GB776295A - Improvements in the chlorination of titaniferous ores - Google Patents
Improvements in the chlorination of titaniferous oresInfo
- Publication number
- GB776295A GB776295A GB2569054A GB2569054A GB776295A GB 776295 A GB776295 A GB 776295A GB 2569054 A GB2569054 A GB 2569054A GB 2569054 A GB2569054 A GB 2569054A GB 776295 A GB776295 A GB 776295A
- Authority
- GB
- United Kingdom
- Prior art keywords
- line
- solids
- bed
- gases
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
- C22B1/08—Chloridising roasting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1268—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams
- C22B34/1272—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams reduction of titanium halides, e.g. Kroll process
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
<PICT:0776295/III/1> A process for chlorinating a titaniferous material at 600-1050 DEG C., preferably 850 to 1000 DEG C., in the presence of a reducing agent in a fluidized bed is characterized in that a portion of the bed is withdrawn, cooled and returned; and in that gaseous reaction products are removed from the bed, passed to a zone in which they undergo direct heat exchange with the fresh titaniferous material which is to be charged to the bed and are separated from said material, after such chlorination products are recovered from the gaseous products. The Specification refers to ilmenite, rutile and titanium oxide concentrates as the titaniferous materials; to solid carbonaceous reducing agents such as carbon, coal or coke, which may be charged into the bed in admixture with the titaniferous material in suspension in the chlorinating gas or may be charged separately; to gaseous reducing agents such as carbon monoxide; and as chlorinating gases to pure chlorine, chlorine diluted with nitrogen or carbon monoxide, the tail gases from oxidation of titanium tetrachloride by air and chlorine compounds such as carbon tetrachloride, sulphuryl chloride, sulphur monochloride and phosgene, the latter rendering an additional reducing agent unnecessary. In the embodiment illustrated, a finely ground mixture of carbonaceous reducing agent and titaniferous material (e.g. 1 part coke to 5 parts rutile or ilmenite by weight), are introduced from hopper A into line 2 in which it mixes with hot gases discharged from reactor B. The solids are separated in cyclone C and products (titanium tetrachloride and ferric chloride), are recovered from the gases emerging through line 15. The solids are passed via lines 3 and 4 into the reactor by means of the chlorine-containing gas entering through valve 25 so as to have a velocity e.g. of 1.0 to 10 feet per second in the reactor to maintain the solids therein in a fluidized state. The cooling is effected by withdrawing solids from the bed by line 5 and passing them by means of an inert gas (e.g. the uncondensable gas from the titanium tetrachloride recovery system) through line 6 and cooler D. This cooling may be supplemented by passing the preheated solids in standpipe 3 through the cooler F by means of an inert gas (e.g. said uncondensable gas) introduced through line 1611 or by cooling the solids between the cyclone C and line 4. It is preferred to allow the non-volatilizable materials and ash residues in B to accumulate to give a low titanium dioxide content of say 10 to 20 per cent, and remove said materials intermittently, but continuous removal is possible. The material may be removed via lines 6 and 7. If desired the reaction chamber may be preheated or the temperature maintained during the reaction by burning fuel therein, by introducing combustion products from an oil burner or other source through line 16, or by external heating, or by introducing air or oxygen to the reaction zone. Details are given of flow rates for gases and particle sizes; in examples the illustrated apparatus is used in one case and in another a long narrow silica tube is employed as reactor and the preheated solid reactants are added at the top through a long delivery tube.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2569054A GB776295A (en) | 1954-09-03 | 1954-09-03 | Improvements in the chlorination of titaniferous ores |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2569054A GB776295A (en) | 1954-09-03 | 1954-09-03 | Improvements in the chlorination of titaniferous ores |
