GB762362A - Improvements in the treatment of solutions containing carboxylic acids and derivatives thereof - Google Patents
Improvements in the treatment of solutions containing carboxylic acids and derivatives thereofInfo
- Publication number
- GB762362A GB762362A GB15947/53A GB1594753A GB762362A GB 762362 A GB762362 A GB 762362A GB 15947/53 A GB15947/53 A GB 15947/53A GB 1594753 A GB1594753 A GB 1594753A GB 762362 A GB762362 A GB 762362A
- Authority
- GB
- United Kingdom
- Prior art keywords
- exchange material
- solution
- anion exchange
- anion
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/02—Refining fats or fatty oils by chemical reaction
- C11B3/06—Refining fats or fatty oils by chemical reaction with bases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/014—Ion-exchange processes in general; Apparatus therefor in which the adsorbent properties of the ion-exchanger are involved, e.g. recovery of proteins or other high-molecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Abstract
A C8-C24 aliphatic carboxylic acid or a lactone or an estolide of a C8-C24 hydroxy aliphatic carboxylic acid is removed from its solution in an organic solvent in which it does not ionize by contacting the solution, in the presence of water, with an anion exchange material having alkaline properties. The process is primarily concerned with purifying fatty oils from free fatty acids &c. but the latter may also be in solution in volatile solvents such as petroleum ether, carbon tetrachloride, trichlorethane and hexane. In the case of fatty oils they may be diluted with an oil-solvent. The anion exchange material is preferably an anion exchange resin of general formula <FORM:0762362/IV(b)/1> where R1 and R2 are alkyl groups such as methyl groups, R3 is an alkyl group or a hydroxy-alkyl group such as methyl or hydroxyethyl, and R4 is a polystyrene group bound by a di-vinyl benzene bridge to another quaternary ammonium group. The anion exchange material having alkaline properties may be formed by washing an anion-exchange material with an aqueous alkaline hydroxide solution until the wash liquor shows only a slight reaction for anion followed by washing with water until the wash liquor is neutral. The water necessary in the process may be present in the solution which is contacted with the anion exchange material. Alternatively the water may be present in the anion exchange material before it is contacted with the solution. The proportion of water is variable but should be insufficient to cover the surface of the exchange material as a separate phase. Refining may be effected by stirring a batch of crude or de-slurried oil with the anion-exchanger and separating the latter by filtration, or by directing a stream of oil through a column of the material. A small quantity of ammonia may be mixed with the oil before the treatment. The anion-exchange material loaded with the fatty acid &c. is regenerated by treatment with an aqueous alkaline hydroxide solution having a pH not less than 11.8. The regeneration may be effected by first exchanging the fatty acid radical by another acid radical, a salt of which other acid radical and an alkaline hydroxide is soluble in an aqueous alkaline hydroxide solution, and then treating the anion exchange material loaded with the other radical with an alkaline hydroxide solution having a pH not less than 11.8. The Provisional Specification refers to the removal of coumarin from its solution in an organic solvent.ALSO:A C8-C24 aliphatic carboxylic acid or a lactone or an estolide of a C8-C24 hydroxy aliphatic caboxylic acid is removed from its solution in an organic solvent in which it does not ionise by contacting the solution, in the presence of water, with an anion exchange material having alkaline properties. The process is primarily concerned with purifying fatty oils from free fatty acids &c., but the latter may also be in solution in volatile solvents such as petroleum ether, carbon tetrachloride, trichloroethane and hexane. In the case of fatty oils they may be diluted with an oil-solvent. The anion exchange material is preferably an anion exchange resin of general formula <FORM:0762362/III/1> where R1 and R2 are alkyl groups such as methyl groups, R3 is an alkyl group or a hydroxy-alkyl group such as methyl or hydroxyethyl, and R4 is a polystyrene group bound by a de-vinyl benzene bridge to another quaternary ammonium group. The anion exchange material having alkaline properties may be formed by washing an anion-exchange material with an aqueous alkaline hydroxide solution until the wash liquor shows only a slight reaction for anion followed by washing with water until the wash liquor is neutral. The water necessary in the process may be present in the solution which is contacted with the anion exchange material. Alternatively the water may be present in the anion exchange material before it is contacted with the solution. The proportion of water is variable but should be insufficient to cover the surface of the exchange material as a separate phase. Refining may be effected by stirring a batch of crude or de-slimed oil with the anion-exchanger and separating the latter by filtration, or by directing a stream of oil through a column of the material. A small quantity of ammonia may be mixed with the oil before the treatment. The anion exchange material loaded with the fatty acid &c. is regenerated by treatment with an aqueous alkaline hydroxide solution having a pH not less than 11.8. This regeneration may be effected by first exchanging the fatty acid radical by another acid radical, a salt of which other acid radical and an alkaline hydroxide is soluble in an aqueous alkaline hydroxide solution, and then treating the anion exchange material loaded with the other radical with an alkaline hydroxide solution having a pH not less than 11.8. The Provisional Specification refers to the removal of coumarin from its solution in an organic solvent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB15947/53A GB762362A (en) | 1953-06-10 | 1953-06-10 | Improvements in the treatment of solutions containing carboxylic acids and derivatives thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB15947/53A GB762362A (en) | 1953-06-10 | 1953-06-10 | Improvements in the treatment of solutions containing carboxylic acids and derivatives thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB762362A true GB762362A (en) | 1956-11-28 |
Family
ID=10068421
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15947/53A Expired GB762362A (en) | 1953-06-10 | 1953-06-10 | Improvements in the treatment of solutions containing carboxylic acids and derivatives thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB762362A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2366043A1 (en) * | 1976-09-30 | 1978-04-28 | Rohm & Haas | PROCESS FOR REMOVING ORGANIC ACIDS BY MEANS OF AN ION EXCHANGER RESIN |
EP1752522A1 (en) * | 2005-08-10 | 2007-02-14 | Cognis IP Management GmbH | Process for treatment of fats |
-
1953
- 1953-06-10 GB GB15947/53A patent/GB762362A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2366043A1 (en) * | 1976-09-30 | 1978-04-28 | Rohm & Haas | PROCESS FOR REMOVING ORGANIC ACIDS BY MEANS OF AN ION EXCHANGER RESIN |
EP1752522A1 (en) * | 2005-08-10 | 2007-02-14 | Cognis IP Management GmbH | Process for treatment of fats |
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