GB785348A - - Google Patents

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Publication number
GB785348A
GB785348A GB785348DA GB785348A GB 785348 A GB785348 A GB 785348A GB 785348D A GB785348D A GB 785348DA GB 785348 A GB785348 A GB 785348A
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United Kingdom
Prior art keywords
aluminium
hydride
metal
hydrogen
hydrides
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Publication of GB785348A publication Critical patent/GB785348A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof

Abstract

785,348. Aluminium hydride; metal aluminium hydrides. FARBENFABRIKEN BAYER AKT.-GES. July 12, 1955 [July 12, 1954], No. 20141/55. Class 1 (2). Metal aluminium hydrides or aluminium hydride are prepared by reacting an aluminium halide with a finely divided mixture of a metal hydride with a metal which does not react with hydrogen to form a stable hydride. The finely divided mixture may be prepared, as in Specification 777,096, by the action of hydrogen on an alloy of a hydride-forming metal and a metal which does not react with hydrogen to form a stable hydride, the alloy being in a finely divided form and substantially free from other elements. Hydrides may be CaH 2 or MgH 2 and metals, which are unaffected during the reaction, may be copper and aluminium. In the example a suspension of magnesium hydride and aluminium in ether is boiled under reflux with aluminium chloride to form AlH 3 or Mg(AlH 4 ) 2 in ether solution, which is filtered off. The magnesium chloride and aluminium powder may be separated by melting or dissolving.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0469463A1 (en) * 1990-07-31 1992-02-05 Studiengesellschaft Kohle mbH Metal-magnesium compounds, process for preparing same and the use thereof for the preparation of finely divided metal and alloy powders and intermetallic compounds
US5565183A (en) * 1993-10-27 1996-10-15 Th. Goldschmidt Ag Method for the preparation of aluminum hydride (AlH3) by reacting magnesium hydride with aluminum halide
US5831103A (en) * 1992-10-20 1998-11-03 Th. Goldschmidt Ag Halogen-magnesium-aluminum hydridohalides, methods for their synthesis and their use as reducing agents

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0469463A1 (en) * 1990-07-31 1992-02-05 Studiengesellschaft Kohle mbH Metal-magnesium compounds, process for preparing same and the use thereof for the preparation of finely divided metal and alloy powders and intermetallic compounds
US5385716A (en) * 1990-07-31 1995-01-31 Studiengesellschaft Kohle Mbh Metal-magnesium compounds, process for preparing same and the use thereof for the preparation of finely divided metal and alloy powders and intermetallic compounds
US5498402A (en) * 1990-07-31 1996-03-12 Studiengesellschaft Kohle Mbh Metal-magnesium compounds
US5831103A (en) * 1992-10-20 1998-11-03 Th. Goldschmidt Ag Halogen-magnesium-aluminum hydridohalides, methods for their synthesis and their use as reducing agents
US5565183A (en) * 1993-10-27 1996-10-15 Th. Goldschmidt Ag Method for the preparation of aluminum hydride (AlH3) by reacting magnesium hydride with aluminum halide

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