GB792035A - Pesticidal compositions - Google Patents
Pesticidal compositionsInfo
- Publication number
- GB792035A GB792035A GB20576/56A GB2057656A GB792035A GB 792035 A GB792035 A GB 792035A GB 20576/56 A GB20576/56 A GB 20576/56A GB 2057656 A GB2057656 A GB 2057656A GB 792035 A GB792035 A GB 792035A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- isopropylphenol
- dimethylaminomethyl
- salt
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Hydrogenated Pyridines (AREA)
Abstract
Compounds of the formula: (CH3)2NOCO-A-CH2Y wherein A is phenyl, alkyl substituted phenyl (the alkyl portion containing not over 4 C atoms), nitrophenyl, or chlorophenyl and Y is lower dialkylamino having not over two carbon atoms per alkyl group, N-piperidino, N-morpholino or N-pyrrolidino are prepared by reacting a dimethyl carbamyl halide with a tertiary-aminomethylphenol, or an alkali metal salt of a tertiary-aminomethylphenol. In an example, 4 - dimethylaminomethyl - 2 - methyl-5-isopropylphenol and dimethylcarbamyl chloride in anhydrous pyridine are heated under reflux to produce the dimethylcarbamate of 4-dimethylaminomethyl - 2 - methyl - 5 - isopropylphenol. The acid oxalate may be prepared by adding excess oxalic acid to the base in absolute alcohol and the pure base may be obtained by treating a solution of the purified oxalate with sodium carbonate. Other dialkyl-carbamates of dialkylaminomethylphenols and their salts may be prepared in a similar manner or by reacting a dialkyl-carbamylchloride with an aqueous solution of an alkali metal salt of a dialkylaminomethylphenol. Specified compounds are the dimethylcarbamates of (1) 2-dimethylaminomethylphenol; (2) 4-dimethylaminomethylphenol; (3) 4-dimethylaminomethyl - 2 - methyl - 5 - isopropylphenol; (4) 4 - piperidinomethyl - 2 - methyl - 5 - isopropylphenol; (5) 4-piperidinomethyl-3,6-dimethylphenol; (6) 4-piperidinomethyl-3-methyl-6-isopropylphenol; (7) 4-piperidinomethyl-3-methyl-6 - tert. - butylphenol; (8) 2 - dimethylaminomethyl - 4 - tert. - butylphenol; (9) 2 - dimethylaminomethyl - 4 - (a ,a ,g ,g - tetra - methylbutyl) - phenol; (10) 2 - dimethylaminomethyl - 4 - chlorophenol; (10) 2 - dimethylaminomethyl - 4 - methylphenol; (12) 2 - dimethylaminomethyl - 4 - nitrophenol; (13) 4 - pyrrolidinomethyl - 2 - methyl - 5 - isopropylphenol, neutral oxalate salt of 1, hydrochloride salt of 2, acid oxalate salt of 3, acid oxalate salt of 4, acid oxalate salt of 5, acid oxalate salt of 6, acid oxalate salt of 7, acid oxalate salt of 8, acid oxalate salt of 9, acid oxalate salt of 10, acid oxalate salt of 11, hydrochloride salt of 12, acid oxalate salt of 13.ALSO:A pesticidal composition comprises a toxicant of the formula (CH3)2NOCO-A-CH2Y, wherein A is phenyl, alkyl substituted phenyl, the alkyl portion containing not over 4 carbon atoms, nitro-phenyl, or chlorophenyl and Y is lower dialkylamino having not over two carbon atoms per alkyl group, N-piperidino, N-morpholino or N-pyrrolidino, preferably in an amount of at least 0.003 per cent of the total composition and either in the form of free base, an acid salt or partially in the form of an acid salt, together with a non-phytotoxic carrier substance. The composition may be applied in dust form or with usual inert diluents sprayed as a liquid, e.g. solutions, emulsions, dispersions with usual wetting, emulsifying and surface-active agents or as an aerosol dissolved in acetone and heavy petroleum oil with a propellant, e.g. methyl chloride or dichloro difluoromethane. Other pesticides and fungicides and casein and blood may also be incorporated. The toxicant may be a dimethyl carbamate of a dialkylaminomethylphenol having not over 2 carbon atoms in each alkyl group therefore or a dimethylcarbamate of a lower dialkylaminomethyllower alkylphenol, the N-alkyl groups each containing not over two carbon atoms. Examples of many specified toxicants are the oxalates of dimethylcarbamates of 2-methyl-4-piperidinomethyl-5-isopropylphenol, 2 - methyl - 4 - pyrrolidinomethyl - 5 - isopropylphenol, 2 - methyl - 4 - morpholino - methyl - 5 - isopropylphenol, 3-methyl - 4 - piperidino - 6 - isopropylphenol, as well as of 2-methyl-4-dimethylaminomethyl-5-isopropylphenol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB20576/56A GB792035A (en) | 1956-07-03 | 1956-07-03 | Pesticidal compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB20576/56A GB792035A (en) | 1956-07-03 | 1956-07-03 | Pesticidal compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB792035A true GB792035A (en) | 1958-03-19 |
Family
ID=10148188
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20576/56A Expired GB792035A (en) | 1956-07-03 | 1956-07-03 | Pesticidal compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB792035A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1618722B1 (en) * | 1966-01-04 | 1970-02-19 | Philips Nv | 4-dimethyllaminomethylphenyl-N-methyl-carbamate |
-
1956
- 1956-07-03 GB GB20576/56A patent/GB792035A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1618722B1 (en) * | 1966-01-04 | 1970-02-19 | Philips Nv | 4-dimethyllaminomethylphenyl-N-methyl-carbamate |
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