GB760116A - Pigments and processes of producing same - Google Patents

Pigments and processes of producing same

Info

Publication number
GB760116A
GB760116A GB19037/53A GB1903753A GB760116A GB 760116 A GB760116 A GB 760116A GB 19037/53 A GB19037/53 A GB 19037/53A GB 1903753 A GB1903753 A GB 1903753A GB 760116 A GB760116 A GB 760116A
Authority
GB
United Kingdom
Prior art keywords
silica gel
organic
treated
mixed
colour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19037/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Allied Corp
Original Assignee
Allied Chemical and Dye Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allied Chemical and Dye Corp filed Critical Allied Chemical and Dye Corp
Publication of GB760116A publication Critical patent/GB760116A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

Pigments of improved dispersability and tinctorial value prepared by mixing finely-divided organic colours in a liquid medium with activated silica gel and thereafter removing the liquid (see Group IV (c)) are used to colour cellulose acetate and nitrate, phenol-formaldehyde, urea-formaldehyde and polyamide resins and polyethylene and polyvinyl resins, e.g. vinyl and vinylidene chloride polymers. A series of green pigments prepared by mixing 5, 10 and 20 parts of activated silica gel with 1 part of dimethoxy-dibenzanthrone and water to a paste followed by grinding and drying are (a) mixed with polystyrene and injection-moulded at 320 DEG F.; and (b) mixed with cellulose acetate and injection-moulded at 350 DEG to 380 DEG F.ALSO:The invention comprises pigments of improved dispersibility and tinctorial value, which are produced by a process wherein an activated silica gel which has a surface area of at least 100 square meters, and preferably 180 to 900 square meters per gram, an oil absorption value of at least 100, and preferably from 150 to 180, and an average particle size of from 0.01 to 50 microns, and preferably from 0.02 to 20 microns, is mixed with a finely divided organic colour in a liquid medium, and thereafter the liquid is removed from the mixture. From 1/20 to 20 parts and preferably from 1/5 to 5 parts by weight of activated silica gel are used per part by weight of organic colour. Specified organic colours are vat, azo, phthalocyanine or triphenylmethane dyes and lakes. Any organic colour which forms a dispersion of finely divided particles in a liquid medium or which may be precipitated in finely divided form from a liquid medium may be used, the silica gel being added prior to the drying thereof. When the organic colour is precipitated from an aqueous medium the silica gel may be added before, during, or after the precipitation. The organic colour may also be separated from the liquid medium, e.g. by filtration and admixed with the silica gel prior to drying. The silica gel and organic colour may also be mixed in a volatile organic solvent, in which the organic colour may be soluble, and the mixture evaporated to dryness. The pigments are suitable for colouring printing inks, enamels, paints, lacquers, and plastics such as cellulose acetate and nitrate and polyethylene or polyvinyl resins (see Group IV(a)), phenol - formaldehyde resins, urea - formaldehyde resins, polyamide resins and rubber. In examples: (1) dimethoxy - dibenzanthrone is mixed to a paste with silica gel and water, ground and dried to give a soft and readily dispersible pigment, 5 : 51 - dichloro - 6 : 61 - dimethyl - 2 : 21 - bis - thionaphthen - indigo and monochloro - N - dihydro - 1 : 2 : 11 : 21 - anthraquinone azine being treated similarly; (2) silica gel is added to the solution of the leuco compound of monochloro - N - dihydro - 1 : 2 : 11 : 21 - anthraquinone azine, the dyestuff is precipitated by oxidation with hydrogen peroxide and the mixture filtered and dried; (3) a filter cake of the monazo dyestuff from diazotized xylidine coupled with b - napthol is treated as in (1); (4) a filter cake of the monoazo-dyestuff from diazotized 2 - chloro - 4 - nitro - aniline coupled with b - napthol is treated as in (1); (5) copper phthalocyanine is treated as in (1); (6) the hydrochloride of pentamethyl triamino triphenylcarbinol anhydride is formed into a lake with alumina, the lake filtered and the resultant press cake mixed with silica gel and dried; (7) the alumina lake of 1 : 2 - dihydroxyanthraquinone is treated as in (6).ALSO:Pigments of improved dispersibility and tinctorial value, are produced by mixing wherein an activated silica gel which has a surface area of at least 100 square meters, and preferably 180 to 900 square meters per gram, an oil absorption value of at least 100, and preferably from 150 to 180, and an average particle size of from 0.01 to 50 microns, and preferably from 0.02 to 20 microns, with a finely divided organic colour in a liquid medium, and thereafter the liquid is removed from the mixture. From 1/20 to 20 parts and preferably from 1/5 to 5 parts by weight of activated silica gel are used per part by weight of organic colour. Specified organic colours are vat, azo, phthalocyanine or triphenylmethane dyes and lakes. Any organic colour which forms a dispersion of finely divided particles in a liquid medium or which may be precipitated in finely divided form from a liquid medium may be used, the silica gel being added prior to the drying thereof. When the organic colour is precipitated from an aqueous medium the silica gel may be added before, during, or after the precipitation. The organic colour may also be separated from the liquid medium, e.g. by filtration and admixed with the silica gel prior to drying. The silica gel and organic colour may also be mixed in a volatile organic solvent, in which the organic colour may be soluble, and the mixture evaporated to dryness. The pigments are suitable for colouring enamels, paints and lacquers. In examples: (1) dimethoxy-dibenzanthrone is mixed to a paste with silica gel and water, ground and dried to give a soft and readily dispersable pigment, 5:51-dichloro-6:61-dimethyl-2:21-bisthionaphthen -indigo and monochloro-N-dihydro-1:2:11:21-anthraquinone azine being treated similarly; (2) silica gel is added to the solution of the leuco compound of monochloro - N - dihydro - 1:2:11:21 - anthraquinone azine, the dyestuff is precipitated by oxidation with hydrogen peroxide and the mixture filtered and dried; (3) a filter cake of the monoazo dyestuff from diazotized xylidine coupled with b -napthol is treated as in (1); (4) a filter cake of the monoazodyestuff from diazotized 2-chloro4-nitro-aniline coupled with b -naphthol is treated as in (1); (5) copper phthalocyanine is treated as in (1); (6) the hydrochloride of pentamethyl triamino triphenylcarbinol anhydride is formed into a lake with alumina, the lake filtered and the resultant press cake mixed with silica gel and dried, (7) the alumina lake of 1:2-dihydroxyanthraquinone is treated as in (6).
GB19037/53A 1952-07-12 1953-07-09 Pigments and processes of producing same Expired GB760116A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US760116XA 1952-07-12 1952-07-12

Publications (1)

Publication Number Publication Date
GB760116A true GB760116A (en) 1956-10-31

Family

ID=22129367

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19037/53A Expired GB760116A (en) 1952-07-12 1953-07-09 Pigments and processes of producing same

Country Status (1)

Country Link
GB (1) GB760116A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4251282A (en) * 1977-09-03 1981-02-17 Dynamit Nobel Aktiengesellschaft Method of preparing dye pigments

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4251282A (en) * 1977-09-03 1981-02-17 Dynamit Nobel Aktiengesellschaft Method of preparing dye pigments

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