GB771857A - Composition - Google Patents

Composition

Info

Publication number
GB771857A
GB771857A GB20737/55A GB2073755A GB771857A GB 771857 A GB771857 A GB 771857A GB 20737/55 A GB20737/55 A GB 20737/55A GB 2073755 A GB2073755 A GB 2073755A GB 771857 A GB771857 A GB 771857A
Authority
GB
United Kingdom
Prior art keywords
alpha
butyl
trimethylhexyl
trimethyl
tin oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20737/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Primerica Inc
Original Assignee
Metal and Thermit Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metal and Thermit Corp filed Critical Metal and Thermit Corp
Publication of GB771857A publication Critical patent/GB771857A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols

Abstract

Chlorine-containing synthetic resins, e.g. polyvinyl chloride, are stabilized by incorporating therein a mercaptoacid ester of the formula HSRCOOR1, where both R and R1 represent a substituted or unsubstituted alkyl, aryl or mixed alkyl-aryl radical and optionally a plasticiser and another stabilizer. Esters mentioned are nonyl, glyceryl, butyl monoricinoleate mono-, dihydroabietyl, octadecyl, iso-octyl, decyl, trimethyl hexyl, cyclohexyl, phenoxyethyl, trimethyl nonyl, diethylene glycol laurate, and ethylene glycol ricinoleate mercaptoacetates, dibutyl and dinonyl thiomalates, 2-butyloctyl beta - mercaptopropionate, methyl thiosalicylate, trimethyl alpha-mercaptopropionate, trimethylhexyl beta-mercaptobutyrate, trimethylhexyl alpha - mercaptovalerate, trimethylhexyl alpha - mercaptocaproate, butyl alpha - mercaptocaprylate, ethyl alpha - mercapto - alpha - ethylcaproate, butyl alpha - mercaptopelargonate, butyl alpha - mercaptolaurate, butyl alpha - mercaptopalmitate, butyl alpha-mercaptostearate, ethyl alpha-mercaptophenylacetate, ethyl alpha - mercaptodiphenylacetate, trimethylhexyl alpha - mercaptodiethylacetate, trimethylhexyl 5 - mercapto - valerate, trimethyl - hexyl 6 - mercaptocaproate, trimethylhexyl 7 - mercaptohexanoate, butyl 8 - mercaptocaprylate, and butyl 12-mercaptolaurate. The additional stabilizer may be dimethyl tin oxide, dibutyl tin oxide, dilauryl tin oxide, butyl stannoic acid, the reaction product of organotin oxides with aldehydes or acids, e.g. dibutyl tin oxide and 2-ethyl hexanal, antimony trioxide, trialkyl or triaryl antimonites or antimonyl compounds. Dioctyl phthalate is the exemplified plasticiser.
GB20737/55A 1954-08-26 1955-07-18 Composition Expired GB771857A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US771857XA 1954-08-26 1954-08-26

Publications (1)

Publication Number Publication Date
GB771857A true GB771857A (en) 1957-04-03

Family

ID=22136568

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20737/55A Expired GB771857A (en) 1954-08-26 1955-07-18 Composition

Country Status (2)

Country Link
DE (1) DE1217609B (en)
GB (1) GB771857A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3063963A (en) * 1958-10-13 1962-11-13 Eastman Kodak Co Stabilized polymers of vinylidene chloride or vinyl chloride containing a sulfur compound and a tin compound
EP0001631A1 (en) * 1977-10-26 1979-05-02 Ciba-Geigy Ag Mercaptans on solid carriers and their application in the stabilisation of synthetic thermoplastic materials that contain chlorine
US4256618A (en) 1979-01-24 1981-03-17 Argus Chemical Corporation Antimony mercaptocarboxylic acid or ester-mercaptocarboxylic acid ester stabilizers for rigid polyvinyl chloride resin compositions
US4361665A (en) 1981-06-15 1982-11-30 Tenneco Chemicals, Inc. Heat-stable vinyl halide resin compositions and a process for their production
FR2557115A1 (en) * 1983-12-23 1985-06-28 Centre Nat Rech Scient Process for obtaining plasticised polyvinyl chloride containing grafted plasticising functional groups
US4576984A (en) * 1982-02-04 1986-03-18 Morton Thiokol, Inc. Stabilizer compositions for PVC resins
US4665114A (en) * 1982-02-04 1987-05-12 Morton Thiokol Inc. Stabilizer compositions and polymers containing same
US4686255A (en) * 1983-09-05 1987-08-11 Henkel Kommanditgesellschaft Auf Aktien Stabilized polyvinyl chloride molding compositions
US4701486A (en) * 1981-02-26 1987-10-20 Morton Thiokol, Inc. Stabilizer compositions for PVC resins
US4963594A (en) * 1982-03-30 1990-10-16 Rhone-Poulenc Specialites Chimiques Heat/color stabilized polymers of vinyl chloride

