GB767726A - Sizing composition and fibrous material coated therewith - Google Patents

Sizing composition and fibrous material coated therewith

Info

Publication number
GB767726A
GB767726A GB8238/54A GB823854A GB767726A GB 767726 A GB767726 A GB 767726A GB 8238/54 A GB8238/54 A GB 8238/54A GB 823854 A GB823854 A GB 823854A GB 767726 A GB767726 A GB 767726A
Authority
GB
United Kingdom
Prior art keywords
acid
amides
solubilized
film
forming agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8238/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Libbey Owens Ford Glass Co
Original Assignee
Libbey Owens Ford Glass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Libbey Owens Ford Glass Co filed Critical Libbey Owens Ford Glass Co
Publication of GB767726A publication Critical patent/GB767726A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/272—Unsaturated compounds containing sulfur atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

A sizing composition for application to glass fibres during the formation thereof comprises an aqueous emulsion of a resinous film-forming agent, such as polybutyl methacrylate, polystyrene, styrene-butadiene copolymer, polyvinyl pyridine, polyvinyl butyral and polyvinyl acetate, held in a dispersed condition by a wetting agent of cationic character stable through a pH range of 2 to 8 and capable of air drying to a continuous film, a lubricant which is compatible with the film-forming agent and selected from monobasic fatty acid amines, dibasic acid amides and imidazoline derivatives which have been solubilized with low molecular weight fatty acids, high molecular weight ester type monomers and ester type plasticizers for the film forming agent, and a deionized vinyl silanol in which the average number of organo groups attached to each silicon atom is from 0.8 to 1.5 made by the deionization of a vinyl siliconate of an alkali metal or alkaline earth metal. The vinyl silanol dispersion is preferably produced as described in Specification 746,037, or by treating a neutralized siliconate solution as disclosed in Specification 746,038 to successive or simultaneous treatment with anionic and cationic exchange resins. Lubricants specified are amides of pelargonic acid and tetraethylene pentamine solubilized with acetic acid, amides of stearic acid or caproic acid reacted with tetraethylene pentamine, imidazoline derivatives solubilized with acetic acid, diethyl sulphate or benzyl chloride, diallyl phthalate, ethylene glycol dimethacrylate, diamyl, dibutyl, dicarbitol, dibutoxyglycol or dimethoxyglycol phthalate, butyl phthalyl butyl glycolate, methyl phthalyl ethyl glycolate, triglycol di-2-ethylbutyrate, triglycol di-2-ethylhexoate, tricresyl or triphenyl phosphate, a product prepared by condensing ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol, methoxyethyloleate, or an ester of azelaic or pelargonic acid.ALSO:Glass fibres are sized by application during the formation thereof of an aqueous emulsion of a resinous filmforming agent, such as polybutyl methacrylate, polystyrene, styrene-butadiene copolymer, polyvinyl pyridine, polyvinyl butyral and polyvinyl acetate, held in a dispersed condition by a wetting agent of cationic character stable through a pH range of 2 to 8 and capable of air drying to a continuous film, a lubricant which is compatible with the film-forming agent and selected from monobasic fatty acid amides, dibasic acid amides and imidazoline derivatives which have been solubilized with low molecular weight fatty acids, high molecular weight ester type monomers and ester type plasticizers for the film forming agent, and a deionized vinyl silanol in which the average number of organo groups attached to each silicon atom is from 0.8 to 1.5 made by the deionization of a vinyl siliconate of an alkali metal or alkaline earth metal. The vinyl silanol dispersion is preferably produced as described in Specification 746,037 [Group IV(a)], or by treating a neutralized siliconate solution as disclosed in Specification 746,038 [Group IV(a)], to successive or simultaneous treatment with anionic and cationic exchange resins. Lubricants specified are amides of pelargonic acid and tetraethylene pentamine solubilized with acetic acid, amides of stearic acid or caproic acid reacted with tetraethylene pentamine, imidazoline derivatives solubilized with acetic acid, diethyl sulphate or benzyl chloride, diallyl phthalate, ethylene glycol dimethacrylate, diamyl, dibutyl, dicarbitol, dibutoxyglycol or dimethoxyglycol phthalate, butyl phthalyl butyl glycolate, methyl phthalyl ethyl glycolate, triglycol di-2-ethylbutyrate, triglycol di-2-ethylhexoate, tricresyl or triphenyl phosphate, a product prepared by condensing ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol. methoxy-ethyloleate, or an ester of azelaic or pelargonic acid.
GB8238/54A 1953-03-24 1954-03-22 Sizing composition and fibrous material coated therewith Expired GB767726A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US336162XA 1953-03-24 1953-03-24

Publications (1)

Publication Number Publication Date
GB767726A true GB767726A (en) 1957-02-06

Family

ID=21871428

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8238/54A Expired GB767726A (en) 1953-03-24 1954-03-22 Sizing composition and fibrous material coated therewith

Country Status (5)

Country Link
BE (1) BE527556A (en)
CH (1) CH336162A (en)
DE (1) DE1019637B (en)
FR (1) FR1097128A (en)
GB (1) GB767726A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192089A (en) * 1962-03-19 1965-06-29 Dow Corning Compositions for sizing siliceous fibers and process
DE2139977A1 (en) * 1970-08-14 1972-02-17 Ppg Industries Inc Process for treating glass fibers to improve their adhesion to polyolefins
CN110230200A (en) * 2019-05-21 2019-09-13 武汉纺织大学 A method of improving spandex filament strength

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192089A (en) * 1962-03-19 1965-06-29 Dow Corning Compositions for sizing siliceous fibers and process
DE2139977A1 (en) * 1970-08-14 1972-02-17 Ppg Industries Inc Process for treating glass fibers to improve their adhesion to polyolefins
CN110230200A (en) * 2019-05-21 2019-09-13 武汉纺织大学 A method of improving spandex filament strength
CN110230200B (en) * 2019-05-21 2021-09-24 武汉纺织大学 Method for improving strength of spandex filament

Also Published As

Publication number Publication date
CH336162A (en) 1959-02-15
FR1097128A (en) 1955-06-29
DE1019637B (en) 1957-11-21
BE527556A (en)

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