Publications (1)
Publication Number | Publication Date |
---|---|
GB776295A true GB776295A (en) | 1957-06-05 |
Family
ID=10231714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2569054A Expired GB776295A (en) | 1954-09-03 | 1954-09-03 | Improvements in the chlorination of titaniferous ores |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB776295A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0315985A2 (en) † | 1987-11-10 | 1989-05-17 | E.I. Du Pont De Nemours And Company | Improved fluidized bed process for chlorinating titanium-containing material |
EP0714992A1 (en) * | 1994-12-01 | 1996-06-05 | KRONOS TITAN-GmbH | Method for increased yield when chlorinating titaniferous materials |
CN102774880A (en) * | 2012-08-08 | 2012-11-14 | 中国科学院过程工程研究所 | Device of boiling chlorination furnace for continuous slagging and slagging method |
RU2797475C2 (en) * | 2019-12-30 | 2023-06-06 | Александр Александрович Семенов | Method for producing rare metal tetrachlorides using sulphur |
-
1954
- 1954-09-03 GB GB2569054A patent/GB776295A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0315985A2 (en) † | 1987-11-10 | 1989-05-17 | E.I. Du Pont De Nemours And Company | Improved fluidized bed process for chlorinating titanium-containing material |
EP0315985B2 (en) † | 1987-11-10 | 2000-10-11 | E.I. Du Pont De Nemours And Company | Improved fluidized bed process for chlorinating titanium-containing material |
EP0714992A1 (en) * | 1994-12-01 | 1996-06-05 | KRONOS TITAN-GmbH | Method for increased yield when chlorinating titaniferous materials |
CN102774880A (en) * | 2012-08-08 | 2012-11-14 | 中国科学院过程工程研究所 | Device of boiling chlorination furnace for continuous slagging and slagging method |
CN102774880B (en) * | 2012-08-08 | 2014-07-30 | 中国科学院过程工程研究所 | Device of boiling chlorination furnace for continuous slagging and slagging method |
RU2797475C2 (en) * | 2019-12-30 | 2023-06-06 | Александр Александрович Семенов | Method for producing rare metal tetrachlorides using sulphur |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4389391A (en) | Process for beneficiating titaniferous ores | |
US2701179A (en) | Metal halide production | |
US2486912A (en) | Process for producing titanium tetrachloride | |
EP0416015A1 (en) | Process for preparing titanium dioxide. | |
US4140746A (en) | Recovery of chlorine values from iron chloride by-produced in chlorination of ilmenite and the like | |
US3591333A (en) | Method of chlorinating titanium-bearing materials | |
US4854972A (en) | Nitrogen-free process for chloride-route TiO2 pigment manufacture | |
US3989510A (en) | Manufacture of titanium chloride and metallic iron from titaniferous materials containing iron oxides | |
US4183899A (en) | Chlorination of ilmenite and the like | |
US3787556A (en) | Method for preparing titanium tetrachloride | |
US2790703A (en) | Process for the production of titanium tetrachloride | |
US4046853A (en) | Production of titanium tetrachloride | |
GB776295A (en) | Improvements in the chlorination of titaniferous ores | |
US4055621A (en) | Process for obtaining titanium tetrachloride, chlorine and iron oxide from ilmenite | |
EP0173132A2 (en) | Two stage chlorination of titaniferous ore with FeCl3 reclamation | |
US4619815A (en) | Chlorination of iron-containing metaliferous material | |
US3944647A (en) | Recovering chlorine from the chlorination of titaniferous material | |
US4994255A (en) | Oxidation of ferrous chloride directly to chlorine in a fluid bed reactor | |
US4629607A (en) | Process of producing synthetic rutile from titaniferous product having a high reduced titanium oxide content | |
CA1113225A (en) | Recovery of chlorine values | |
US2940827A (en) | Discharge of solid by-products separated from chlorination gases | |
US3050362A (en) | Process for producing titanium tetrachloride | |
US3149911A (en) | Process for producing titanium tetrachloride | |
US4179489A (en) | Chlorination of iron-containing materials | |
US3295921A (en) | Production of halides |