GB774805A - Improvements in or relating to a process for producing a thermosetting resinous molding composition - Google Patents

Improvements in or relating to a process for producing a thermosetting resinous molding composition

Info

Publication number
GB774805A
GB774805A GB18538/54A GB1853854A GB774805A GB 774805 A GB774805 A GB 774805A GB 18538/54 A GB18538/54 A GB 18538/54A GB 1853854 A GB1853854 A GB 1853854A GB 774805 A GB774805 A GB 774805A
Authority
GB
United Kingdom
Prior art keywords
extruder
maintained
pellets
zones
diameter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18538/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB774805A publication Critical patent/GB774805A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion

Abstract

A thermosetting resinous moulding composition is made by pulverizing thermosetting resinous material to a particle size within the range of 44-1410 microns, continuously introducing the pulverized material into a zone divided into a plurality of sub-zones maintained at different temperatures and wherein continuous densification of the material occurs, all of said temperatures being above 20 DEG C. but below 150 DEG C., continuously removing the densified material from the zone in an extruded form and continuously cutting into pellets and cooling said material to room temperature. When starting with a dry resin, the resin (if desired, with a fibrous or non-fibrous filler, a dye, a pigment, a metallic powder, a mould lubricant or a curing catalyst is introduced into a continuous pulverizer. When starting with a resinous syrup, the syrup (together if desired with any of the additions mentioned above) is, prior to pulverization, introduced into a mixer maintained at 100-160 DEG F., and if desired under pressure and is then passed to a continuous dryer maintained at a temperature of 100-215 DEG F. dry bulk and 80-140 DEG F. wetbulk where the volatile content of the syrup is reduced to less than 15 per cent by weight. In either case, the pulverized material is passed to an extruder wherein a plurality of heating zones are maintained, the temperatures in which may increase or decrease in the direction of motion or may first increase, then decrease and again increase. Vacuum may be applied to a section of the extruder to remove volatiles. The densified material may be extruded with or without a die and cut into pellets having a diameter and length ranging from 0.025-0.10 inches. Cooling (e.g. in a water-cooled rotating cooler) may be effected before or after cutting the material into pellets. The resin may be derived from an aldehyde and a phenol, an aminotriazine, an aminotriazole, a urea, a urea and an aminotriazine, an aminodiazine, a protein or a polyamide. Also it may be shellac, a polymerizable unsaturated polyester or a mixture of such a polyester and a polymerizable compound containing a CH2=C< group. The Specification lists many examples of specific resins, fillers, mould lubricants, dyes, pigments and curing catalysts. In examples: (1) a mixture of melamine-formaldehyde resin, an aniline-formaldehyde resin modified by mono-m-p-cresyl glyceryl ether, alpha cellulose, magnesium oxide and cadmium red were ground and introduced into an extruder having zones heated to 20 DEG C., 100 DEG C. and 70 DEG C., or 150 DEG C., 100 DEG C. and 20 DEG C.; (2) a mixture of melamine-formaldehyde resin, aniline - cresol - formaldehyde resin, anilineshellac-formaldehyde resin cotton flock, calcined asbestos and zinc stearate was ground and densified in an extruder having zones maintained at 20 DEG C., 120 DEG C., 45 DEG C. and 62 DEG C.; (3) and (4) a mixture of melamine-formaldehyde resin, aniline-cresol-formaldehyde resin, wood flour, calcium stearate, cadmium red and magnesium oxide was ground and densified in an extruder having two zones maintained at 100 DEG and 65 DEG C., or three zones maintained at 20 DEG C., 100 DEG C. and 60 DEG C.; (5) a mixture of a urea-formaldehyde resinous syrup, wood flour, barium sulphate and zinc palmitate was blended in a vessel maintained at 120-130 DEG F., dried in a continuous dryer having a dry-bulk temperature of 160 DEG C. and a wet-bulk temperature of 115 DEG C., pulverized and passed to an extruder having zones at 20 DEG C., 85 DEG C. and 80 DEG C.; (6) a mixture of urea-formaldehyde resinous syrup, alpha cellulose, tetrachlorophthalic anhydride, hexamethylene tetramine, zinc palmitate and barium sulphate was blended in a vessel maintained at 125 DEG F., dried in a continuous dryer having a drybulk temperature of 160 DEG F. and a wet-bulk temperature of 115 DEG F., pulverized and passed to an extruder having zones at 20 DEG C., 120 DEG C., 65 DEG C. and 105 DEG C.; (8) a mixture of an ethylene glycol - maleic anhydride polyester, diallyl phthalate, a urea-dicyandiamide-formaldehyde resin, cotton flock and clay was ground, benzoyl peroxide, ditertiary butyl paracresol and zinc stearate added and the mixture introduced into an extruder having zones at 20 DEG C., 70 DEG C., 65 DEG C., 80 DEG C. and 60 DEG C.; (9) a mixture of a phenol-formaldehyde novolak resin, hexamethylene tetramine, wood flour and zinc stearate was ground and then densified in an extruder with zones maintained at 20 DEG C., 70 DEG C., 95 DEG C., 110 DEG C., and 90 DEG C. In Examples (1)-(7) the extruder screws rotate at 40 or 60 r.p.m. and the material is extruded through a 2 inch die area having 119 or 300 holes each having a diameter of 0.072 inch, the material then being cut by rotating knife blades into pellets having length and diameter of 0.072 inch. In Examples (8) and (9), the material was extruded through a 2 inch die area containing 104 holes, each having 0.122-0.144 inch tapered diameter, the material then being cut by rotating knife blades into pellets having a diameter and length of about 0.130 inch.ALSO:A thermosetting resinous moulding composition is made by pulverizing thermosetting resinous material to a particle size within the range of 44-1410 microns, continuously introducing the pulverized material into a zone divided into a plurality of sub-heating zones maintained at different temperatures and wherein continuous densification of the material occurs, all of said temperatures being above 20 DEG C. but below 150 DEG C., continuously removing the densified material from the zone in an extruded form and continuously cutting into pellets and cooling said material to room temperature. When starting with a dry resin, the resin (together if desired with a fibrous or non-fibrous filler, a dye, a pigment, a metallic powder, a mould lubricant or a curing catalyst 1 is introduced into a continuous pulverizer. When starting with a resinous syrup, the syrup (together if desired, with any of the additions mentioned above) is, prior to pulverization, introduced into a mixer maintained at 100 DEG -160 DEG F. and if desired under pressure and is then passed to a continuous dryer maintained at a temperature of 100 DEG -215 DEG F. dry-bulb and 80 DEG -140 DEG F. wet-bulb where the volatile content of the syrup is reduced to less than 15 per cent by weight. In either case, the pulverized material is passed to an extruder wherein a plurality of heating zones are maintained, the temperature in which may increase or decrease in the direction of motion or may first increase, then decrease and again increase. Vacuum may be applied to a section of the extruder to remove volatiles. The densified material may be extruded with or without a die and cut into pellets having a diameter and length ranging from 0,025-0,10 inches. Cooling (e.g. in a water-cooled rotating cooler) may be effected before or after cutting the material into pellets. In examples (1)-(7) the extruder screws rotate at 40 or 60 r.p.m. and the densified material is extruded through a 2 inch die having 119 or 300 holes each having a diameter of 0,072 inches, the material then being cut by rotating knife blades into pellets having lengths and diameter of 0,072 inches. In examples (8) and (9), the material was extruded through a 2 inch die area containing 104 holes each having 0,122-0,144 inch tapered diameter; the material then being cut by rotating knife blades into pellets having a diameter and length of about 0,130 inches.
GB18538/54A 1953-06-26 1954-06-24 Improvements in or relating to a process for producing a thermosetting resinous molding composition Expired GB774805A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US774805XA 1953-06-26 1953-06-26

