | 1958-04-16 |
Family
ID=4537142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB36384/54A Expired GB793532A (en) | 1953-12-15 | 1954-12-15 | New monoazo dyestuffs and process for making them |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB793532A (en) |
-
1954
- 1954-12-15 GB GB36384/54A patent/GB793532A/en not_active Expired
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