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2491871A1 (en) * 1980-10-10 1982-04-16 Ato Chimie IMPROVEMENT IN STERILIZATION OF OBJECTS IN HALOGENO-VINYL POLYMERS BY IONIZING RADIATION, AND RESINS FOR THEIR PRODUCTION
FR2491936A1 (en) * 1980-10-13 1982-04-16 Ato Chimie PROCESS FOR MAKING POLYMERS RESISTANT TO IONIZING RADIATION, AND COMPOSITIONS OBTAINED
US4360619A (en) 1981-02-26 1982-11-23 Carstab Corporation Stabilizer compositions and polymers containing same
DE3806094A1 (en) * 1988-02-26 1989-09-07 Huels Chemische Werke Ag STABILIZER MIXTURE FOR MOLDING MATERIALS BASED ON VINYL CHLORIDE POLYMERISATES, THEIR USE AND THE MOLDING MATERIALS
EP0365483B1 (en) * 1988-10-20 1993-12-29 Ciba-Geigy Ag Mercaptobenzoic-acid esters used as stabilizers for chlorine-containing polymers

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2222928A (en) * 1939-05-17 1940-11-26 Goodrich Co B F Polyvinyl halide compositions
FR956489A (en) * 1946-09-25 1950-02-02
US2614095A (en) * 1951-06-15 1952-10-14 Goodrich Co B F Heat stabilization of a chlorine containing polymer with a mercapto acid amide

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3063963A (en) * 1958-10-13 1962-11-13 Eastman Kodak Co Stabilized polymers of vinylidene chloride or vinyl chloride containing a sulfur compound and a tin compound
EP0001631A1 (en) * 1977-10-26 1979-05-02 Ciba-Geigy Ag Mercaptans on solid carriers and their application in the stabilisation of synthetic thermoplastic materials that contain chlorine
US4256618A (en) 1979-01-24 1981-03-17 Argus Chemical Corporation Antimony mercaptocarboxylic acid or ester-mercaptocarboxylic acid ester stabilizers for rigid polyvinyl chloride resin compositions
US4701486A (en) * 1981-02-26 1987-10-20 Morton Thiokol, Inc. Stabilizer compositions for PVC resins
US4361665A (en) 1981-06-15 1982-11-30 Tenneco Chemicals, Inc. Heat-stable vinyl halide resin compositions and a process for their production
US4576984A (en) * 1982-02-04 1986-03-18 Morton Thiokol, Inc. Stabilizer compositions for PVC resins
US4665114A (en) * 1982-02-04 1987-05-12 Morton Thiokol Inc. Stabilizer compositions and polymers containing same
US4963594A (en) * 1982-03-30 1990-10-16 Rhone-Poulenc Specialites Chimiques Heat/color stabilized polymers of vinyl chloride
US4686255A (en) * 1983-09-05 1987-08-11 Henkel Kommanditgesellschaft Auf Aktien Stabilized polyvinyl chloride molding compositions
FR2557115A1 (en) * 1983-12-23 1985-06-28 Centre Nat Rech Scient Process for obtaining plasticised polyvinyl chloride containing grafted plasticising functional groups

Also Published As

Publication number Publication date
DE1217609B (en) 1966-05-26

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