GB770392A - Method and apparatus for continuous percolation of liquid hydrocarbons - Google Patents
Method and apparatus for continuous percolation of liquid hydrocarbonsInfo
- Publication number
- GB770392A GB770392A GB16449/52A GB1644952A GB770392A GB 770392 A GB770392 A GB 770392A GB 16449/52 A GB16449/52 A GB 16449/52A GB 1644952 A GB1644952 A GB 1644952A GB 770392 A GB770392 A GB 770392A
- Authority
- GB
- United Kingdom
- Prior art keywords
- adsorbent
- liquid
- column
- oil
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
- C10G25/08—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil according to the "moving bed" method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
A method of countercurrently contacting a liquid hydrocarbon with a downwardly moving column of solid absorbent (in the form of particles within the range of 4-100 mesh) comprises maintaining a column of the absorbent along an intermediate portion of a confined elongated treating zone, maintaining a body of contacted liquid in an upper portion of the treating zone immediately above and open to the surface of the column, replenishing the column at its upper end with fresh absorbent in one confined feed stream or a plurality of such streams horizontally spaced, the stream or streams discharging a substantial distance below the surface of the body of contacted liquid in the upper portion of the treating zone, introducing liquid hydrocarbon feed into the lower section of the column of adsorbent so as to force the liquid to flow upwardly into and through the column of adsorbent at a velocity controlled at the liquid inlet which velocity is below that at which the flowing liquid would entrain the adsorbent particles, and withdrawing contacted liquid from the upper portion of the above-mentioned body of contacted liquid hydrocarbon. The method is applicable to the treatment of liquid hydrocarbons, particularly lubricating oils and lower-boiling petroleum fractions which are of low asphalt content, with solid adsorbents for the purpose of removing small amounts of impurities or undesirable contaminants therefrom. Oilpurifying processes to which the method is applicable are decolorization, neutralization, removal of suspended colloidal or dissolved impurities such as carbon, coke, oxygen- or nitrogen-containing and other gum-forming compounds, and improvement of demulsibility properties of the oil. The method is also applicable to the separation of hydrocarbon mixtures by adsorption and to the treatment of absorbents with liquid hydrocarbons such as petroleum naphtha or n-heptane to recover occluded liquid materials such as oil. Adsorbents mentioned are Fuller's <PICT:0770392/III/1> <PICT:0770392/III/2> <PICT:0770392/III/3> earth, bauxite, bone char, bentonite, charcoal, magnesium silicate, heat- and acid-activated kaolin, activated carbon silica gel, alumina gel and silica-alumina gel. After being used for treating hydrocarbon oil, the adsorbent may be washed, dried and burnt, and the regenerated adsorbent thus obtained may be recycled to the oil treatment stage. In Fig. 1, adsorbent from conduit 12 enters vessel 10 through a plurality of pipes 18 and drops through tubes 20, which are suspended from the ends of pipes 18, into the body of contacted liquid hydrocarbon. The adsorbent column 55 is supported on partition 30, spent adsorbent being withdrawn through conduits 37. The liquid hydrocarbon is introduced through pipe 36 and passes through holes 50 in conduit 35 and then through nozzles 33 into the adsorbent column. Treated liquid hydrocarbon is withdrawn through pipe 23. An alternative form of treating apparatus is shown in Fig. 6, while an alternative method of introducing the adsorbent into the apparatus is illustrated in Fig. 7. In a specific example, the method is applied to the decolorization of a petroleum bright stock using fuller's earth as the adsorbent. The bright stock is blended with naphtha before treatment and the spent fuller's earth is freed of oil, this oil being recycled to the decolorization zone. The spent Fuller's earth is then washed, dried, regenerated and finally recycled to the decolorization zone. Specifications 576,058, 770,391, 770,393 and 770,395 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US237268A US2749290A (en) | 1951-07-17 | 1951-07-17 | Method and apparatus for continuous percolation of liquid hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB770392A true GB770392A (en) | 1957-03-20 |
Family
ID=22893013
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14861/52A Expired GB770391A (en) | 1951-07-17 | 1952-06-12 | Method and apparatus for treating liquid hydrocarbons with moving absorbents |
GB16449/52A Expired GB770392A (en) | 1951-07-17 | 1952-06-30 | Method and apparatus for continuous percolation of liquid hydrocarbons |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14861/52A Expired GB770391A (en) | 1951-07-17 | 1952-06-12 | Method and apparatus for treating liquid hydrocarbons with moving absorbents |
Country Status (4)
Country | Link |
---|---|
US (1) | US2749290A (en) |
DE (1) | DE966390C (en) |
FR (1) | FR1074553A (en) |
GB (2) | GB770391A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT980491B (en) * | 1972-03-27 | 1974-09-30 | Degussa | PROCEDURE AND DEVICE FOR THE ELUTION OF SUBSTANCES FROM PRECIOUS VOLUMINOUS PITATES OR SUSPENSION |
SE390888B (en) * | 1974-07-10 | 1977-01-31 | Uddeholms Ab | APPARATUS FOR TREATMENT OF LIQUID |
CN109622192B (en) * | 2018-12-25 | 2020-12-29 | 宁波越茂活性炭有限公司 | Active carbon treatment device |
CN112473182A (en) * | 2020-11-10 | 2021-03-12 | 湖南创源生物科技有限公司 | Sugar liquid decoloration jar convenient to wash |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2132151A (en) * | 1935-03-13 | 1938-10-04 | Pennsylvania Petroleum Res Cor | Apparatus for treating mineral oils |
US2412135A (en) * | 1943-01-28 | 1946-12-03 | Socony Vacuum Oil Co Inc | Method and apparatus for hydrocarbon conversion |
US2490336A (en) * | 1945-11-17 | 1949-12-06 | Socony Vacuum Oil Co Inc | Method for conversion of petroleum hydrocarbons |
US2459056A (en) * | 1945-12-31 | 1949-01-11 | Sinclair Refining Co | Gas-solid contacting apparatus |
US2477281A (en) * | 1947-03-10 | 1949-07-26 | Soncony Vacuum Oil Company Inc | Method for hydrocarbon conversion |
US2552436A (en) * | 1947-12-06 | 1951-05-08 | Standard Oil Dev Co | Process for treating lubricating oil with solid adsorbents |
US2552435A (en) * | 1947-12-06 | 1951-05-08 | Standard Oil Dev Co | Lubricating oil treating process |
US2564717A (en) * | 1949-04-28 | 1951-08-21 | Sun Oil Co | Continuous adsorption process |
US2618586A (en) * | 1950-11-03 | 1952-11-18 | Wigton Abbott Corp | Process for desulfurizing petroleum products in the liquid phase |
-
1951
- 1951-07-17 US US237268A patent/US2749290A/en not_active Expired - Lifetime
-
1952
- 1952-06-12 GB GB14861/52A patent/GB770391A/en not_active Expired
- 1952-06-30 GB GB16449/52A patent/GB770392A/en not_active Expired
- 1952-07-16 FR FR1074553D patent/FR1074553A/en not_active Expired
- 1952-07-17 DE DES29337A patent/DE966390C/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB770391A (en) | 1957-03-20 |
DE966390C (en) | 1957-08-01 |
FR1074553A (en) | 1954-10-06 |
US2749290A (en) | 1956-06-05 |
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