Publications (1)

Publication Number Publication Date
GB774805A true GB774805A (en) 1957-05-15

Family

ID=22138297

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18538/54A Expired GB774805A (en) 1953-06-26 1954-06-24 Improvements in or relating to a process for producing a thermosetting resinous molding composition

Country Status (1)

Country Link
GB (1) GB774805A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3174940A (en) * 1961-02-17 1965-03-23 Rhoads Molded Products Inc Process of preparing a molded article from a thermosetting formaldehyde resin and sawdust
DE2351545A1 (en) * 1972-11-06 1974-05-16 Gen Electric INJECTION PROCESSABLE HEAT-CURING COMPOSITION AND METHOD FOR MANUFACTURING IT
WO2003016011A1 (en) * 2001-08-21 2003-02-27 Owens Corning Moldable pellet based on the combination of synthetic cellulose fibers and thermoplastic polymers
EP2099721A1 (en) * 2006-11-21 2009-09-16 Young-Bok Kim The production method of building materials and vessels using environment-friendly yellow earth

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3174940A (en) * 1961-02-17 1965-03-23 Rhoads Molded Products Inc Process of preparing a molded article from a thermosetting formaldehyde resin and sawdust
DE2351545A1 (en) * 1972-11-06 1974-05-16 Gen Electric INJECTION PROCESSABLE HEAT-CURING COMPOSITION AND METHOD FOR MANUFACTURING IT
WO2003016011A1 (en) * 2001-08-21 2003-02-27 Owens Corning Moldable pellet based on the combination of synthetic cellulose fibers and thermoplastic polymers
US6756114B2 (en) 2001-08-21 2004-06-29 Owens Corning Fiberglas Technology, Inc. Moldable pellet based on the combination of synthetic cellulose fibers and thermoplastic polymers
EP2099721A1 (en) * 2006-11-21 2009-09-16 Young-Bok Kim The production method of building materials and vessels using environment-friendly yellow earth
EP2099721A4 (en) * 2006-11-21 2011-06-22 Young-Bok Kim The production method of building materials and vessels using environment-friendly yellow earth
US8696959B2 (en) 2006-11-21 2014-04-15 Industry-Academic Cooperation Foundation, The Catholic University Of Korea Production method of building materials and vessels using environment-friendly yellow earth

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