GB772820A - Improvements in sequestering polyvalent metal ions - Google Patents

Improvements in sequestering polyvalent metal ions

Info

Publication number
GB772820A
GB772820A GB4166/55A GB416655A GB772820A GB 772820 A GB772820 A GB 772820A GB 4166/55 A GB4166/55 A GB 4166/55A GB 416655 A GB416655 A GB 416655A GB 772820 A GB772820 A GB 772820A
Authority
GB
United Kingdom
Prior art keywords
carboxymethyl
hexityl
methyl
glucyl
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4166/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlas Powder Co
Original Assignee
Atlas Powder Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlas Powder Co filed Critical Atlas Powder Co
Publication of GB772820A publication Critical patent/GB772820A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/01Separation of suspended solid particles from liquids by sedimentation using flocculating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00Regeneration or reactivation of ion-exchangers; Apparatus therefor

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A process of sequestering polyvalent heavy metal ions having an atomic number greater than 24 comprises bringing together in solution salts of said heavy metals and a compound containing no more than two carboxyl bearing carbon atoms of the formula <FORM:0772820/IV(b)/1> wherein the empirical radical C6H13O5 represents the hexane pentol residue of a hexityl amine; R is hydrogen, (C1-C3) alkyl or (C2-C3) hydroxyalkyl; Y is hydrogen or an alkali metal; n is 1 or 2; a is 0 or 1; b is 0, 1 or 2; c is 0 or 1; d is 0 or 1 and a+b+c+d=2. Ions capable of being sequestered are Ce++++, Cd++, Cu++, Fe++, Fe+++, Sn++, Hg++, Bi+++, Co++, Zn++, As+++, Sb+++, Ti++++, Zr++++, Mn++, Ni++ and Pb++. Specified sequestering agents are N-methyl N-carboxymethyl, N - methyl N - carboxyethyl, N - ethyl N - carboxymethyl, N - ethyl N - carboxyethyl, N - 2 - hydroxyethyl N - carboxymethyl, N-carboxymethyl and N - propyl N - carboxymethyl glucamines; N-methyl N-carboxymethyl, N : N-bis - carboxymethyl and N - carboxymethyl fructamines; glucamine diacetic acid; glucamine dipropionic acid; N-methyl N-glucyl, N-ethyl N-glucyl, N-glucyl and N-fructyl aspartic acids; N-methyl N-glucyl, N-ethyl N-glucyl, N-glucyl, N-fructyl and N-methyl N-fructyl aminomalonic acids. N : N-Bis-(carboxyalkyl) hexityl amines are prepared by reacting 2 moles. of an o -halogen fatty acid with one mole. of a hexityl amine. N-hexityl and N-alkyl N-hexityl aspartic acids are prepared by reacting equimolar amounts of an alkali maleate and a hexityl or N-alkyl hexityl amine. N-Alkyl N-hexityl aminomalonic acids are prepared by reacting equimolar amounts of a halomalonic acid and an N-alkyl hexityl amine. Specification 771,698 is referred to.ALSO:Iron may be prevented from precipitating during the kier boiling of cotton with sodium hydroxide and subsequent peroxide bleaching by the addition of a sequestering agent containing no more than two carboxyl bearing carbon atoms of the formula <FORM:0772820/IV(b)/1> wherein the empirical radical C6H13O5 represents the hexane pentol residue of a hexityl amine; R is hydrogen, (C1-C3) alkyl or (C2-C3) hydroxyalkyl; Y is hydrogen or an alkali metal; n is 1 or 2; a is 0 or 1; b is 0, 1 or 2; c is 0 or 1; d is 0 or 1 and the sum of a, b c and d is 2. Specified sequestering agents are N - methyl - N - carboxymethyl, N - methyl - N - carboxyethyl, N - ethyl - N - carboxymethyl, N ethyl - N - carboxyethyl, N - 2 - hydroxyethyl - N - carboxymethyl, N - carboxymethyl and N - propyl - N - carboxymethyl glucamines; N - methyl - N - carboxymethyl, N : N - bis-carboxymethyl and N-carboxymethyl fructamines; glucamine diacetic acid; glucamine dipropionic acid; N - methyl - N - glucyl, N - ethyl - N - glucyl, N - glucyl and N - fructyl aspartic acids; N - methyl - N - glucyl, N - ethyl-N - glucyl, N - glucyl, N - fructyl and N-methyl - N - fructyl aminomalonic acids. Other sequestering agents such as ethylenediamine tetraacetic acid may be used in conjunction with the above sequestrants.ALSO:Compounds containing no more than two carboxyl bearing carbon atoms of the formula <PICT:0772820/III/1> wherein the empirical radical C6H13O5 represents the hexane pentol residue of a hexityl amine; R is hydrogen, (C1-C3) alkyl or (C2-C3) hydroxyalkyl; Y is hydrogen or an alkali metal; n is 1 or 2; a is 0 or 1; b is 0, 1 or 2; c is 0 or 1; d is 0 or 1; and the sum of a, b, c and d is 2, alone or in conjunction with other sequestering agents such as ethylenediamine tetraacetic acid, are used to sequester polyvalent heavy metal ions having an atomic number greater than 24. For this purpose the above compounds are added to fats, oils and soap formulations for prevention of rancidity and discoloration, to detergents and dishwashing compounds, and to sodium silicate solutions for use in the preparation of silica gels. Alternatively, a solution of a polyvalent heavy metal (e.g. iron) complexed with one of the above sequestrants (e.g. N-methyl N-carboxymethyl glucamine) may be added to a solution of sodium silicate without precipitation and the solution treated with acid to form a gel in which the polyvalent heavy metal is evenly dispersed throughout. Such silica gels may be employed as catalysts in the cracking of petroleums.ALSO:Solutions containing polyvalent heavy metal ions having an atomic number greater than 24 are treated with a sequestering agent containing no more than two carboxyl bearing carbon atoms of the formula: <FORM:0772820/I/1> wherein the empirical radical C6H13O4 represents the hexane pentol residue of a hexityl amine, R is hydrogen, (C1-C3) alkyl or (C2-C3) hydroxy - alkyl; Y is hydrogen or an alkali metal; n is 1 or 2; a is 0 or 1; b is 0, 1 or 2; c is 0 or 1; d is 0 or 1 and a + b + c + d = 2. The process may be applied to the selective removal of ions such as Ce++++, Cd++, Cu++, Fe+++, Fe++, Sn++, Hg++, Bi+++, Co++, Zn++, As+++, Sb+++, Ti++++, Zr++++, Ni++, Mn++ and Pb++ from solutions also containing alkaline earth metal ions such as Ca++ and Mg++. Other sequestering agents such as ethylenediamine tetraacetic acid may be used in conjunction with the above sequestrant. Silica gel compositions containing complexes between one or more of the above polyvalent heavy metal ions and the above sequestering agents are used to supply trace elements to soils deficient in such elements.ALSO:Latex formulations are stabilized against traces of polyvalent heavy metal ions having an atomic number greater than 24 by the addition of a compound containing no more than two carboxyl bearing carbon atoms of the formula: <FORM:0772820/V/1> wherein the empirical radical C6H13O5 represents the hexane pentol residue of a hexityl amine; R is hydrogen, (C1-C3) alkyl or (C2-C3) hydroxy-alkyl; Y is hydrogen or an alkali metal; n is 1 or 2; a is 0 or 1; b us 0, 1 or 2; c is 0 or 1; d is 0 or 1 and a+b+c+d=2. Other sequestering agents such as ethylene diamine tetraacetic acid may be used in conjunction with the above sequestrant.
GB4166/55A 1954-02-12 1955-02-11 Improvements in sequestering polyvalent metal ions Expired GB772820A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US772820XA 1954-02-12 1954-02-12

Publications (1)

Publication Number Publication Date
GB772820A true GB772820A (en) 1957-04-17

Family

ID=22137155

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4166/55A Expired GB772820A (en) 1954-02-12 1955-02-11 Improvements in sequestering polyvalent metal ions

Country Status (1)

Country Link
GB (1) GB772820A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5023018A (en) * 1987-03-27 1991-06-11 Huls Aktiengesellschaft Use of polyhydroxyalkylamine-N,N-dicarboxylic acids and their salts as builders in detergents and cleaning agents
CN104725254A (en) * 2015-02-13 2015-06-24 陕西科技大学 Preparation method of glycosylated surfactant
JP2015127326A (en) * 2013-11-29 2015-07-09 川研ファインケミカル株式会社 Cosmetic containing amino sugar derivative

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5023018A (en) * 1987-03-27 1991-06-11 Huls Aktiengesellschaft Use of polyhydroxyalkylamine-N,N-dicarboxylic acids and their salts as builders in detergents and cleaning agents
JP2015127326A (en) * 2013-11-29 2015-07-09 川研ファインケミカル株式会社 Cosmetic containing amino sugar derivative
CN104725254A (en) * 2015-02-13 2015-06-24 陕西科技大学 Preparation method of glycosylated surfactant

Similar Documents

Publication Publication Date Title
US3728385A (en) N-oxide-iminodicarboxylates
JP3615546B2 (en) Use of glycine-N, N-diacetic acid derivatives as biologically degradable complexing agents for alkaline earth metal- and heavy metal ions and their preparation
JPS63199295A (en) Detergent composition containing ethylenediamine-n, n&#39;-disuccinic acid
SA516370704B1 (en) Mixtures of enantiomers, and process for making such mixtures
CH624709A5 (en)
US2868724A (en) Sequestering process
CZ340296A3 (en) Low-foaming branched alkyldimethylaminooxides
JPS6325597B2 (en)
GB772820A (en) Improvements in sequestering polyvalent metal ions
WO1982000665A1 (en) Process and product for the passivation of iron and steel surfaces
US2362401A (en) Detergent compositions
ES398553A1 (en) Detergent compositions
JP2843112B2 (en) Detergent composition
EP0314648B1 (en) Detergent compositions
JPH02272099A (en) Normally liquid detergent and/or bleaching composition containing low-molecular-weight tertiary amine of n-oxide form
US2483253A (en) Detergent composition
US3991000A (en) Built bleaching detergent
US2528380A (en) Cycloimidine derivatives and methods for preparing them
US3001997A (en) Carboxylic acid amides of n-aminoalkylene-heterocyclic amines
US2073923A (en) Art of stabilizing soap
JPH05246962A (en) Deodorization of aqueous solution containing basic amino acid or its salt
GB848654A (en) Improvements in or relating to detergents and disinfectants
US2628162A (en) Method for inhibiting precipitation of 2, 4-d salts in hard water
USRE23767E (en) Hydroxy-aromatic alkylene di-imino
JP4124524B2 (en) Method for producing N-substituted β-alanine or salt thereof and surfactant composition containing N-substituted β-alanine or salt thereof